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METHYL (TRIMETHYLSILYL)ACETATE

Product Name
METHYL (TRIMETHYLSILYL)ACETATE
CAS No.
2916-76-9
Chemical Name
METHYL (TRIMETHYLSILYL)ACETATE
Synonyms
Methyl 2-(triMethylsilyl)acetate;METHYLTRIMETHYLSILICATE;METHYL (TRIMETHYLSILYL)ACETATE;Methyl (trimethylsilyl)acetate,98%;Trimethylsilylacetic acid methyl ester;2-(Trimethylsilyl)acetic acid methyl ester;Acetic acid, 2-(trimethylsilyl)-, methyl ester;2-[Dimethyl(methyl)silyl]acetic acid methyl ester
CBNumber
CB7704732
Molecular Formula
C6H14O2Si
Formula Weight
146.26
MOL File
2916-76-9.mol
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METHYL (TRIMETHYLSILYL)ACETATE Property

Boiling point:
38-39 °C13 mm Hg(lit.)
Density 
0.891 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.414(lit.)
Flash point:
91 °F
storage temp. 
Flammables area
form 
liquid
Specific Gravity
0.890
Hydrolytic Sensitivity
2: reacts with aqueous acid
BRN 
1098961
InChI
InChI=1S/C6H14O2Si/c1-8-6(7)5-9(2,3)4/h5H2,1-4H3
InChIKey
JIHUZDFFYVRXKP-UHFFFAOYSA-N
SMILES
C(OC)(=O)C[Si](C)(C)C
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Safety

Hazard Codes 
F,Xi
Risk Statements 
11-36/37/38
Safety Statements 
16-26-36
RIDADR 
UN 3272 3/PG 3
WGK Germany 
3
F 
10-21
TSCA 
No
HazardClass 
3.1
PackingGroup 
II
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
234966
Product name
Methyl trimethylsilylacetate
Purity
97%
Packaging
5g
Price
$79.6
Updated
2023/01/07
TRC
Product number
M322525
Product name
Methyl2-(Trimethylsilyl)acetate
Packaging
1g
Price
$45
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK283775
Product name
Methyl trimethylsilylacetate
Purity
98%
Packaging
5g
Price
$67
Updated
2021/12/16
AK Scientific
Product number
8796AJ
Product name
Methyl trimethylsilylacetate
Packaging
5g
Price
$117
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK283775
Product name
Methyl trimethylsilylacetate
Purity
98%
Packaging
25g
Price
$192
Updated
2021/12/16
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METHYL (TRIMETHYLSILYL)ACETATE Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl 2-(Trimethylsilyl)acetate is a useful compound in the organic synthesis.

General Description

Methyl trimethylsilylacetate on reaction with lithium diisopropylamide in THF at -78°C yields methyl lithiotrimethylsilylacetate. It also undergoes Peterson olefination to yield mainly Z-isomers of steroid 17β-side chain methyl acrylates.

Purification Methods

Methyl trimethylsilylacetate [2916-76-9] M 146.3, b 65-68o/50mm, d 4 0.89. Dissolve it in Et2O, shaken with 1M HCl, wash with H2O, aqueous saturated NaHCO3, H2O again, and dry it (a precipitate may be formed in the NaHCO3 solution and should be drawn off and discarded). The solvent is distilled off, and the residue is fractionated through a good column. IR (CHCl3) max 1728cm1 . [Fessenden & Fessenden J Org Chem 32 3535 1967, Matsuda et al. J Org Chem 45 237 1980, Beilstein 4 III 1855, 4 IV 3974 for Et ester.]

METHYL (TRIMETHYLSILYL)ACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METHYL (TRIMETHYLSILYL)ACETATE manufacturers

Career Henan Chemical Co
Product
Methyl (trimethylsilyl)acetate 2916-76-9
Price
US $1.00/g
Min. Order
1g
Purity
Min98% HPLC
Supply Ability
g/kg/ton
Release date
2019-12-28

2916-76-9, METHYL (TRIMETHYLSILYL)ACETATERelated Search:

TERT-BUTYL TRIMETHYLSILYLACETATE (TRIMETHYLSILYL)ACETIC ACID Trimethylsilyl acetate ETHYL TRIMETHYLSILYLDIFLUOROACETATE TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE ETHYL (DIPHENYLMETHYLSILYL)ACETATE 2,2-DIFLUORO-2-(TRIMETHYLSILYL)ACETIC ACID PROPYL ESTER METHYL 2-(TRIMETHYLSILYL)PROPIONATE METHYL TRIMETHYLSILYLDIFLUOROACETATE (S)-4-((R)-2-BENZYLOXY-TRIDECYL)-3-HEXYL-3-TRIMETHYLSILANYL-OXETAN-2-ONE METHYL (1-TRIMETHYLSILYL)ACRYLATE ETHYL 2-BROMO-2-(1,1,1-TRIMETHYLSILYL)ACETATE METHYL (TRIMETHYLSILYL)ACETATE Ethyl (trimethylsilyl)acetate

  • METHYLTRIMETHYLSILICATE
  • METHYL (TRIMETHYLSILYL)ACETATE
  • Methyl 2-(triMethylsilyl)acetate
  • 2-(Trimethylsilyl)acetic acid methyl ester
  • 2-[Dimethyl(methyl)silyl]acetic acid methyl ester
  • Trimethylsilylacetic acid methyl ester
  • Methyl (trimethylsilyl)acetate,98%
  • Acetic acid, 2-(trimethylsilyl)-, methyl ester
  • 2916-76-9
  • 2961-76-9
  • CH33SiCH2CO2CH3
  • Esters
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  • Building Blocks
  • C6 to C7
  • Carbonyl Compounds
  • C6 to C7
  • Carbonyl Compounds
  • Esters