(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

Product Name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
CAS No.: 12257-42-0
Chemical Name: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER
Synonyms: bis[(2,3,5,6-B7;-chlorodirhodium;4-norbornadiene)dirhodium(I);Dichloro(norbornadiene)dirhodium;NORBORNADIENE RHODIUM(1) CHLORIDE;Chloronorbornadiene rhodium dimer;Bis[chloro(norbornadiene)rhodium];BIS(NORBORNADIENE-MU-CHLORORHODIUM);Dichlorobis(norbornadiene)dirhodium;Norbornadiene rhodium chloride dimer
CBNumber: CB5697449
Molecular Formula: C14H16Cl2Rh28*
Formula Weight: 460.99
MOL File: 12257-42-0.mol

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Property

Melting point:: 239-241°C (dec.)
storage temp.: 2-8°C
solubility: sol chloroform and benzene; insol ether and light petroleum
form: Powder
color: yellow to orange
Water Solubility: insoluble in water
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3

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Safety

Hazard Codes: Xi,Xn
Risk Statements: 36/37/38
Safety Statements: 37/39-26
WGK Germany: 3
F: 10-21
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 683167
Product name: Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Packaging: 2g
Price: $647
Updated: 2024/03/01

Sigma-Aldrich

Product number: 249939
Product name: Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Purity: 96%
Packaging: 500mg
Price: $481
Updated: 2024/03/01

TCI Chemical

Product number: N0453
Product name: Norbornadiene Rhodium(I) Chloride Dimer
Packaging: 100mg
Price: $70
Updated: 2024/03/01

Alfa Aesar

Product number: 010467
Product name: Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
Packaging: 0.5g
Price: $528
Updated: 2023/06/20

Alfa Aesar

Product number: 010467
Product name: Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min
Packaging: 1g
Price: $1024
Updated: 2023/06/20

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Chemical Properties,Usage,Production

Chemical Properties

mustard yellow crystals

Uses

Di-μ-chlorobis(norbornadiene)dirhodium(I) is used as catalysts in olefin hydroformylation, olefin hydrogenation and olefin isomerization

Preparation

Bis(bicyclo[2.2.1]hepta-2,5- diene)dichlorodirhodium is prepared by reacting rhodium(III) Chloride and bicyclo[2.2.1]hepta-2,5-diene in aq ethanol, when shaken for 2 days, give a yellow deposit.

Purification Methods

It recrystallises from hot CHCl3/pet ether as fine crystals soluble in CHCl3 and *C6H6 but is almost insoluble in Et2O or pet ether. [Abel et al. J Chem Soc 3178 1959.]

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Preparation Products And Raw materials

Raw materials

Preparation Products

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER Suppliers

Americas 1 Belgium 3 Canada 1 China 124 Europe 1 Germany 5 India 5 Japan 4 Spain 1 Switzerland 1 United Kingdom 4 United States 28 Global 178

Panjin Greenchem Technology Co., Ltd.

Tel: 13121959385 13121959385
Email: chemrocking@bjgreenchem.com
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J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
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Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
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Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
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Email: Sales-CN@TCIchemicals.com
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Beijing HwrkChemical Technology Co., Ltd

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Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
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Energy Chemical

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Fax: 021-58436166
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Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
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Email: isenchem@163.com
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Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
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ProdList: 9809
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Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
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ProdList: 19179
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View Lastest Price from (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (BICYCLO2.2.1HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER 12257-42-0
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Longyan Tianhua Biological Technology Co., Ltd

Product: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER 12257-42-0
Price: US $20.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-11-11

Career Henan Chemical Co

Product: (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER 12257-42-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2019-07-02

12257-42-0, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMERRelated Search:

GRUBBS CATALYST 2ND GENERATION Ruthenium acetylacetonate Benzeneruthenium(II) chloride dimer [1,3-Bis(diphenylphosphino)propane]nickel(II) chloride Tris(triphenylphosphine)ruthenium(II) chloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Dichloro(p-cymene)ruthenium(II) dimer Rhodium(II) acetate dimer Ruthenium(II) chloride mesitylene dimer Tris(triphenylphosphine)rhodiu Rhodium(III) 2,4-pentanedionate Bis(tricyclohexylphosphine)nickel(II) chloride, 99% Benzylidene-bis(tricyclohexylphosphine)dichlororuthenium 172222-30-9 EXO-NORBORNEOL 2,5-Norbornadiene Rhodium (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

NORBORNADIENE RHODIUM(1) CHLORIDE

NORBORNADIENE RHODIUM(I) CHLORIDE DIMER

RHODIUM(I) CHLORIDE 2,5-NORBORNADIENE COMPLEX DIMER

Chloronorbornadienerhodium(I)dimer,99%

di-ae-chlorobis(norbornadiene) dirhodium(i)

bis[(2,3,5,6-eta)-bicyclo[2.2.1]hepta-2,5-diene]di-mu-chlorodirhodium

BICYCLO(2.2.1)HEPTA-2,5-DIENE-RHODIUM(I)

Chloro(norbornadiene)rhodium(I), dimer, 99.9%

Di-μ-chlorobis(norbornadiene)dirhodium(I), Rh 44% min

4-norbornadiene)dirhodium(I)

DI-M-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)

Chloronorbornadiene rhodium dimer

2,5-Norbornadiene-rhodium(I) chloride dimer, Chloro(2,5-norbornadiene)rhodium(I) dimer, Rhodium(I) chloride 2,5-Norbornadiene complex dimer

Norbornadiene rhodium chloride dimer

Di-μ-chlorobis(norbornadiene) dirhodiuM(I)

Chloronorbornadiene rhodium(I) dimer, [Rh(NBD)Cl]2

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 96%

Bicyclo[2.2.1]hepta-2,5-diene-rhodium chloride dimer

2,5-NORBORNADIENE-RHODIUM(I) CHLORIDE DIMER

Di-^m-chlorobis(norbornadiene)dirhodium(I), Rh 44% min

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER

BICYCLO[2.2.1]HEPTA-2,5-DIENE-RHODIUM(I) CHLORIDE DIMER

BIS(NORBORNADIENE-MU-CHLORORHODIUM)

CHLORO(2,5-NORBORNADIENE)RHODIUM(I) DIMER

CHLORO(NORBORNADIENE)RHODATE (I) DIMER

CHLORONORBORNADIENE RHODIUM(I) DIMER

DI-MU-CHLOROBIS(NORBORNADIENE) DIRHODIUM(I)

Di-mu-chlorobis(norbornadiene)dirhodium(I), Rh 44% min

bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorodirhodium

Chloronorbornadiene rhodiuM(I) diMer, 99% 100MG

Bis((mu-chloro)(norbornadiene)rhodium)

Bis(chloro(eta4-norbornadiene)rhodium)

Bis(mu-chloro)bis(norbornadiene)dirhodium

Bis(mu-chloro)bis[(norbornadiene)rhodium]

Bis[chloro(norbornadiene)rhodium]

Dichloro(norbornadiene)dirhodium

Dichlorobis(norbornadiene)dirhodium

Di-mu-chlorobis(eta4-norbornadiene)dirhodium(I)

Chloronorbornadiene rhodiuM(I) diMer,98% [Rh(NBD)Cl]2

Bis(norbornadiene-mu-chlororhodium) Chloronorbornadiene Rhodium(I) Dimer

Di-Mu-chlorobis(norbornadiene)dirhodiuM

Chloronorbornadiene rhodium(Ⅰ) dimer

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER ISO 9001：2015 REACH

Chloronorbornadienerhodium(I) Dimer, Rh 44.0%

bis[(2,3,5,6-η)-bicyclo[2.2.1]hepta-2,5-diene]di-μ-chlorod...

)-bicyclo[2.2.1]hepta-2,5-diene]di-BC

bis[(2,3,5,6-B7

-chlorodirhodium

Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer 12257-42-0

12257-42-0

RhNBDCl2

C14H16Cl2Rh2

C14H16Cl2Rh

RhClC7H82

2C7H82ClRh

Catalysts for Organic Synthesis

Rh (Rhodium) Compounds

Transition Metal Compounds