METHYL (TRIMETHYLSILYL)ACETATE

Product Name: METHYL (TRIMETHYLSILYL)ACETATE
CAS No.: 2916-76-9
Chemical Name: METHYL (TRIMETHYLSILYL)ACETATE
Synonyms: Methyl 2-(triMethylsilyl)acetate;METHYLTRIMETHYLSILICATE;METHYL (TRIMETHYLSILYL)ACETATE;Methyl (trimethylsilyl)acetate,98%;Trimethylsilylacetic acid methyl ester;2-(Trimethylsilyl)acetic acid methyl ester;Acetic acid, 2-(trimethylsilyl)-, methyl ester;2-[Dimethyl(methyl)silyl]acetic acid methyl ester
CBNumber: CB7704732
Molecular Formula: C6H14O2Si
Formula Weight: 146.26
MOL File: 2916-76-9.mol

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METHYL (TRIMETHYLSILYL)ACETATE Property

Boiling point:: 38-39 °C13 mm Hg(lit.)
Density: 0.891 g/mL at 25 °C(lit.)
refractive index: n20/D 1.414(lit.)
Flash point:: 91 °F
storage temp.: Flammables area
Specific Gravity: 0.890
Hydrolytic Sensitivity: 2: reacts with aqueous acid
BRN: 1098961

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Safety

Hazard Codes: F,Xi
Risk Statements: 11-36/37/38
Safety Statements: 16-26-36
RIDADR: UN 3272 3/PG 3
WGK Germany: 3
F: 10-21
TSCA: No
HazardClass: 3.1
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 234966
Product name: Methyl trimethylsilylacetate
Purity: 97%
Packaging: 5g
Price: $79.6
Updated: 2023/01/07

TRC

Product number: M322525
Product name: Methyl2-(Trimethylsilyl)acetate
Packaging: 1g
Price: $45
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK283775
Product name: Methyl trimethylsilylacetate
Purity: 98%
Packaging: 5g
Price: $67
Updated: 2021/12/16

AK Scientific

Product number: 8796AJ
Product name: Methyl trimethylsilylacetate
Packaging: 5g
Price: $117
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK283775
Product name: Methyl trimethylsilylacetate
Purity: 98%
Packaging: 25g
Price: $192
Updated: 2021/12/16

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METHYL (TRIMETHYLSILYL)ACETATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl 2-(Trimethylsilyl)acetate is a useful compound in the organic synthesis.

General Description

Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.

Purification Methods

Methyl trimethylsilylacetate [2916-76-9] M 146.3, b 65-68o/50mm, d 4 0.89. Dissolve it in Et2O, shaken with 1M HCl, wash with H2O, aqueous saturated NaHCO3, H2O again, and dry it (a precipitate may be formed in the NaHCO3 solution and should be drawn off and discarded). The solvent is distilled off, and the residue is fractionated through a good column. IR (CHCl3) max 1728cm1 . [Fessenden & Fessenden J Org Chem 32 3535 1967, Matsuda et al. J Org Chem 45 237 1980, Beilstein 4 III 1855, 4 IV 3974 for Et ester.]

METHYL (TRIMETHYLSILYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL (TRIMETHYLSILYL)ACETATE Suppliers

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View Lastest Price from METHYL (TRIMETHYLSILYL)ACETATE manufacturers

Career Henan Chemical Co

Product: Methyl (trimethylsilyl)acetate 2916-76-9
Price: US $1.00/g
Min. Order: 1g
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2019-12-28

2916-76-9, METHYL (TRIMETHYLSILYL)ACETATERelated Search:

TERT-BUTYL TRIMETHYLSILYLACETATE (TRIMETHYLSILYL)ACETIC ACID Trimethylsilyl acetate ETHYL TRIMETHYLSILYLDIFLUOROACETATE TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE ETHYL (DIPHENYLMETHYLSILYL)ACETATE 2,2-DIFLUORO-2-(TRIMETHYLSILYL)ACETIC ACID PROPYL ESTER METHYL 2-(TRIMETHYLSILYL)PROPIONATE METHYL TRIMETHYLSILYLDIFLUOROACETATE (S)-4-((R)-2-BENZYLOXY-TRIDECYL)-3-HEXYL-3-TRIMETHYLSILANYL-OXETAN-2-ONE METHYL (1-TRIMETHYLSILYL)ACRYLATE ETHYL 2-BROMO-2-(1,1,1-TRIMETHYLSILYL)ACETATE METHYL (TRIMETHYLSILYL)ACETATE Ethyl (trimethylsilyl)acetate

METHYLTRIMETHYLSILICATE

METHYL (TRIMETHYLSILYL)ACETATE

Methyl 2-(triMethylsilyl)acetate

2-(Trimethylsilyl)acetic acid methyl ester

2-[Dimethyl(methyl)silyl]acetic acid methyl ester

Trimethylsilylacetic acid methyl ester

Methyl (trimethylsilyl)acetate,98%

Acetic acid, 2-(trimethylsilyl)-, methyl ester

2916-76-9

2961-76-9

CH33SiCH2CO2CH3

Esters

Organic Building Blocks

Building Blocks

C6 to C7

Carbonyl Compounds

C6 to C7

Carbonyl Compounds

Esters