Reaction
ChemicalBook > CAS DataBase List > (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

Reaction
Product Name
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
CAS No.
135620-04-1
Chemical Name
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
Synonyms
(S,S)-Jacbosen;(S,S)-JACOBSEN;(S,S)-Jacobsencat.;JACOBSEN'S CATALYST;(S,S)-JACOBSEN CATALYST;(S,S)-JACOBSEN'S CATALYST;-1,2-cyclohexanediamine]manganese(III);(S,S)-(+)-Jacobsen manganese (III) catalyst;(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
CBNumber
CB0286099
Molecular Formula
C36H52ClMnN2O2
Formula Weight
635.2
MOL File
135620-04-1.mol
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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Property

Melting point:
330-332 °C(lit.)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
brown
InChIKey
VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference
135620-04-1
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-20/21/22
Safety Statements 
26-36-36/37/39
WGK Germany 
3
F 
9
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
404454
Product name
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging
1g
Price
$34.32
Updated
2024/03/01
Sigma-Aldrich
Product number
404454
Product name
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging
5g
Price
$112.2
Updated
2024/03/01
Strem Chemicals
Product number
25-0301
Product name
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.
Packaging
1g
Price
$47
Updated
2024/03/01
Strem Chemicals
Product number
25-0301
Product name
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat.
Packaging
5g
Price
$183
Updated
2024/03/01
Sigma-Aldrich
Product number
404454
Product name
(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
Packaging
25g
Price
$663
Updated
2024/03/01
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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
  2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
  3. Asymmetric Kinetic resolution of secondary alcohols in water.
  4. Enantioselective Reformatsky reaction with ketones.

Chemical Properties

dark brown powder

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Suppliers

Belgium 1 China 84 Germany 3 India 3 Japan 1 Slovakia 1 Switzerland 1 United States 9 Global 103
J & K SCIENTIFIC LTD.
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View Lastest Price from (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE manufacturers

Career Henan Chemical Co
Product
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE 135620-04-1
Price
US $1.00/KG
Min. Order
1KG
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-07

135620-04-1, (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDERelated Search:

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM (III) CHLORIDE (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE Manganese chloride tetrahydrate N,N'-BIS(SALICYLIDENE)-1,2-PROPANEDIAMINE (+/-)-trans-1,2-Diaminocyclohexane CIS/TRANS-DISALYCYLIDENE-1,2-CYCLOHEXYLIDENEDIAMINE N-benzylidenecyclohexylamine (1S,2S)-(+)-1,2-Diaminocyclohexane N,N'-BIS(SALICYLIDENE)ETHYLENEDIAMINE (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE N,N'-BIS(SALICYLIDENE)-1,6-HEXANEDIAMINE

  • (+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
  • (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL
  • (1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride
  • (S,S)-Jacobsencat.
  • (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.
  • (S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco
  • (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo
  • (1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
  • (1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕manganese(Ⅲ) Chloride
  • (1S,2S)-(+)-[1,2-Cyclohexanediammino-N,N'-bis(3,5-di-t-butylsalicylidene)] manganese (III)chloride,98% (S,S)-Jacobsen Cat
  • (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
  • (S,S)-(+)-N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride
  • (S,S)-Jacbosen
  • -1,2-cyclohexanediamine]manganese(III)
  • (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE
  • JACOBSEN'S CATALYST
  • (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • (S,S)-JACOBSEN CATALYST
  • (S,S)-JACOBSEN'S CATALYST
  • (S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX
  • (S,S)-JACOBSEN
  • (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE ISO 9001：2015 REACH
  • (III)(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III)
  • (S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride
  • (S,S)-(+)-Jacobsen manganese (III) catalyst
  • (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
  • (4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-manganatetracyclo[19.4.0.0?,?.012,1?]pentacosa-1(25),2,10,12,14,16,21,23-octaen-19-ylium chloride
  • (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride
  • (S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride
  • 135620-04-1
  • CH33C2C6H22OCHN2C6H10MnCl
  • C36H54Cl3MnN2O2
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • Epoxidation
  • Chiral Reagents
  • Jacobsen Metal
  • Other Metal