Dimethyl 5-aminoisophthalate
- Product Name
- Dimethyl 5-aminoisophthalate
- CAS No.
- 99-27-4
- Chemical Name
- Dimethyl 5-aminoisophthalate
- Synonyms
- 5-AIPA-DME;LABOTEST-BB LT00080775;3,5-Dicarbomethoxyaniline;5-AMINO-METHYL ISOPHATHALATE;DIMETHYL 5-AMINOISOPHTHALATE;dimethyl-5-amino isopthalate;5-AMINO-DIMETHYL ISO-PHTHALATE;5-AMINO-DIMETHYL ISOPHATHALATE;DIMETHYL 5-AMINOISOPHTHALATE HCl;Dimethyl 5-aminoisophthalate 98%
- CBNumber
- CB5445316
- Molecular Formula
- C10H11NO4
- Formula Weight
- 209.2
- MOL File
- 99-27-4.mol
Dimethyl 5-aminoisophthalate Property
- Melting point:
- 178-181 °C (lit.)
- Boiling point:
- 178-180 °C
- Density
- 1.248±0.06 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Soluble in Chloroform.
- pka
- 2.31±0.10(Predicted)
- form
- powder to crystal
- color
- White to Light yellow to Light orange
- BRN
- 2116565
- InChI
- InChI=1S/C10H11NO4/c1-14-9(12)6-3-7(10(13)15-2)5-8(11)4-6/h3-5H,11H2,1-2H3
- InChIKey
- DEKPYXUDJRABNK-UHFFFAOYSA-N
- SMILES
- C1(C(OC)=O)=CC(N)=CC(C(OC)=O)=C1
- CAS DataBase Reference
- 99-27-4(CAS DataBase Reference)
- NIST Chemistry Reference
- 5-Aminoisophthalic acid, dimethyl ester(99-27-4)
- EPA Substance Registry System
- 1,3-Benzenedicarboxylic acid, 5-amino-, dimethyl ester (99-27-4)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D142158
- Product name
- Dimethyl 5-aminoisophthalate
- Purity
- 98%
- Packaging
- 25g
- Price
- $61.2
- Updated
- 2025/07/31
- Product number
- D142158
- Product name
- Dimethyl 5-aminoisophthalate
- Purity
- 98%
- Packaging
- 100g
- Price
- $188
- Updated
- 2025/07/31
- Product number
- A1586
- Product name
- Dimethyl 5-Aminoisophthalate
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 25g
- Price
- $39
- Updated
- 2025/07/31
- Product number
- A1586
- Product name
- Dimethyl 5-Aminoisophthalate
- Purity
- >98.0%(HPLC)(T)
- Packaging
- 250g
- Price
- $177
- Updated
- 2025/07/31
- Product number
- D492943
- Product name
- Dimethyl 5-Aminoisophthalate
- Packaging
- 1g
- Price
- $45
- Updated
- 2021/12/16
Dimethyl 5-aminoisophthalate Chemical Properties,Usage,Production
Chemical Properties
Solid
Uses
Dimethyl 5-aminoisophthalate is a important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. Hexagonal assembly of double helices of luminescent calcium 5-aminoisophthalate coordination polymer leaves enough room for the formation of loosely held water pipes, which could be dehydrated at very low temperatures.
Synthesis
13290-96-5
99-27-4
The general procedure for the synthesis of dimethyl 5-aminoisophthalate from dimethyl 5-nitroisophthalate was as follows: the hydrogenation of nitroaromatics was carried out in a PTFE-lined stainless steel autoclave equipped with a manometer and a magnetic stirrer. The procedure was as follows: 0.5 mmol of dimethyl 5-nitroisophthalate, 15 mol% of Co/C-N-X catalyst, 100 μL of n-hexadecane, and 2 mL of solvent were mixed and added to the reactor at room temperature. The autoclave was purged several times using hydrogen to remove air. After the preset reaction temperature was reached, the hydrogen pressure was adjusted to 1 MPa and a magnetic stirrer (600 r/min) was activated to start the reaction. Upon completion of the reaction, the solid catalyst in the reaction solution was separated by centrifugation. The products in the reaction solution were quantitatively analyzed and structurally identified by gas chromatography-mass spectrometry (Shimadzu GCMS-QP5050A, equipped with a 0.25 mm × 30 m DB-WAX capillary column). Nuclear magnetic resonance hydrogen (1H NMR) and carbon (13C NMR) spectral data were acquired on a Bruker Avance III 400 spectrometer using CDCl3 or DMSO-d6 as solvents and tetramethylsilane (TMS) as an internal standard. Pure products from amplification experiments were obtained by fast column chromatography (eluent was a solvent mixture of petroleum ether and ethyl acetate) purification.
References
[1] ACS Catalysis, 2015, vol. 5, # 3, p. 1526 - 1529
[2] Journal of the Chemical Society, 1905, vol. 87, p. 1265
[3] Journal fuer Praktische Chemie (Leipzig), 1882, vol. <2> 25, p. 505,515
[4] Australian Journal of Chemistry, 1997, vol. 50, # 12, p. 1159 - 1182
[5] Patent: US2004/82811, 2004, A1
Dimethyl 5-aminoisophthalate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Dimethyl 5-aminoisophthalate manufacturers
- Product
- Dimethyl 5-aminoisophthalate 99-27-4
- Price
- US $111.63/Kg/Drum
- Min. Order
- 25Kg/Drum
- Purity
- 99.00%HPLC
- Supply Ability
- 5tons/month
- Release date
- 2021-09-23
- Product
- Dimethyl 5-aminoisophthalate 99-27-4
- Price
- US $30.00-10.00/kg
- Min. Order
- 10kg
- Purity
- 99%
- Supply Ability
- 100000kg
- Release date
- 2024-08-23
- Product
- Dimethyl 5-aminoisophthalate 99-27-4
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000KG
- Release date
- 2024-08-25