PHENYLTHIOPHOSPHONIC DICHLORIDE Property

Melting point:

76-77 °C

Boiling point:

270 °C

Density 

1,4 g/cm³

refractive index 

1.6178-1.6182

Flash point:

118℃

form 

clear liquid

color 

Colorless to Light orange to Yellow

Water Solubility 

1.522g/L(23 ºC)

CAS DataBase Reference

3497-00-5(CAS DataBase Reference)

EPA Substance Registry System

Phosphonothioic dichloride, P-phenyl- (3497-00-5)

Safety

Hazard Codes 

C

Risk Statements 

34-20/21/22

Safety Statements 

26-36/37/39-45

RIDADR 

2799

HS Code 

2931.90.6000

HazardClass 

8

PackingGroup 

II

Hazardous Substances Data

3497-00-5(Hazardous Substances Data)

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P363Wash contaminated clothing before reuse.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

PHENYLTHIOPHOSPHONIC DICHLORIDE Chemical Properties,Usage,Production

Uses

Phenylthiophosphonic dichloride is a thiophosphonate and has been used to prepare high-refractive-index materials.

General Description

Colorless liquid with unpleasant acrid pungent odor. Corrodes metals slowly.

Air & Water Reactions

Flammable. Decomposes to give hydrochloric acid in water, although this reaction is slow. The reaction becomes vigorous if the water is hot.

Reactivity Profile

PHENYLTHIOPHOSPHONIC DICHLORIDE is water reactive. Incompatible with strong oxidizing agents, alcohols, amines, alkali. Contact with active metals generates flammable hydrogen gas. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Health Hazard

CORROSIVE and/or TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Fire will produce irritating, corrosive and/or toxic gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Contact with molten substance may cause severe burns to skin and eyes. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

EXCEPT FOR ACETIC ANHYDRIDE (UN1715), THAT IS FLAMMABLE, some of these materials may burn, but none ignite readily. May ignite combustibles (wood, paper, oil, clothing, etc.). Substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. Flammable/toxic gases may accumulate in confined areas (basement, tanks, hopper/tank cars, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. Substance may be transported in a molten form.

Safety Profile

A corrosive. When heated to decomposition it emits toxic vapors of SOx and POx.