POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
Synthesis- Product Name
- POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
- CAS No.
- 166328-09-2
- Chemical Name
- POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
- Synonyms
- Potassium (3,5-bis(trifluoromethyl);POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&;[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE;Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate;potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui;Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%;Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%;potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
- CBNumber
- CB5731640
- Molecular Formula
- C8H3BF9K
- Formula Weight
- 320
- MOL File
- 166328-09-2.mol
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Property
- Melting point:
- >300℃
- storage temp.
- Inert atmosphere,Room Temperature
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 571563
- Product name
- Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
- Packaging
- 1g
- Price
- $59.8
- Updated
- 2023/06/20
- Product number
- H53113
- Product name
- Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
- Packaging
- 1g
- Price
- $49.9
- Updated
- 2023/06/20
- Product number
- H53113
- Product name
- Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96%
- Packaging
- 5g
- Price
- $205
- Updated
- 2023/06/20
- Product number
- P699195
- Product name
- Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 102348
- Product name
- Potassium 3,5-bistrifluoromethylphenyltrifluoroborate
- Purity
- >95%
- Packaging
- 1g
- Price
- $83
- Updated
- 2021/12/16
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Chemical Properties,Usage,Production
Synthesis
A solution of 3,5-bis(triflfluoromethyl)phenylboronic acid (10 g, 38.8 mmol) in methanol (15 mL) was added to an aqueous solution of KHF2 (4.5 M, 26 mL, 117 mmol) at room temperature. A heavy precipitate was deposited. The resulting suspension was stirred 148 MODERN ORGANIC SYNTHESIS IN THE LABORATORYfor 1 h at room temperature, and the precipitated product was collected and washed with methanol. Recrystallization from a minimum amount of acetone produced 11 g (89%) of potassium 3,5-bis(triflfluoromethyl)phenyltriflfluoroborate. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.
Uses
Thos chemical has been used for inserting a 3,5-bis(trifluoromethyl)phenyl group into the position of a halogen or triflate group of various arenes and various heterocycles in Pd-catalyzed Suzuli-Miyaura cross-coupling reactions.
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Preparation Products And Raw materials
Raw materials
Preparation Products
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Suppliers
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