ETHYL (DIPHENYLMETHYLSILYL)ACETATE
- Product Name
- ETHYL (DIPHENYLMETHYLSILYL)ACETATE
- CAS No.
- 13950-57-7
- Chemical Name
- ETHYL (DIPHENYLMETHYLSILYL)ACETATE
- Synonyms
- ethyl (methyldiphenylsilyl)acetate;ETHYL (DIPHENYLMETHYLSILYL)ACETATE;2-(Methyldiphenylsilyl)acetic acid ethyl ester
- CBNumber
- CB5497193
- Molecular Formula
- C17H20O2Si
- Formula Weight
- 284.425
- MOL File
- 13950-57-7.mol
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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Chemical Properties,Usage,Production
Physical properties
clear to light yellow liquids.
Uses
vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.
Preparation
whereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.
ETHYL (DIPHENYLMETHYLSILYL)ACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
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ETHYL (DIPHENYLMETHYLSILYL)ACETATE Suppliers
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51471
- Advantage
- 80
13950-57-7, ETHYL (DIPHENYLMETHYLSILYL)ACETATERelated Search:
PHENYLTRIMETHYLSILANE
ETHYL (DIPHENYLMETHYLSILYL)ACETATE
(TRIMETHYLSILYL)ACETIC ACID
DIMETHYLPHENYLSILYLACETIC ACID
2-(METHYLDIPHENYLSILYL)ETHANOL
Diphenylsilane
2-(Trimethylsilyl)ethanol
METHYL (TRIMETHYLSILYL)ACETATE
DIMETHYLDIPHENYLSILANE
Ethyl (trimethylsilyl)acetate