(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

Reactions

Product Name: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
CAS No.: 164931-83-3
Chemical Name: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE
Synonyms: (R,R)Jacbosen;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan;RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride;(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride;（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1R,2R)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE;(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride;(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent;(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent
CBNumber: CB5761982
Molecular Formula: C36H52ClCrN2O2
Formula Weight: 632.27
MOL File: 164931-83-3.mol

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Property

Melting point:: >350 °C(lit.)
form: Powder
color: brown

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 531944
Product name: (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride
Packaging: 1g
Price: $85.3
Updated: 2024/03/01

Sigma-Aldrich

Product number: 531944
Product name: (R,R)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride
Packaging: 5g
Price: $144.6
Updated: 2024/03/01

Strem Chemicals

Product number: 24-0850
Product name: (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
Packaging: 1g
Price: $64
Updated: 2024/03/01

Strem Chemicals

Product number: 24-0850
Product name: (1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
Packaging: 5g
Price: $239
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000040
Product name: (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
Purity: 95.00%
Packaging: 1G
Price: $294
Updated: 2021/12/16

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Chemical Properties,Usage,Production

Reactions

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
Catalyst for copolymerization of CO2 and epoxides.
Catalyst for enantioselective alkylation of tributyltin enolates.
Enantioselective addition of Me2Zn to aldehydes.
Enantioselective intramolecular addition of tertiary enamides to ketones.
Asymmetric iodocyclization.
Catalytic intermolecular linear allylic C-H animation.

Uses

Catalyst used for:

Asymmetric anti-Mannich reactions
Coupling reactions
Ring-opening and Diels-Alder reactions
Allylic C-H oxidation of terminal alkenes

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE Suppliers

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164931-83-3, (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDERelated Search:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE CHROMIUM(II) CHLORIDE Chromium(III) chloride Chromium (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE N-benzylidenecyclohexylamine N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE HYDROCHLORIDE CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE

(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE

（1R,2R）-(－)-〔1，2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride

(1R,2R)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene)]chromium(III)chloride

(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(iii) chloride

(r,r)-n,n'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexan

Chromium,chloro[[2,2'-[(1R,2R)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-

(R,R)Jacbosen

RR,R)-N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride

(R,R)-N,N'-BIs(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent

(R,R)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride Catalytic reagent

(1R,2R)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)chromium(III) chloride

164931-83-3

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Cycloaddition

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

CycloadditionChiral Catalysts, Ligands, and Reagents

Privileged Ligands and Complexes

SALENs