(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

Reaction

Product Name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
CAS No.: 135620-04-1
Chemical Name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
Synonyms: (S,S)-Jacbosen;(S,S)-JACOBSEN;(S,S)-Jacobsencat.;JACOBSEN'S CATALYST;(S,S)-JACOBSEN CATALYST;(S,S)-JACOBSEN'S CATALYST;-1,2-cyclohexanediamine]manganese(III);(S,S)-(+)-Jacobsen manganese (III) catalyst;(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
CBNumber: CB0286099
Molecular Formula: C36H52ClMnN2O2
Formula Weight: 635.2
MOL File: 135620-04-1.mol

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Property

Melting point:: 330-332 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
form: Powder
color: brown
InChIKey: VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference: 135620-04-1

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38-20/21/22
Safety Statements: 26-36-36/37/39
WGK Germany: 3
F: 9
HS Code: 29310099

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 404454
Product name: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging: 1g
Price: $34.32
Updated: 2024/03/01

Sigma-Aldrich

Product number: 404454
Product name: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging: 5g
Price: $112.2
Updated: 2024/03/01

Strem Chemicals

Product number: 25-0301
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.
Packaging: 1g
Price: $47
Updated: 2024/03/01

Strem Chemicals

Product number: 25-0301
Product name: (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.
Packaging: 5g
Price: $183
Updated: 2024/03/01

Sigma-Aldrich

Product number: 404454
Product name: (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging: 25g
Price: $663
Updated: 2024/03/01

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties,Usage,Production

Reaction

Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
Asymmetric Kinetic resolution of secondary alcohols in water.
Enantioselective Reformatsky reaction with ketones.

Chemical Properties

dark brown powder

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Suppliers

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View Lastest Price from (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE manufacturers

Career Henan Chemical Co

Product: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE 135620-04-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-01-07

135620-04-1, (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDERelated Search:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Manganese chloride tetrahydrate N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (+/-)-trans-1,2-Diaminocyclohexane CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE N-benzylidenecyclohexylamine (1S,2S)-(+)-1,2-Diaminocyclohexane N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE

(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL

(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL

(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride

(S,S)-Jacobsencat.

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.

(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco

(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo

(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.

(1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕manganese(Ⅲ) Chloride

(1S,2S)-(+)-[1,2-Cyclohexanediammino-N,N'-bis(3,5-di-t-butylsalicylidene)] manganese (III)chloride,98% (S,S)-Jacobsen Cat

(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride

(S,S)-(+)-N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride

(S,S)-Jacbosen

-1,2-cyclohexanediamine]manganese(III)

(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE

JACOBSEN'S CATALYST

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-JACOBSEN CATALYST

(S,S)-JACOBSEN'S CATALYST

(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX

(S,S)-JACOBSEN

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE ISO 9001：2015 REACH

(III)(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)

(S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride

(S,S)-(+)-Jacobsen manganese (III) catalyst

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride

(4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-manganatetracyclo[19.4.0.0?,?.012,1?]pentacosa-1(25),2,10,12,14,16,21,23-octaen-19-ylium chloride

(1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride

(S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride

135620-04-1

CH33C2C6H22OCHN2C6H10MnCl

C36H54Cl3MnN2O2

Chiral Catalysts, Ligands, and Reagents

Asymmetric Synthesis

Epoxidation

Chiral Reagents

Jacobsen Metal

Other Metal