CHLOROMETHYL PHENYL SULFIDE
- Product Name
- CHLOROMETHYL PHENYL SULFIDE
- CAS No.
- 7205-91-6
- Chemical Name
- CHLOROMETHYL PHENYL SULFIDE
- Synonyms
- (phenylthio)methyl chloride;Chlorothioanisole;α-Chlorothioanisole;ALPHA-CHLOROTHIOANISOLE;α-Chlorothioanisole >[(chloromethyl)thio]benzene;CHLOROMETHYL PHENYL SULFIDE;chloromethylsulfanylbenzene;chloromethylephenyl sulfide;CHLOROMETHYL PHENYL SULPHIDE
- CBNumber
- CB5755381
- Molecular Formula
- C7H7ClS
- Formula Weight
- 158.65
- MOL File
- 7205-91-6.mol
CHLOROMETHYL PHENYL SULFIDE Property
- Boiling point:
- 66 °C/0.2 mmHg (lit.)
- Density
- 1.184 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.594(lit.)
- Flash point:
- 214 °F
- storage temp.
- 2-8°C
- solubility
- sol most organic solvents; insol H2O
- form
- Liquid
- color
- Clear colorless to pale yellow
- Sensitive
- Stench
- BRN
- 1617369
- InChIKey
- LLSMWLJPWFSMCP-UHFFFAOYSA-N
- CAS DataBase Reference
- 7205-91-6(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 216631
- Product name
- Chloromethyl phenyl sulfide
- Purity
- 97%
- Packaging
- 5g
- Price
- $58.56
- Updated
- 2024/03/01
- Product number
- 216631
- Product name
- Chloromethyl phenyl sulfide
- Purity
- 97%
- Packaging
- 25g
- Price
- $158.4
- Updated
- 2024/03/01
- Product number
- C0912
- Product name
- α-Chlorothioanisole
- Purity
- >95.0%(GC)
- Packaging
- 5g
- Price
- $54
- Updated
- 2024/03/01
- Product number
- C0912
- Product name
- α-Chlorothioanisole
- Purity
- >95.0%(GC)
- Packaging
- 25g
- Price
- $158
- Updated
- 2024/03/01
- Product number
- C382070
- Product name
- Chloromethyl phenyl sulfide
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
CHLOROMETHYL PHENYL SULFIDE Chemical Properties,Usage,Production
Uses
Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1
Uses
Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.
Synthesis
The two most convenient methods of chloromethyl phenyl sulfide are the reaction of Thioanisole with Sulfuryl Chloride and the reaction of Thiophenol with bromochloromethane using 1,8-Diazabicyclo[5.4.0]undec-7-ene or an alkali metal hydroxide as the base.
storage
Chloromethyl phenyl sulfideshould be handled in a well-ventilated fume hood and kept cooled. Freshly prepared material can be stored at 0-5 °C without any appreciable decomposition. It is advisable to use freshly prepared or distilled material for reactions.
Purification Methods
Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.]
CHLOROMETHYL PHENYL SULFIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from CHLOROMETHYL PHENYL SULFIDE manufacturers
- Product
- CHLOROMETHYL PHENYL SULFIDE 7205-91-6
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27
- Product
- CHLOROMETHYL PHENYL SULFIDE 7205-91-6
- Price
- US $3.00/KG
- Min. Order
- 1KG
- Purity
- 99
- Supply Ability
- 100kg
- Release date
- 2019-07-10