ChemicalBook > CAS DataBase List > METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE

METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE

Product Name
METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE
CAS No.
72054-60-5
Chemical Name
METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE
Synonyms
2-amino-5-ethoxycarbonyl-4-methylthiazole;methyl 2-(2-amino-5-methylthiazol-4-yl)acetate;5-CHLORO-1,2,3,4-TETRAHYDRO-[2,6]NAPHTHYRIDINE;METHYL (2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE;METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE;4-Thiazolecarboxylic acid, 2-amino-5-methyl-, ethyl ester;METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE###72054-60-5
CBNumber
CB5395594
Molecular Formula
C7H10N2O2S
Formula Weight
186.23
MOL File
72054-60-5.mol
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METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE Property

Melting point:
111-113°C
Boiling point:
313.1±22.0 °C(Predicted)
Density 
1.283±0.06 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
pka
3.08±0.10(Predicted)
Appearance
Light yellow to yellow Solid
InChI
InChI=1S/C7H10N2O2S/c1-3-11-6(10)5-4(2)12-7(8)9-5/h3H2,1-2H3,(H2,8,9)
InChIKey
KTGUPAFUVGHOQS-UHFFFAOYSA-N
SMILES
S1C(C)=C(C(OCC)=O)N=C1N
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Safety

HazardClass 
IRRITANT
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
E899568
Product name
Ethyl2-amino-5-methyl-1,3-thiazole-4-carboxylate
Packaging
50mg
Price
$55
Updated
2021/12/16
TRC
Product number
E899568
Product name
Ethyl2-amino-5-methyl-1,3-thiazole-4-carboxylate
Packaging
100mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
W8082
Product name
Ethyl2-amino-5-methylthiazole-4-carboxylate
Packaging
1g
Price
$141
Updated
2021/12/16
Matrix Scientific
Product number
187879
Product name
Ethyl 2-amino-5-methylthiazole-4-carboxylate
Packaging
5g
Price
$898
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CYT0000057
Product name
ETHYL 2-AMINO-5-METHYLTHIAZOLE-4-CARBOXYLATE
Purity
95.00%
Packaging
1G
Price
$1062.6
Updated
2021/12/16
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METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE Chemical Properties,Usage,Production

Synthesis

17356-08-0

609-15-4

72054-60-5

Step 2: Synthesis of ethyl 2-amino-5-methylthiazole-4-carboxylate Thiourea (47 g, 616.83 mmol) was added to a solution of ethyl 2-chloro-3-oxobutanoate (100 g, 577.19 mmol) in ethanol (1000 mL). The resulting mixture was stirred and reacted under reflux conditions for 2 hours. Upon completion of the reaction, the reaction mixture was cooled to room temperature in a water/ice bath. The precipitate was collected by filtration to give 105 g (93% yield) of ethyl 2-amino-5-methylthiazole-4-carboxylate as a light yellow solid.

References

[1] Patent: US2008/139558, 2008, A1. Location in patent: Page/Page column 51

METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE manufacturers

Career Henan Chemical Co
Product
METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE 72054-60-5
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg; 10kg; 100kg
Release date
2019-08-30

72054-60-5, METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATERelated Search:

METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE SPECS AB-601/30964063 ETHYL 2-AMINO-4,5,6,7-TETRAHYDRO-1,3-BENZOTHIAZOLE-4-CARBOXYLATE ETHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE Methyl 2-amino-4-(2-methoxy-2-oxoethyl)thiazole-5-carboxylate hydrochloride

  • METHYL (2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE
  • METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE
  • 5-CHLORO-1,2,3,4-TETRAHYDRO-[2,6]NAPHTHYRIDINE
  • methyl 2-(2-amino-5-methylthiazol-4-yl)acetate
  • METHYL 2-(2-AMINO-5-METHYL-1,3-THIAZOL-4-YL)ACETATE###72054-60-5
  • 2-amino-5-ethoxycarbonyl-4-methylthiazole
  • 4-Thiazolecarboxylic acid, 2-amino-5-methyl-, ethyl ester
  • 72054-60-5