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ChemicalBook > CAS DataBase List > (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

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Product Name
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS No.
169689-05-8
Chemical Name
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms
Rostligand;(S,S)-DACH-phenyl ligand;(1S,2S)-(-)-1,2-TROST LIGAND;1S,2S- DHAC-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand;95% (S,S)-DACH-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand 95%;(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp...
CBNumber
CB9299425
Molecular Formula
C44H40N2O2P2
Formula Weight
690.76
MOL File
169689-05-8.mol
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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Property

Melting point:
134-136°C
Boiling point:
817.0±65.0 °C(Predicted)
alpha 
-134o (C=1 IN METHANOL)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
13.35±0.40(Predicted)
form 
Powder
color 
white to off-white
optical activity
[α]20/D -134°, c = 1 in methanol
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
692794
Product name
(S,S)-DACH-phenyl Trost ligand
Purity
95%
Packaging
250mg
Price
$64.8
Updated
2024/03/01
Sigma-Aldrich
Product number
692794
Product name
(S,S)-DACH-phenyl Trost ligand
Purity
95%
Packaging
1g
Price
$374
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
100mg
Price
$41
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
500mg
Price
$161
Updated
2024/03/01
Strem Chemicals
Product number
15-0961
Product name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging
2g
Price
$495
Updated
2024/03/01
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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties,Usage,Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Suppliers

Daicel Chiral Technologies (China)CO.,LTD
Tel
021-50460086-9 15921403865
Fax
+86-21-50462321
Email
han_yajun@dctc.daicel.com
Country
China
ProdList
7195
Advantage
65
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3013
Advantage
58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
Tel
0371-65511006 18625597674
Email
sales@kingorgchem.com
Country
China
ProdList
953
Advantage
55
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
Advantage
62
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3461
Advantage
50
Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9718
Advantage
55
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View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(S,S)-DACH-phenyl Trost ligand 169689-05-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 169689-05-8
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-10

169689-05-8, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)Related Search:


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