ChemicalBook > CAS DataBase List > 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
- Product Name
- 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
- CAS No.
- 13735-81-4
- Chemical Name
- 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
- Synonyms
- Trimethyl[(1-phenylvinyl)oxy]silane;DK071;α-(trimethylsiloxy)styrene;à-(trimethylsiloxy)styrene;α-(Trimethylsilyloxy)styrene;ALPHA-(TRIMETHYLSILOXY)STYRENE;1-Phenyl-1-trimethylsiloxyethene;ALPHA-(TRIMETHYLSILYLOXY)STYRENE;(1-phenylvinyl)oxyTrimethylsilane;trimethyl(1-phenylethenoxy)silane
- CBNumber
- CB5740196
- Molecular Formula
- C11H16OSi
- Formula Weight
- 192.33
- MOL File
- 13735-81-4.mol
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Property
- Melting point:
- 122-123 °C
- Boiling point:
- 88-89 °C/11 mmHg (lit.)
- Density
- 0.938 g/mL at 25 °C (lit.)
- vapor density
- >1 (vs air)
- refractive index
- n20/D 1.502(lit.)
- Flash point:
- 174 °F
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Specific Gravity
- 0.938
- Water Solubility
- Reacts with water.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- BRN
- 1306914
- CAS DataBase Reference
- 13735-81-4(CAS DataBase Reference)
- EPA Substance Registry System
- Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 235040
- Product name
- 1-Phenyl-1-trimethylsiloxyethylene
- Purity
- 98%
- Packaging
- 5g
- Price
- $108
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 235040
- Product name
- 1-Phenyl-1-trimethylsiloxyethylene
- Purity
- 98%
- Packaging
- 25g
- Price
- $483
- Updated
- 2024/03/01
TCI Chemical
- Product number
- P1280
- Product name
- 1-Phenyl-1-trimethylsilyloxyethylene
- Purity
- >95.0%(GC)
- Packaging
- 10mL
- Price
- $164
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L05308
- Product name
- 1-Phenyl-1-trimethylsiloxyethylene, 97%
- Packaging
- 1g
- Price
- $22.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L05308
- Product name
- 1-Phenyl-1-trimethylsiloxyethylene, 97%
- Packaging
- 5g
- Price
- $78.65
- Updated
- 2024/03/01
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Chemical Properties,Usage,Production
Uses
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.
Uses
1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:
- β-amino ketones in water via Mannich-type reaction
- cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction
General Description
1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Preparation Products And Raw materials
Raw materials
Preparation Products
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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Suppliers
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View Lastest Price from 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE manufacturers
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1-Phenyl-1-trimethylsiloxyethylene 98% 13735-81-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
Career Henan Chemical Co
- Product
- 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 13735-81-4
- Price
- US $9.80/KG
- Min. Order
- 1g
- Purity
- ≥99%
- Supply Ability
- 100kg
- Release date
- 2020-01-10
13735-81-4, 1-PHENYL-1-TRIMETHYLSILOXYETHYLENERelated Search:
ISOPROPENYLOXYTRIMETHYLSILANE
VINYLOXYTRIMETHYLSILANE
(3,4-DIHYDRO-1-NAPHTHYLOXY)TRIMETHYLSILANE
DIMETHYLETHOXYSILANE
DIMETHYLMETHOXYSILANE
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
Ethoxytrimethylsilane
BENZYLOXYTRIMETHYLSILANE
METHOXYTRIMETHYLSILANE