(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

Reactions

Product Name: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
CAS No.: 174810-09-4
Chemical Name: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms: (R,R)-TROST LIGAND(NAPHTHYL);(R,R)-DACH-naphthyl Trost ligand;(R,R)-DACH-naphthyl Trost ligand 95%;(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide);(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL);(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide;1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-
CBNumber: CB0725802
Molecular Formula: C52H44N2O2P2
Formula Weight: 790.87
MOL File: 174810-09-4.mol

More

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Property

Melting point:: 224-231 °C
alpha: 69o (C=1 IN METHANOL)
form: Powder
pka: 13.43±0.40(Predicted)
color: off-white
optical activity: [α]20/D +69.0°, c = 1 in methanol
InChIKey: VXFKMKXTPXVEMU-AWSIMMLFSA-N
CAS DataBase Reference: 174810-09-4

More

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3
HS Code: 2931499090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H361Suspected of damaging fertility or the unborn child

H370Causes damage to organs

H372Causes damage to organs through prolonged or repeated exposure

H402Harmful to aquatic life

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692778
Product name: (R,R)-DACH-naphthyl Trost ligand
Purity: 95%
Packaging: 250mg
Price: $80.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692778
Product name: (R,R)-DACH-naphthyl Trost ligand
Purity: 95%
Packaging: 1g
Price: $306.6
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0963
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand
Packaging: 100mg
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0963
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand
Packaging: 500mg
Price: $157
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0963
Product name: (1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand
Packaging: 2g
Price: $499
Updated: 2024/03/01

More

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Usage,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and fluorides nucleophiles.

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Suppliers

China 76 Germany 2 Switzerland 1 Ukraine 1 United Kingdom 1 United States 4 Global 85

LaaJoo

Tel: 021-60702684 18516024827
Email: huang.jiayi@sinocompound.com
Country: China
ProdList: 2603
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

Jia Xing Isenchem Co.,Ltd

Tel: 0573-85285100 18627885956
Fax: 0573-85285100
Email: isenchem@163.com
Country: China
ProdList: 9413
Advantage: 66

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7191
Advantage: 65

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 335
Advantage: 62

Tianjin Derchemist Science & Technology Co., Ltd.

Tel: 22-58627059 13920586291
Fax: 022-58620305
Email: zdcomcon@126.com
Country: China
ProdList: 3461
Advantage: 50

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

More

Less

View Lastest Price from (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: (1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl) 174810-09-4
Price: US $1.00-0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20 tons
Release date: 2020-01-16

Career Henan Chemical Co

Product: (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 174810-09-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg,5kg,100kg
Release date: 2019-08-08

174810-09-4, (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)Related Search:

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-Diphenylethylenediamine (1R,2R)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 1,2-Diaminocyclohexane N,N'-Dimethyl-1,2-cyclohexanediamine TRANS-N,N'-DIACETYLCYCLOHEXANE-1,2-DIAMINE Trans-(1R,2R)N,N'-Dimethyl-cyclohexane-1,2-diamine 2-Diphenylphosphinobenzaldehyde

(R,R)-TROST LIGAND(NAPHTHYL)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(R,R)-DACH-NaphthylTrostLigand

(R,R)-DACH-naphthyl Trost ligand

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94%

(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (R,R)-DACH-Naphthyl Trost Ligand

(1R,2R)-(+)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(R,R)-DACH-Naphthyl Trost Ligand

N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)

1-NaphthalenecarboxaMide,N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

(R,R)-DACH-naphthyl Trost ligand 95%

N,N'-(1R,2R)-Cyclohexane-1,2-diylbis[2-(diphenylphosphanyl)naphthalene-1-carboxamide]

2-diphenylphosphanyl-N-[(1R,2R)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide

(1R,2R)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...

N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide

N,N'-((1R,2R)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)

(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% ?(R,R)-DACH-Naphthyl Trost Ligand

174810-09-4

Chiral Nitrogen

DACH&Trost Series