(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

Reactions

Product Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
CAS No.: 205495-66-5
Chemical Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms: min.94%rostligand(naphthyl);(S,S)TROST LIGAND(NAPHTHYL);(S,S)-DACH-naphthyl Trost Ligand;(S,S)-DACH-naphthyl Trost Ligand 95%;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)
CBNumber: CB4337841
Molecular Formula: C52H44N2O2P2
Formula Weight: 790.88
MOL File: 205495-66-5.mol

More

Less

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Property

Melting point:: 232-237 °C
alpha: -65.2° (c 1, CH3OH)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 13.43±0.40(Predicted)
color: off-white
optical activity: [α]20/D -66.0°, c = 1 in methanol

More

Less

Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 250mg
Price: $28.12
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 1g
Price: $106.8
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 100mg
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 500mg
Price: $157
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 2g
Price: $499
Updated: 2024/03/01

More

Less

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Usage,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles.

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Suppliers

China 65 Germany 2 India 1 Japan 1 Switzerland 1 Ukraine 1 United Kingdom 1 United States 4 Global 76

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44689
Advantage: 61

China DongFan Chemical Co.,LTD

Tel: 86-0571-85151182
Fax: 86-0571-85151182
Country: China
ProdList: 5691
Advantage: 66

Daicel Chiral Technologies (China)CO.,LTD

Tel: 021-50460086-9 15921403865
Fax: +86-21-50462321
Email: han_yajun@dctc.daicel.com
Country: China
ProdList: 7191
Advantage: 65

Nanjin Cynthia chemicals Technology Co.,Ltd

Tel: 0550-5618439 15951861180
Fax: 0550-5610690
Email: cynthiachem@163.com
Country: China
ProdList: 335
Advantage: 62

Tianjin Derchemist Science & Technology Co., Ltd.

Tel: 22-58627059 13920586291
Fax: 022-58620305
Email: zdcomcon@126.com
Country: China
ProdList: 3401
Advantage: 50

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9891
Advantage: 58

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 18017383231 18017383231
Fax: qq：2817624287
Email: lyh_antaeus@163.com
Country: China
ProdList: 9347
Advantage: 55

Shanghai Incat Chemtech Co.,Ltd.

Tel: 021-57603038 13601791340
Fax: 021-57603057
Email: 307593986@qq.com
Country: China
ProdList: 475
Advantage: 58

More

Less

View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Career Henan Chemical Co

Product: 2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide 205495-66-5
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

205495-66-5, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)Related Search:

(1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-Diphenylphosphinobenzaldehyde (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl)

(S,S)TROST LIGAND(NAPHTHYL)

min.94%rostligand(naphthyl)

1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand

(S,S)-DACH-naphthyl Trost Ligand

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94%

(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand

(S,S)-DACH-naphthyl Trost Ligand 95%

(1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane

1-Naphthalenecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...

N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% ?(S,S)-DACH-Naphthyl Trost Ligand

205495-66-5

C52H44N2O2P2

Chiral Nitrogen

DACH&Trost Series