(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

Reactions

Product Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
CAS No.: 205495-66-5
Chemical Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
Synonyms: min.94%rostligand(naphthyl);(S,S)TROST LIGAND(NAPHTHYL);(S,S)-DACH-naphthyl Trost Ligand;(S,S)-DACH-naphthyl Trost Ligand 95%;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide);(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane;(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl);N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)
CBNumber: CB4337841
Molecular Formula: C52H44N2O2P2
Formula Weight: 790.88
MOL File: 205495-66-5.mol

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Property

Melting point:: 232-237 °C
alpha: -65.2° (c 1, CH3OH)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: Powder
pka: 13.43±0.40(Predicted)
color: off-white
optical activity: [α]20/D -66.0°, c = 1 in methanol

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 250mg
Price: $28.12
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692786
Product name: (S,S)-DACH-naphthyl Trost Ligand
Purity: 95%
Packaging: 1g
Price: $106.8
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 100mg
Price: $43
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 500mg
Price: $157
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0964
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Packaging: 2g
Price: $499
Updated: 2024/03/01

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Chemical Properties,Usage,Production

Reactions

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, and seleno nucleophiles.

Chemical Properties

white to off-white powder

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) Suppliers

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View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) manufacturers

Career Henan Chemical Co

Product: 2-diphenylphosphanyl-N-[(1S,2S)-2-[(2-diphenylphosphanylnaphthalene-1-carbonyl)amino]cyclohexyl]naphthalene-1-carboxamide 205495-66-5
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

205495-66-5, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)Related Search:

(1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 2-Diphenylphosphinobenzaldehyde (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl)

(S,S)TROST LIGAND(NAPHTHYL)

min.94%rostligand(naphthyl)

1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),min.94%(S,S)-DACH-NaphthylTrostLigand

(S,S)-DACH-naphthyl Trost Ligand

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-napthoyl),94%

(1S,2S)-(-)-N,N'-Bis(2-diphenylphosphino-1-napthoyl)-1,2-diaminocyclohexane

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),94% (S,S)-DACH-Naphthyl Trost Ligand

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthaMide)

(1S,2S)-(-)-1,2-DiaMinocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl),(S,S)-DACH-Naphthyl Trost Ligand

(S,S)-DACH-naphthyl Trost Ligand 95%

(1S,2S)-1,2-Bis[[[2-(diphenylphosphino)naphthalen-1-yl]carbonyl]amino]cyclohexane

1-Naphthalenecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosph...

N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)-1-naphthalenecarboxamide

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)-1-naphthamide)

205495-66-5

C52H44N2O2P2

Chiral Nitrogen

DACH&Trost Series