(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

Reaction

Product Name: (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
CAS No.: 219143-92-7
Chemical Name: (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
Synonyms: -bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride;-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride;(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride;(1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE;(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE;(1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chrominum(III)chloride;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))chromium(III)chloride;2,4-ditert-butyl-6-[[(1S,2S)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol;2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol] - trichlorochromium (1:1)
CBNumber: CB7476295
Molecular Formula: C36H52ClCrN2O2
Formula Weight: 632.26
MOL File: 219143-92-7.mol

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(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Property

Melting point:: 250-255 °C(lit.)
form: Powder
color: brown

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 26-36
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H332Harmful if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 24-0851
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
Packaging: 1g
Price: $63
Updated: 2024/03/01

Strem Chemicals

Product number: 24-0851
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
Packaging: 5g
Price: $236
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: OGM0000047
Product name: (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
Purity: 95.00%
Packaging: 1G
Price: $655.85
Updated: 2021/12/16

BLDpharm

Product number: BD212011
Product name: (S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
Purity: 98+%
Packaging: 1g
Price: $45
Updated: 2021/12/16

BLDpharm

Product number: BD212011
Product name: (S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III)chloride
Purity: 98+%
Packaging: 5g
Price: $188
Updated: 2021/12/16

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(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Chemical Properties,Usage,Production

Reaction

Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides.
Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions.
Catalyst for copolymerization of CO2 and epoxides.
Catalyst for enantioselective alkylation of tributyltin enolates.
Enantioselective addition of Me2Zn to aldehydes.
Enantioselective intramolecular addition of tertiary enamides to ketones.
Asymmetric iodocyclization.
Catalytic intermolecular linear allylic C-H animation.
Cocatalyst for enantioselective ring opening of epoxides with fluoride.

Uses

Rosmarinic acid has been used in study to assess its immunomodulatory effect in a murine model of respiratory allergy induced by the Blomia tropicalis (Bt) mite.

General Description

Rosmarinic acid is commonly used in traditional Uighur medicine for treating cancer.

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Suppliers

China 35 Germany 3 Switzerland 1 United Kingdom 1 United States 4 Global 44

J & K SCIENTIFIC LTD.

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View Lastest Price from (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE manufacturers

Career Henan Chemical Co

Product: 2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol] - trichlorochromium (1:1) 219143-92-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98%
Supply Ability: g/kg/ton
Release date: 2020-01-08

219143-92-7, (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDERelated Search:

(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chromium(III) chloride CHROMIUM(II) CHLORIDE (1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))chromium(III)chloride

2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol] - trichlorochromium (1:1)

(1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride

-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride

-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride

Chromium,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-

2,4-ditert-butyl-6-[[[(1S,2S)-2-[(3,5-ditert-butyl-6-oxido-cyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylene]cyclohexa-2,4-dien-1-olate

(1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chrominum(III)chloride

2,4-ditert-butyl-6-[[(1S,2S)-2-[(3,5-ditert-butyl-2-hydroxyphenyl)methylideneamino]cyclohexyl]iminomethyl]phenol

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

(S,S)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride

219143-92-7

C36H52ClCrN2O2

C36H52N2O2CrCl

Cycloaddition

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

CycloadditionChiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands and Complexes

SALENs