Synthesis
ChemicalBook > CAS DataBase List > POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

Synthesis
Product Name
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
CAS No.
166328-09-2
Chemical Name
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
Synonyms
Potassium (3,5-bis(trifluoromethyl);POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&;[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE;Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate;potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui;Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%;Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%;potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
CBNumber
CB5731640
Molecular Formula
C8H3BF9K
Formula Weight
320
MOL File
166328-09-2.mol
More
Less

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Property

Melting point:
>300℃
storage temp. 
Inert atmosphere,Room Temperature
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
2931900090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
571563
Product name
Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging
1g
Price
$59.8
Updated
2023/06/20
Alfa Aesar
Product number
H53113
Product name
Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging
1g
Price
$49.9
Updated
2023/06/20
Alfa Aesar
Product number
H53113
Product name
Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging
5g
Price
$205
Updated
2023/06/20
TRC
Product number
P699195
Product name
Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging
500mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
102348
Product name
Potassium 3,5-bistrifluoromethylphenyltrifluoroborate
Purity
>95%
Packaging
1g
Price
$83
Updated
2021/12/16
More
Less

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Chemical Properties,Usage,Production

Synthesis

A solution of 3,5-bis(triflfluoromethyl)phenylboronic acid (10 g, 38.8 mmol) in methanol (15 mL) was added to an aqueous solution of KHF2 (4.5 M, 26 mL, 117 mmol) at room temperature. A heavy precipitate was deposited. The resulting suspension was stirred 148 MODERN ORGANIC SYNTHESIS IN THE LABORATORYfor 1 h at room temperature, and the precipitated product was collected and washed with methanol. Recrystallization from a minimum amount of acetone produced 11 g (89%) of potassium 3,5-bis(triflfluoromethyl)phenyltriflfluoroborate. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.

Uses

Thos chemical has been used for inserting a 3,5-bis(trifluoromethyl)phenyl group into the position of a halogen or triflate group of various arenes and various heterocycles in Pd-catalyzed Suzuli-Miyaura cross-coupling reactions.

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Suppliers

BoroChem SAS
Tel
--
Fax
--
Email
info@borochem.fr
Country
France
ProdList
852
Advantage
46

166328-09-2, POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATERelated Search:


  • potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
  • Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%
  • Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%
  • Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&
  • Potassium (3,5-bis(trifluoromethyl)
  • Borate(1-), [3,5-bis(trifluoromethyl)phenyl]trifluoro-, potassium (1:1), (T-4)-
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
  • [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide
  • potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui
  • 166328-09-2
  • C8H3BF9K
  • CF32C6H3BF3K
  • Organometallic Reagents
  • Trifluoroborate Salts
  • Boronic Acids and Derivatives
  • Aryl
  • Aryl
  • Boronic Acids and Derivatives
  • Trifluoroborate Salts
  • blocks
  • Trifluoroborates
  • Molander Ates
  • Organoborons
  • Aryl Trifluoroborate Salts
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • Trifluoroborate Salts