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2-Methyl-3-buten-2-ol

Product Name
2-Methyl-3-buten-2-ol
CAS No.
115-18-4
Chemical Name
2-Methyl-3-buten-2-ol
Synonyms
3-Buten-2-ol, 2-methyl-;Methylbutenol;2-Methylbut-3-en-2-ol;2-METHYL-3-BUTENE-2-OL;2-methylbut-3-en;1,1-DIMETHYLALLYL ALCOHOL;2-Methyl-3-buten-2-ol, 97% 250ML;2-methylbut-;Methyl-3-bute;CH2=CHC(CH3)2OH
CBNumber
CB5462775
Molecular Formula
C5H10O
Formula Weight
86.13
MOL File
115-18-4.mol
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2-Methyl-3-buten-2-ol Property

Melting point:
-43 °C
Boiling point:
98-99 °C (lit.)
Density 
0.824 g/mL at 25 °C (lit.)
vapor pressure 
51 mm Hg ( 25 °C)
refractive index 
n20/D 1.416(lit.)
Flash point:
56 °F
storage temp. 
Store below +30°C.
form 
Liquid
pka
14.56±0.29(Predicted)
color 
Clear colorless to very slightly yellow
PH
9-10 (100g/l, H2O, 20℃)
Odor
at 10.00 % in dipropylene glycol. herbal earthy oily
Odor Type
herbal
explosive limit
1.5-9.4%(V)
BRN 
1698263
LogP
0.66 at 25℃
CAS DataBase Reference
115-18-4(CAS DataBase Reference)
NIST Chemistry Reference
3-Buten-2-ol, 2-methyl-(115-18-4)
EPA Substance Registry System
2-Methyl-3-buten-2-ol (115-18-4)
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Safety

Hazard Codes 
F,Xn,F++
Risk Statements 
11-22-36
Safety Statements 
16-26-36
RIDADR 
UN 1987 3/PG 2
WGK Germany 
1
RTECS 
EM9472000
Autoignition Temperature
380 °C
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29052990
Toxicity
LD50 orally in Rabbit: 1800 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.41089
Product name
2-Methyl-3-buten-2-ol
Purity
for synthesis
Packaging
250ML
Price
$39
Updated
2024/03/01
Sigma-Aldrich
Product number
8.41089
Product name
2-Methyl-3-buten-2-ol
Purity
for synthesis
Packaging
1L
Price
$94.1
Updated
2024/03/01
Sigma-Aldrich
Product number
136816
Product name
2-Methyl-3-buten-2-ol
Purity
98%
Packaging
1l
Price
$58.74
Updated
2024/03/01
TCI Chemical
Product number
M0178
Product name
2-Methyl-3-buten-2-ol
Purity
>97.0%(GC)
Packaging
25mL
Price
$55
Updated
2024/03/01
TCI Chemical
Product number
M0178
Product name
2-Methyl-3-buten-2-ol
Purity
>97.0%(GC)
Packaging
500mL
Price
$253
Updated
2024/03/01
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2-Methyl-3-buten-2-ol Chemical Properties,Usage,Production

Chemical Properties

Clear colourless to very slightly yellow liquid.
Powerful, oily-herbaceous, somewhat earthy, fungus-like odor of considerable radiance. Poor tenacity.

Uses

2-Methyl-3-buten-2-ol was used to study the kinetics of the gas-phase reaction of OH radicals with 3-methyl-2-butenal.

Uses

2-Methyl-3-buten-2-ol may be used as an analytical reference standard for the determination of the analyte in Humulus Lupulus L. (Hop) and pine-mushroom extracts by chromatography techniques.

Definition

ChEBI: 3-hydroxy-3-methylbut-1-ene is a tertiary alcohol that is 3-methylbut-1-ene carrying a hydroxy substituent at position 3. It has a role as a fragrance, a pheromone, a plant metabolite and an animal metabolite. It is a tertiary alcohol and an olefinic compound. It derives from a hydride of a 3-methylbut-1-ene.

Application

This unsaturated alcohol has found a little use in perfume compositions, mainly in the reconstruction of Lavender and Lavandin oils, etc.
It is occasionally used as a powerful additive in soap and detergent perfumes, but it needs skilful blending and firm fixation in order to control its odor to an acceptable level.

Production Methods

2-Methyl-3-buten-2-ol can be produced from Vinyl magnesium bromide and Acetone by Grignard reaction.

General Description

Colorless liquid.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

An unsaturated aliphatic/alcohol. The unsaturated aliphatic hydrocarbons are generally much more reactive than the alkanes, which are saturated aliphatic hydrocarbons. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides.

Health Hazard

Harmful if inhaled or swallowed. Material is irritating to mucous membrane and upper respiratory tract.

Fire Hazard

Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back.

2-Methyl-3-buten-2-ol Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methyl-3-buten-2-ol Suppliers

Changzhou Fourman Chemical Co., Ltd.
Tel
0519-89882557 13912311481
Fax
0519-8988-2559
Email
fourmanchem@163.com
Country
China
ProdList
64
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60
SiChuang NanBu Honesty Technology Co., Ltd.
Tel
0838-5675166 15883665058
Fax
0838-5675535
Email
nbcxkj@126.com
Country
China
ProdList
667
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55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
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61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12390
Advantage
60
JinYan Chemicals(ShangHai) Co.,Ltd.
Tel
13817811078
Fax
86-021-50426522,50426273
Email
sales@jingyan-chemical.com
Country
China
ProdList
9976
Advantage
60
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
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View Lastest Price from 2-Methyl-3-buten-2-ol manufacturers

Changzhou Xuanming Pharmaceutical Technology Co., Ltd.
Product
2-Methyl-3-buten-2-ol 115-18-4
Price
US $60.00-280.00/ml
Min. Order
1ml
Purity
99
Supply Ability
1200
Release date
2024-10-25
Career Henan Chemical Co
Product
2-Methyl-3-buten-2-ol 115-18-4
Price
US $7.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2019-12-31

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