Synthesis
ChemicalBook > CAS DataBase List > POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

Synthesis
Product Name
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
CAS No.
166328-09-2
Chemical Name
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
Synonyms
Potassium (3,5-bis(trifluoromethyl);POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&;[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE;Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate;potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui;Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%;Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%;potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
CBNumber
CB5731640
Molecular Formula
C8H3BF9K
Formula Weight
320
MOL File
166328-09-2.mol
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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Property

Melting point:
>300℃
storage temp. 
Inert atmosphere,Room Temperature
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
571563
Product name
Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging
1g
Price
$59.8
Updated
2023/06/20
Alfa Aesar
Product number
H53113
Product name
Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging
1g
Price
$49.9
Updated
2023/06/20
Alfa Aesar
Product number
H53113
Product name
Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
Packaging
5g
Price
$205
Updated
2023/06/20
TRC
Product number
P699195
Product name
Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
Packaging
500mg
Price
$75
Updated
2021/12/16
Matrix Scientific
Product number
102348
Product name
Potassium 3,5-bistrifluoromethylphenyltrifluoroborate
Purity
>95%
Packaging
1g
Price
$83
Updated
2021/12/16
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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Chemical Properties,Usage,Production

Synthesis

A solution of 3,5-bis(triflfluoromethyl)phenylboronic acid (10 g, 38.8 mmol) in methanol (15 mL) was added to an aqueous solution of KHF2 (4.5 M, 26 mL, 117 mmol) at room temperature. A heavy precipitate was deposited. The resulting suspension was stirred 148 MODERN ORGANIC SYNTHESIS IN THE LABORATORYfor 1 h at room temperature, and the precipitated product was collected and washed with methanol. Recrystallization from a minimum amount of acetone produced 11 g (89%) of potassium 3,5-bis(triflfluoromethyl)phenyltriflfluoroborate. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.

Uses

Thos chemical has been used for inserting a 3,5-bis(trifluoromethyl)phenyl group into the position of a halogen or triflate group of various arenes and various heterocycles in Pd-catalyzed Suzuli-Miyaura cross-coupling reactions.

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Suppliers

Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71

166328-09-2, POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATERelated Search:


  • potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
  • Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%
  • Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%
  • Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&
  • Potassium (3,5-bis(trifluoromethyl)
  • Borate(1-), [3,5-bis(trifluoromethyl)phenyl]trifluoro-, potassium (1:1), (T-4)-
  • POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
  • [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide
  • potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui
  • 166328-09-2
  • C8H3BF9K
  • CF32C6H3BF3K
  • Organometallic Reagents
  • Trifluoroborate Salts
  • Boronic Acids and Derivatives
  • Aryl
  • Aryl
  • Boronic Acids and Derivatives
  • Trifluoroborate Salts
  • blocks
  • Trifluoroborates
  • Molander Ates
  • Organoborons
  • Aryl Trifluoroborate Salts
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • Trifluoroborate Salts