ChemicalBook > CAS DataBase List > ALUMINUM TERT-BUTOXIDE

ALUMINUM TERT-BUTOXIDE

Product Name
ALUMINUM TERT-BUTOXIDE
CAS No.
556-91-2
Chemical Name
ALUMINUM TERT-BUTOXIDE
Synonyms
ALUMINUM T-BUTOXIDE;uminum tert-butoxide;Alumiuniumt-butoxide,;Aluminium t-Butoxide;ALUMINUM TERT-BUTOXIDE;ALUMINUM TERT-BUTYLATE;tri-tert-butoxyaluminum;ALUMINUM(III)T-BUTOXIDE;ALUMINUM TRI-T-BUTOXIDE;ALUMINIUM TERT-BUTOXIDE
CBNumber
CB5682825
Molecular Formula
C12H27AlO3
Formula Weight
246.32
MOL File
556-91-2.mol
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ALUMINUM TERT-BUTOXIDE Property

Melting point:
241°C
Boiling point:
156°C 2mm
Density 
1,0251 g/cm3
Flash point:
>65°C
solubility 
Very soluble in organic solvents like alcohols, benzene, toluene and xylene.
form 
Powder
color 
White to Gray
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
Merck 
14,333
BRN 
4148229
Stability:
Stable, but air and moisture sensitive. Incompatible with acids, strong oxidizing agents. Highly flammable.
CAS DataBase Reference
556-91-2(CAS DataBase Reference)
EPA Substance Registry System
2-Propanol, 2-methyl-, aluminum salt (556-91-2)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
8-16-26-36/37/39-45
RIDADR 
UN 2925 4.1/PG 2
WGK Germany 
3
F 
8-21
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
III
HS Code 
29051990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H228Flammable solid

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
235849
Product name
Aluminum tert-butoxide
Purity
technical grade
Packaging
10g
Price
$43.62
Updated
2024/03/01
Sigma-Aldrich
Product number
235849
Product name
Aluminum tert-butoxide
Purity
technical grade
Packaging
50g
Price
$303
Updated
2024/03/01
TCI Chemical
Product number
A0804
Product name
Aluminum tert-Butoxide
Purity
>98.0%(T)
Packaging
5g
Price
$49
Updated
2024/03/01
Alfa Aesar
Product number
089891
Product name
Aluminum tert-butoxide, 97%
Packaging
5g
Price
$39.65
Updated
2024/03/01
Alfa Aesar
Product number
089891
Product name
Aluminum tert-butoxide, 97%
Packaging
25g
Price
$179
Updated
2024/03/01
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ALUMINUM TERT-BUTOXIDE Chemical Properties,Usage,Production

Chemical Properties

slightly yellow crystalline powder

Uses

Aluminum tert-butoxide is utilized as a reagent in the Oppenauer oxidation of alcohols to ketones. It is also used in Meerwein-Ponndorf-Verley reduction of ketones. It is actively involved in the preparation of 1,1,2-triethoxyethene by reacting with 1,1,2,2-tetraethoxyethane followed by the elimination of alcohol.

Uses

Reagent for oxidation of alcohols to ketones; in dealcoholation of orthoesters.

Purification Methods

Crystallise it from *C6H6 and it sublimes it at 180o. [McElvain & Davie J Am Chem Soc 73 1400 1951, Beilstein 1 IV 1612.]

ALUMINUM TERT-BUTOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ALUMINUM TERT-BUTOXIDE manufacturers

Career Henan Chemical Co
Product
ALUMINUM TERT-BUTOXIDE) 556-91-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%-99.9%
Supply Ability
200kg
Release date
2020-01-10

556-91-2, ALUMINUM TERT-BUTOXIDERelated Search:

tert-Butylhydroquinone Potassium tert-butoxide Tetraethyl orthosilicate tert-Butyllithium Aluminum chloride p-Toluenesulfonic acid Aluminum Stearate Sodium tert-butoxide Aluminium isopropoxide Triethylaluminum Butylate tert-Butanol ALUMINUM TERT-BUTOXIDE Lithium tri-tert-butoxyaluminum hydride LITHIUM TRIS[(3-ETHYL-3-PENTYL)OXY]ALUMINOHYDRIDE LITHIUM TRI-TERT-BUTOXYALUMINODEUTERIDE LITHIUM TETRA(PERFLUORO-T-BUTOXY)ALUMINATE Lithium hydridotris(tert-butoxy)aluminate, nominally 1M in THF, packaged under Argon in resealable ChemSeal^t bottles

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  • Homogeneous Catalysts
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  • Catalysts for Organic Synthesis
  • Titanium Alkoxides, etc. (Homogeneous Catalysts)
  • Classes of Metal Compounds
  • Typical Metal Compounds
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