(+/-)-trans-1,2-Diaminocyclohexane
- Product Name
- (+/-)-trans-1,2-Diaminocyclohexane
- CAS No.
- 1121-22-8
- Chemical Name
- (+/-)-trans-1,2-Diaminocyclohexane
- Synonyms
- TRANS-1,2-CYCLOHEXANEDIAMINE;Cyclohexanediamine;TIMTEC-BB SBB007639;trans-1,2-Cyclohexanedi;(±)-trans-1,2-DiaminocycL;trans-1,2-Diaminocyclohex;trans-1,2-Cyclohexaneiamine;1,2-TRAMS-DIAMINOCYCLOHEXANE;Diaminocyclohexane,trans-1,2-;1,2-Cyclohexanediamine, trans-
- CBNumber
- CB0247786
- Molecular Formula
- C6H14N2
- Formula Weight
- 114.19
- MOL File
- 1121-22-8.mol
(+/-)-trans-1,2-Diaminocyclohexane Property
- Melting point:
- 14-15 °C(lit.)
- Boiling point:
- 79-81 °C15 mm Hg(lit.)
- Density
- 0.951 g/mL at 25 °C(lit.)
- vapor pressure
- 0.4 mm Hg ( 20 °C)
- refractive index
- n20/D 1.489(lit.)
- Flash point:
- 156 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Liquid
- pka
- 9.94(at 20℃)
- color
- Clear colorless to light yellow
- Water Solubility
- Soluble
- Sensitive
- Air Sensitive
- BRN
- 506142
- InChIKey
- SSJXIUAHEKJCMH-WDSKDSINSA-N
- CAS DataBase Reference
- 1121-22-8(CAS DataBase Reference)
- NIST Chemistry Reference
- trans-1,2-Cyclohexanediamine(1121-22-8)
- EPA Substance Registry System
- 1,2-Cyclohexanediamine, (1R,2R)-rel- (1121-22-8)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-36/37/39-45
- RIDADR
- UN 2735 8/PG 2
- WGK Germany
- 3
- F
- 10-34
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29213000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 270016
- Product name
- (±)-trans-1,2-Diaminocyclohexane
- Purity
- 99%
- Packaging
- 10ml
- Price
- $36.2
- Updated
- 2024/03/01
- Product number
- 270016
- Product name
- (±)-trans-1,2-Diaminocyclohexane
- Purity
- 99%
- Packaging
- 50ml
- Price
- $119
- Updated
- 2024/03/01
- Product number
- C1120
- Product name
- trans-1,2-Cyclohexanediamine
- Purity
- >97.0%(GC)(T)
- Packaging
- 25mL
- Price
- $45
- Updated
- 2024/03/01
- Product number
- C1120
- Product name
- trans-1,2-Cyclohexanediamine
- Purity
- >97.0%(GC)(T)
- Packaging
- 250mL
- Price
- $224
- Updated
- 2024/03/01
- Product number
- L06626
- Product name
- (±)-trans-1,2-Diaminocyclohexane
- Purity
- 99%
- Packaging
- 10g
- Price
- $40.65
- Updated
- 2024/03/01
(+/-)-trans-1,2-Diaminocyclohexane Chemical Properties,Usage,Production
Chemical Properties
clear colorless to light yellow liquid
Uses
(^+)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis.
Uses
(±)-trans-1,2-Diaminocyclohexane was used in the synthesis of macrocyclic [3+3] hexa Schiff base. It was also employed in the synthesis of multidentate ligands, chiral auxiliaries and chiral stationary phases.
General Description
(±)-trans-1,2-Diaminocyclohexane was condensed with aliphatic dialdehydes to form [3+3] or [2+2] macrocyclization products.
Purification Methods
Purify and store the diamine as for the cis-isomer above as it is a strong base and becomes yellow on storage. [Beilstein 13 IV 1.]
(+/-)-trans-1,2-Diaminocyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from (+/-)-trans-1,2-Diaminocyclohexane manufacturers
- Product
- (+/-)-trans-1,2-Diaminocyclohexane 1121-22-8
- Price
- US $20.00-141.00/g
- Min. Order
- 25g
- Purity
- 0.99
- Supply Ability
- 25kg
- Release date
- 2023-12-11
- Product
- (+/-)-trans-1,2-Diaminocyclohexane 1121-22-8
- Price
- US $125.00/kgkg
- Min. Order
- 1kgkg
- Purity
- 0.99
- Supply Ability
- 120
- Release date
- 2023-09-14
- Product
- (+/-)-trans-1,2-Diaminocyclohexane 1121-22-8
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-24