ChemicalBook > CAS DataBase List > (+/-)-trans-1,2-Diaminocyclohexane

(+/-)-trans-1,2-Diaminocyclohexane

Product Name
(+/-)-trans-1,2-Diaminocyclohexane
CAS No.
1121-22-8
Chemical Name
(+/-)-trans-1,2-Diaminocyclohexane
Synonyms
TRANS-1,2-CYCLOHEXANEDIAMINE;Cyclohexanediamine;TIMTEC-BB SBB007639;trans-1,2-Cyclohexanedi;(±)-trans-1,2-DiaminocycL;trans-1,2-Diaminocyclohex;trans-1,2-Cyclohexaneiamine;1,2-TRAMS-DIAMINOCYCLOHEXANE;Diaminocyclohexane,trans-1,2-;1,2-Cyclohexanediamine, trans-
CBNumber
CB0247786
Molecular Formula
C6H14N2
Formula Weight
114.19
MOL File
1121-22-8.mol
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(+/-)-trans-1,2-Diaminocyclohexane Property

Melting point:
14-15 °C(lit.)
Boiling point:
79-81 °C15 mm Hg(lit.)
Density 
0.951 g/mL at 25 °C(lit.)
vapor pressure 
0.4 mm Hg ( 20 °C)
refractive index 
n20/D 1.489(lit.)
Flash point:
156 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid
pka
9.94(at 20℃)
color 
Clear colorless to light yellow
Water Solubility 
Soluble
Sensitive 
Air Sensitive
BRN 
506142
InChIKey
SSJXIUAHEKJCMH-WDSKDSINSA-N
CAS DataBase Reference
1121-22-8(CAS DataBase Reference)
NIST Chemistry Reference
trans-1,2-Cyclohexanediamine(1121-22-8)
EPA Substance Registry System
1,2-Cyclohexanediamine, (1R,2R)-rel- (1121-22-8)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-36/37/39-45
RIDADR 
UN 2735 8/PG 2
WGK Germany 
3
10-34
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29213000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
270016
Product name
(±)-trans-1,2-Diaminocyclohexane
Purity
99%
Packaging
10ml
Price
$36.2
Updated
2024/03/01
Sigma-Aldrich
Product number
270016
Product name
(±)-trans-1,2-Diaminocyclohexane
Purity
99%
Packaging
50ml
Price
$119
Updated
2024/03/01
TCI Chemical
Product number
C1120
Product name
trans-1,2-Cyclohexanediamine
Purity
>97.0%(GC)(T)
Packaging
25mL
Price
$45
Updated
2024/03/01
TCI Chemical
Product number
C1120
Product name
trans-1,2-Cyclohexanediamine
Purity
>97.0%(GC)(T)
Packaging
250mL
Price
$224
Updated
2024/03/01
Alfa Aesar
Product number
L06626
Product name
(±)-trans-1,2-Diaminocyclohexane
Purity
99%
Packaging
10g
Price
$40.65
Updated
2024/03/01
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(+/-)-trans-1,2-Diaminocyclohexane Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

(^+)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis.

Uses

(±)-trans-1,2-Diaminocyclohexane was used in the synthesis of macrocyclic [3+3] hexa Schiff base. It was also employed in the synthesis of multidentate ligands, chiral auxiliaries and chiral stationary phases.

General Description

(±)-trans-1,2-Diaminocyclohexane was condensed with aliphatic dialdehydes to form [3+3] or [2+2] macrocyclization products.

Purification Methods

Purify and store the diamine as for the cis-isomer above as it is a strong base and becomes yellow on storage. [Beilstein 13 IV 1.]

(+/-)-trans-1,2-Diaminocyclohexane Preparation Products And Raw materials

Raw materials

Preparation Products

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(+/-)-trans-1,2-Diaminocyclohexane Suppliers

Jinan Yuantai Pharmaceutical Co.,Ltd
Tel
0531-69959492 15966603228
Fax
0531-69959492
Email
85633700@qq.com
Country
China
ProdList
80
Advantage
55
Chengdu Forest Science and Technology Development Co., Ltd.
Tel
028-87925786 18982287581
Fax
028-61777050
Email
sales@cdforestchem.com
Country
China
ProdList
1374
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15848
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
BeiJing Hwrk Chemicals Limted
Tel
0757-86329057 18501085097
Fax
010-89508210
Email
sales3.gd@hwrkchemical.com
Country
China
ProdList
7583
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
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View Lastest Price from (+/-)-trans-1,2-Diaminocyclohexane manufacturers

Henan Fengda Chemical Co., Ltd
Product
(+/-)-trans-1,2-Diaminocyclohexane 1121-22-8
Price
US $34.00-1.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08
Henan Fengda Chemical Co., Ltd
Product
(R,R)-(-)-1,2-Diaminocyclohexane 1121-22-8
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99
Supply Ability
g-kg-tons,free sample is available
Release date
2024-01-02
Hebei Duling International Trade Co. LTD
Product
Trans-1,2-diaminocyclohexane 1121-22-8
Price
US $35.00-32.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
99 Ton/Tons per Month
Release date
2022-10-14

1121-22-8, (+/-)-trans-1,2-DiaminocyclohexaneRelated Search:


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