(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

Reactions

Product Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
CAS No.: 205495-66-5
Chemical Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms: min.94%rostligand(naphthyl);(S,S)TROST LIGAND(NAPHTHYL);(S,S)-DACH-naphthyl Trost Ligand;(S,S)-DACH-naphthyl Trost Ligand 95%;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)
CBNumber: CB4337841
Molecular Formula: C52H44N2O2P2
Formula Weight: 790.88
MOL File: 205495-66-5.mol

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Property

Melting point:: 232-237 °C
alpha: -65.2° (c 1, CH3OH)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 13.43±0.40(Predicted)
color: off-white
optical activity: [α]20/D -66.0°, c = 1 in methanol

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 250mg
Price: $28.12
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 1g
Price: $106.8
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 100mg
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 500mg
Price: $157
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 2g
Price: $499
Updated: 2024/03/01

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Usage,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles.

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Suppliers

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View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Career Henan Chemical Co

Product: 2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide 205495-66-5
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

205495-66-5, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)Related Search:

(1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-Diphenylphosphinobenzaldehyde (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl)

(S,S)TROST LIGAND(NAPHTHYL)

min.94%rostligand(naphthyl)

1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand

(S,S)-DACH-naphthyl Trost Ligand

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94%

(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand

(S,S)-DACH-naphthyl Trost Ligand 95%

(1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane

1-Naphthalenecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...

N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% ?(S,S)-DACH-Naphthyl Trost Ligand

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

205495-66-5

C52H44N2O2P2

Chiral Nitrogen

DACH&Trost Series