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TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE

Product Name
TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE
CAS No.
66406-43-7
Chemical Name
TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE
Synonyms
REVBFXGFKCMPSR-UHFFFAOYSA-N;t-Butyl 2-Chloro-2-trimethylsilylacetate;TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE;Acetic acid, 2-chloro-2-(trimethylsilyl)-, 1,1-dimethylethyl ester;tert-Butyl-2-chloro-2-trimethylsilylacetate**CUSTOMSYNTHESISPLEASEASK**
CBNumber
CB5730395
Molecular Formula
C9H19ClO2Si
Formula Weight
222.78
MOL File
66406-43-7.mol
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TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE Property

Boiling point:
221.2±20.0 °C(Predicted)
Density 
0.976±0.06 g/cm3(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
ORS0001583
Product name
T-BUTYL 2-CHLORO-2-TRIMETHYLSILYLACETATE
Purity
95.00%
Packaging
5MG
Price
$503.03
Updated
2021/12/16
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TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE Chemical Properties,Usage,Production

Application

Tert-butyl-2-chloro-2-trimethylsilylacetate can olefinate enolizable ketones via the Peterson enolation reaction to generate functionalized tetrasubstituted olefins (α,β-unsaturated esters).

Preparation

Tert-butyl-2-chloro-2-trimethylsilylacetate is prepared from t-Butyl Chloroacetate by sequential reaction with Lithium  Diisopropylamide and Chlorotrimethylsilane followed by aqueous workup and distillation.

storage

As this material is an activated alkyl halide, it must be considered a  potential alkylating agent and lachrymator and handled with care and suitable protective clothing (e.g.  gloves) in a fume hood.

TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE Suppliers

China 2 United Kingdom 2 Global 4
Chempro Tech Co., Ltd.
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China
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Guangzhou WeiBo Chemical Co., Ltd.
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weibochem@163.com
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China
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6187
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Fluorochem Ltd
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vernam@fluorochem.co.uk
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United Kingdom
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Fluorochem Ltd.
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enquiries@fluorochem.co.uk
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United Kingdom
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66406-43-7, TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATERelated Search:

Ethyl (trimethylsilyl)acetate 2-(Trimethylsilyl)ethanol 1-CHLOROETHYLTRIMETHYLSILANE Chloromethyltrimethylsilane METHYL (TRIMETHYLSILYL)ACETATE Isopropyl chloroacetate tert-Butyl chloroacetate TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE TERT-BUTYL TRIMETHYLSILYLACETATE (TRIMETHYLSILYL)ACETIC ACID

  • TERT-BUTYL-2-CHLORO-2-TRIMETHYLSILYLACETATE
  • tert-Butyl-2-chloro-2-trimethylsilylacetate**CUSTOMSYNTHESISPLEASEASK**
  • t-Butyl 2-Chloro-2-trimethylsilylacetate
  • REVBFXGFKCMPSR-UHFFFAOYSA-N
  • Acetic acid, 2-chloro-2-(trimethylsilyl)-, 1,1-dimethylethyl ester
  • 66406-43-7