ChemicalBook > CAS DataBase List > 4-(TERT-BUTYL)-2,6-DIMETHYLANILINE

4-(TERT-BUTYL)-2,6-DIMETHYLANILINE

Product Name
4-(TERT-BUTYL)-2,6-DIMETHYLANILINE
CAS No.
42014-60-8
Chemical Name
4-(TERT-BUTYL)-2,6-DIMETHYLANILINE
Synonyms
4-(TERT-BUTYL)-2,6-DIMETHYLANILINE;2,6-Dimethyl- 4-tert-butyl-aniline;4-(tert-Butyl)-2,6-dimethylaniline 98%;Benzenamine, 4-(1,1-dimethylethyl)-2,6-dimethyl-;2-Amino-5-(tert-butyl)-m-xylene, 4-(tert-Butyl)-2,6-xylidine
CBNumber
CB5426584
Molecular Formula
C12H19N
Formula Weight
177.29
MOL File
42014-60-8.mol
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4-(TERT-BUTYL)-2,6-DIMETHYLANILINE Property

Melting point:
29-29.5 °C
Boiling point:
96 °C
Density 
0.9321 g/cm3(Temp: 25 °C)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
4.63±0.10(Predicted)
Appearance
Colorless to light yellow Liquid
CAS DataBase Reference
42014-60-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
20/21/22-36/37/38-36
Safety Statements 
26-36/37/39
RIDADR 
2810
Hazard Note 
Irritant
HazardClass 
6.1
PackingGroup 
HS Code 
2921420090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P311Call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
B129615
Product name
4-(tert-Butyl)-2,6-dimethylaniline
Packaging
1g
Price
$220
Updated
2021/12/16
Matrix Scientific
Product number
081190
Product name
4-tert-Butyl-2,6-dimethylaniline
Purity
97%
Packaging
5g
Price
$350
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB147124
Product name
4-(tert-Butyl)-2,6-dimethylaniline
Packaging
10g
Price
$381
Updated
2021/12/16
Matrix Scientific
Product number
081190
Product name
4-tert-Butyl-2,6-dimethylaniline
Purity
97%
Packaging
10g
Price
$588
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0026586
Product name
4-(TERT-BUTYL)-2,6-DIMETHYLANILINE
Purity
95.00%
Packaging
100MG
Price
$594.96
Updated
2021/12/16
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4-(TERT-BUTYL)-2,6-DIMETHYLANILINE Chemical Properties,Usage,Production

Synthesis

6279-89-6

42014-60-8

5-(tert-butyl)-1,3-dimethyl-2-nitrobenzene (15 g, 0.072 mol) was mixed with stannous chloride (41 g, 0.216 mol) in 300 mL of ethanol and the reaction was heated at reflux for 24 hours. Upon completion of the reaction, the reaction mixture was cooled to room temperature and neutralized by slowly adding aqueous potassium hydroxide solution under stirring. Subsequently, the reaction mixture was extracted with ethyl acetate to separate the organic phase. The organic phase was purified by column chromatography to give 7 g of 4-tert-butyl-2,6-dimethyl-aniline ([Intermediate 8-b]) in 58% yield.

References

[1] Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1987, p. 1 - 8
[2] Chemistry Letters, 1983, p. 1373 - 1374
[3] Journal of Chemical Research - Part S, 2000, # 6, p. 290 - 291
[4] Patent: KR2015/124677, 2015, A. Location in patent: Paragraph 0291; 0296-0299
[5] Organometallics, 2010, vol. 29, # 24, p. 6723 - 6731

4-(TERT-BUTYL)-2,6-DIMETHYLANILINE Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(TERT-BUTYL)-2,6-DIMETHYLANILINE Suppliers

Specs
Tel
--
Fax
--
Email
info@specs.net
Country
The Netherlands
ProdList
6833
Advantage
70
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View Lastest Price from 4-(TERT-BUTYL)-2,6-DIMETHYLANILINE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4-tert-Butyl-2,6-dimethylaniline 42014-60-8
Price
US $3.90-5.90/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-06-13