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METHYL VALERATE

Product Name
METHYL VALERATE
CAS No.
624-24-8
Chemical Name
METHYL VALERATE
Synonyms
C5;Methyl E;FEMA 2752;Methylvalerat;Valeric acid M;METHYL VALERATE;CH3(CH2)3COOCH3;PENTANOIC METHYL;METHYL N-VALERATE;methylvalerianate
CBNumber
CB5733134
Molecular Formula
C6H12O2
Formula Weight
116.16
MOL File
624-24-8.mol
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METHYL VALERATE Property

Melting point:
-91°C
Boiling point:
128 °C (lit.)
Density 
0.875 g/mL at 25 °C (lit.)
vapor pressure 
19.33hPa at 20℃
FEMA 
2752 | METHYL VALERATE
refractive index 
n20/D 1.397(lit.)
Flash point:
72 °F
storage temp. 
Flammables area
solubility 
5g/l
form 
Liquid
Specific Gravity
0.892 (20/4℃)
color 
Clear colorless
Odor
at 1.00 % in dipropylene glycol. sweet green fruity apple pineapple nutty
Odor Type
fruity
Odor Threshold
0.0022ppm
Water Solubility 
3.5g/L at 20℃
JECFA Number
159
BRN 
1741905
Dielectric constant
4.3(19℃)
LogP
2.25 at 25℃
CAS DataBase Reference
624-24-8(CAS DataBase Reference)
EPA Substance Registry System
Methyl valerate (624-24-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
10-20-2017/10/20
Safety Statements 
16-7/9-2007/9/16
RIDADR 
UN 3272 3/PG 2
WGK Germany 
2
RTECS 
YV7750500
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29156000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H317May cause an allergic skin reaction

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
94560
Product name
Methyl valerate
Purity
analytical standard
Packaging
1ml
Price
$56.6
Updated
2024/03/01
Sigma-Aldrich
Product number
148997
Product name
Methyl valerate
Purity
99%
Packaging
100ml
Price
$69.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W275204
Product name
Methyl valerate
Purity
≥99%, FG
Packaging
1kg
Price
$129
Updated
2023/01/07
Sigma-Aldrich
Product number
W275204
Product name
Methyl valerate
Purity
≥99%, FG
Packaging
4kg
Price
$467
Updated
2023/01/07
Sigma-Aldrich
Product number
W275204
Product name
Methyl valerate
Purity
≥99%, FG
Packaging
9kg
Price
$888
Updated
2023/01/07
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METHYL VALERATE Chemical Properties,Usage,Production

Description

Methyl pentanoate, commonly known as methyl valerate, is the methyl ester of pentanoic acid (valeric acid) with a fruity odor.
Methyl pentanoate is commonly used in fragrances, beauty care, soap, laundry detergents at levels of 0.1 – 1 % .
In a very pure form ( greater than 99.5 % ) it is used as a plasticizer in the manufacture of plastics.
It is also used as an insecticide.

Chemical Properties

Methyl valerate has a pungent, green-fruity odor that is apple- and pineapple-like with a corresponding flavor at 1 0 - 5 0 ppm. May be prepared by direct esterification of the valeric acid with methanol in the presence of concentrated H2S04; note: this ester hydrolyzes readily.

Chemical Properties

Methyl valerate has a pungent, green-fruity odor, apple and pineapple-like. It has a similar flavor at 10 to 50 ppm

Chemical Properties

clear colorless liquid

Occurrence

Reported found in small amounts in the essential oil from the fruits of Ananas sativus Schult. Also reported present in apple, coffee, honey, kiwi, melon, papaya, pineapple, strawberry, tea, wine, blackberry, baked potato, olive, starfruit, passion fruit, soursop, Bourbon vanilla, mountain papaya and naranjilla fruit.

Uses

Methyl valerate can be used:

  • In the preparation of lankacidin C 8-valerate.
  • As a reactant to synthesize bis(2,2,2-trifluoroethyl) 2-oxoalkylphosphonates.
  • As a substrate in the fluorination reactions of unactivated C(sp3)H bonds using decatungstate photocatalyst and N-fluorobenzenesulfonimide.

Application

Methyl valerate is primarily used in flavor compositions, although it occasionally finds application in certain phases of perfumery (masking, household products of certain type, etc.).
Its Apple-like character is useful in fruit complexes where diffusive power is desirable (chewing gum, etc.) and it performs very well in Pineapple or fantasy flavors.

Preparation

By direct esterification of valeric acid with methanol in the presence of concentrated H2SO4. Note: This ester hydrolyzes readily

Aroma threshold values

Detection: 20 to 89 ppb

Taste threshold values

Taste characteristics at 20 ppm: sweet, ripe, fruity with sweaty, dairy and cheesy nuance

Synthesis Reference(s)

Journal of the American Chemical Society, 97, p. 1180, 1975 DOI: 10.1021/ja00838a036

General Description

Clear colorless to yellowish oily liquid.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

METHYL VALERATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. METHYL VALERATE reacts with oxidizing agents, bases and acids.

Fire Hazard

METHYL VALERATE is flammable.

Flammability and Explosibility

Flammable

METHYL VALERATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL VALERATE Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
Advantage
57
Tianjin heowns Biochemical Technology Co., Ltd.
Tel
400 638 7771
Email
sales@heowns.com
Country
China
ProdList
14435
Advantage
57
Spectrum Chemical Manufacturing Corp.
Tel
021-021-021-67601398-809-809-809 15221380277
Fax
021-57711696
Email
marketing_china@spectrumchemical.com
Country
China
ProdList
9658
Advantage
60
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
Shanghai civi chemical technology co.,Ltd
Tel
86-21-34053660
Fax
86-21-34053661
Email
sale@labgogo.com
Country
China
ProdList
9865
Advantage
52
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View Lastest Price from METHYL VALERATE manufacturers

Qingdao RENAS Polymer Material Co., Ltd.
Product
Methyl pentanoate 624-24-8
Price
US $0.00/kg
Min. Order
20kg
Purity
99%
Supply Ability
20 tons
Release date
2024-08-19
Hebei Yanxi Chemical Co., Ltd.
Product
METHYL VALERATE 624-24-8
Price
US $60.00-20.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20 tons
Release date
2023-10-11
Hebei Mojin Biotechnology Co., Ltd
Product
methyl valerate 624-24-8
Price
US $100.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
5000KG
Release date
2021-11-25

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