ChemicalBook > CAS DataBase List > 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine

4,4'-Bis(methoxycarbonly)-2,2'-bipyridine

Product Name: 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine
CAS No.: 71071-46-0
Chemical Name: 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine
Synonyms: Nsc297840;4-Bis(methoxycarbonly)-2;4,4′-Dimethoxycarbonyl-2,2′-bipyridine;4,4'-bis(carbomethoxy)-2,2'-bipyridine;4,4'-bis(methoxycarbonly)-2,2'-bipyridine;4,4'-BIS(METHOXYCARBONYL)-2,2'-BIPYRIDINE;Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate;Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate >2,2'-Bipyridine-4,4'-dicarboxylic acid dimethyl ester;2,2'-Bipyridine-4,4'-biscarboxylic acid dimethyl ester
CBNumber: CB5511651
Molecular Formula: C14H12N2O4
Formula Weight: 272.26
MOL File: 71071-46-0.mol

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4,4'-Bis(methoxycarbonly)-2,2'-bipyridine Property

Melting point:: 208.0 to 212.0 °C
Boiling point:: 440.8±45.0 °C(Predicted)
Density: 1.254±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Room Temperature
form: powder to crystal
pka: 1.85±0.30(Predicted)
color: White to Almost white
InChI: InChI=1S/C14H12N2O4/c1-19-13(17)9-3-5-15-11(7-9)12-8-10(4-6-16-12)14(18)20-2/h3-8H,1-2H3
InChIKey: HBWBVIDKBKOVEX-UHFFFAOYSA-N
SMILES: C1(C2=NC=CC(C(OC)=O)=C2)=NC=CC(C(OC)=O)=C1
CAS DataBase Reference: 71071-46-0(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 37/38-41
Safety Statements: 26-39
WGK Germany: 3
HS Code: 29333990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 742481
Product name: Dimethyl 2,2′-bipyridine-4,4′-dicarboxylate
Purity: ≥98.0% (HPLC)
Packaging: 100mg
Price: $105
Updated: 2025/07/31

Sigma-Aldrich

Product number: 742481
Product name: Dimethyl 2,2′-bipyridine-4,4′-dicarboxylate
Purity: ≥98.0% (HPLC)
Packaging: 500mg
Price: $436
Updated: 2023/06/20

TCI Chemical

Product number: D4635
Product name: Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate
Purity: >98.0%(T)
Packaging: 1g
Price: $101
Updated: 2025/07/31

TCI Chemical

Product number: D4635
Product name: Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate
Purity: >98.0%(T)
Packaging: 5g
Price: $335
Updated: 2025/07/31

TRC

Product number: D472748
Product name: Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate
Packaging: 250mg
Price: $75
Updated: 2021/12/16

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4,4'-Bis(methoxycarbonly)-2,2'-bipyridine Chemical Properties,Usage,Production

Uses

4,4'-Bis(methoxycarbonyl)-2,2'-bipyridine is a chemical reaction reagent or organic synthesis intermediate that can be used as a ligand in cross-coupling reactions, binding to metal ions and forming complexes. 4,4'-Bis(methoxycarbonyl)-2,2'-bipyridine has a constant value that maximizes the yield of the reaction and has luminescence, which can be used for voltammetry studies. The transfer of the chromophore or the catalyst can be optimized using this product. 4,4'-Bis(methoxycarbonyl)-2,2'-bipyridine provides a method for cross-coupling reactions using electrochemical studies and dichroism.

Synthesis

67-56-1

6813-38-3

71071-46-0

General procedure for the synthesis of methyl 2,2'-bipyridine-4,4'-dicarboxylate from methanol and 2,2'-bipyridine-4,4'-dicarboxylic acid: 2,2'-Bipyridine-4,4'-dicarboxylic acid (2.00 g, 8.10 mmol) was suspended in methanol (150 mL), and thionyl chloride (1492 μL, 20.48 mmol) was slowly added dropwise. The reaction mixture was stirred under reflux conditions overnight. Upon completion of the reaction, the solvent was removed by distillation under reduced pressure. The residue was partitioned between dichloromethane (100 mL) and water (100 mL). The organic phase was washed three times with saturated aqueous sodium bicarbonate and dried over anhydrous sodium sulfate. Finally, the solvent was removed by reduced pressure distillation to give the white solid product methyl 2,2'-bipyridine-4,4'-dicarboxylate (2.00 g, 90% yield).

References

[1] Journal of the American Chemical Society, 2007, vol. 129, # 18, p. 5919 - 5925
[2] Tetrahedron Asymmetry, 2013, vol. 24, # 8, p. 515 - 525
[3] Inorganic Chemistry, 2018, vol. 57, # 15, p. 9316 - 9326
[4] Dalton Transactions, 2018, vol. 47, # 37, p. 13081 - 13087
[5] Journal of the American Chemical Society, 2016, vol. 138, # 51, p. 16815 - 16826

4,4'-Bis(methoxycarbonly)-2,2'-bipyridine Preparation Products And Raw materials

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View Lastest Price from 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine manufacturers

HANGZHOU HAILAN CHEMICAL CO.,LTD.

Product: 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine 71071-46-0
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 2000KGS
Release date: 2025-10-24

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4,4'-Bis(methoxycarbonly)-2,2'-bipyridine 71071-46-0
Price: US $1.10-9.90/kg
Min. Order: 100kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-08-14

Shanghai UCHEM Inc.

Product: Dimethyl 2,2'-bipyridine-4,4'-dicarboxylate 71071-46-0
Price: US $17.00-81.00/g
Min. Order: 5g
Purity: 0.98
Supply Ability: 25kg
Release date: 2024-07-09

71071-46-0, 4,4'-Bis(methoxycarbonly)-2,2'-bipyridineRelated Search:

Methyl anthranilate 2,2'-Bipyridine Dimethyl phthalate Dimethyl ether Methyl benzoate Dimethyl sebacate ETHANE Methyl formate Dimethyl fumarate 4,4'-Bipyridine DIPIPERIDINOMETHANE Dimethyl sulfoxide N,N-Dimethylformamide Methylparaben Dimethyl carbonate AcidEster DIBUTYL 2,2'-BIPYRIDINE-4,4'-DICARBOXYLATE Methyl chloroformate

4,4'-bis(methoxycarbonly)-2,2'-bipyridine

2,2'-Bipyridinyl-4,4'-dicarboxylic acid dimethyl ester

2,2'-Bipyridine-4,4'-bis(carboxylic acid methyl) ester

2,2'-Bipyridine-4,4'-biscarboxylic acid dimethyl ester

2,2'-Bipyridine-4,4'-dicarboxylic acid dimethyl ester

2,2'-Bipyridine-4,4'-diylbis(formic acid methyl) ester

Nsc297840

[2,2′-Bipyridine]-4,4′-dicarboxylic acid 4,4′-dimethyl ester

4,4′-Dimethoxycarbonyl-2,2′-bipyridine

Dimethyl [2,2'-bipyridine]-4,4'-dicarboxylate≥ 98% (HPLC)

4,4'-bis(carbomethoxy)-2,2'-bipyridine

2-(4-methoxycarbonyl-2-pyridinyl)-4-pyridinecarboxylic acid methyl ester

Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate &gt

4,4'-Bis(methoxycarbonly)-2,2'-bipyridine ISO 9001：2015 REACH

4-Bis(methoxycarbonly)-2

Dimethyl 2,2'-Bipyridine-4,4'-dicarboxylate

4,4'-BIS(METHOXYCARBONYL)-2,2'-BIPYRIDINE

(2,2')BIPYRIDINYL-4,4'-DICARBOXYLIC ACID DIMETHYL ESTER

Dimethyl [2,2′-bipyridine]-4,4′-dicarboxylate, CAS 71071-46-0

71071-46-0