(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

ChemicalBook > CAS DataBase List > (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

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Product Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
CAS No.: 169689-05-8
Chemical Name: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms: Rostligand;(S,S)-DACH-phenyl ligand;(1S,2S)-(-)-1,2-TROST LIGAND;1S,2S- DHAC-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand;95% (S,S)-DACH-Phenyl Trost Ligand;(S,S)-DACH-phenyl Trost ligand 95%;(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.;1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl);(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp...
CBNumber: CB9299425
Molecular Formula: C44H40N2O2P2
Formula Weight: 690.76
MOL File: 169689-05-8.mol

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Property

Melting point:: 134-136°C
Boiling point:: 817.0±65.0 °C(Predicted)
alpha: -134o (C=1 IN METHANOL)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: 13.35±0.40(Predicted)
form: Powder
color: white to off-white
optical activity: [α]20/D -134°, c = 1 in methanol

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 692794
Product name: (S,S)-DACH-phenyl Trost ligand
Purity: 95%
Packaging: 250mg
Price: $64.8
Updated: 2024/03/01

Sigma-Aldrich

Product number: 692794
Product name: (S,S)-DACH-phenyl Trost ligand
Purity: 95%
Packaging: 1g
Price: $374
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0961
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging: 100mg
Price: $41
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0961
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging: 500mg
Price: $161
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0961
Product name: (1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Packaging: 2g
Price: $495
Updated: 2024/03/01

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(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Chemical Properties,Usage,Production

Reaction

The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles.

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: (S,S)-DACH-phenyl Trost ligand 169689-05-8
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) 169689-05-8
Price: US $3.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-10

169689-05-8, (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)Related Search:

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) (1S,2S)-N,N'-Dimethyl-1,2-cyclohexanediamine (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-COBALT(II) (1S,2S)-(+)-N-(4-Toluenesulfonyl)-1,2-diphenylethylenediamine (1R,2S)-1-Amino-2-indanol (1S,2S)-(-)-1,2-Diphenyl-1,2-ethanediamine (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) 1,2-Diaminocyclohexane (1S,2S)-(+)-1,2-Diaminocyclohexane 2-Diphenylphosphinobenzaldehyde (+/-)-trans-1,2-Diaminocyclohexane (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) N-(2-AMINO-CYCLOHEXYL)-ACETAMIDE

(1S,2S)-(-)-1,2-TROST LIGAND

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl)

(1S,2S)-(-)-Diaminocyclohexane-N,N'-bis(2'-diphenylphospholinobenzoyl)

(S,S)-DACH-phenyl Trost ligand,(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand

1S,2S- DHAC-Phenyl Trost Ligand

95% (S,S)-DACH-Phenyl Trost Ligand

Rostligand

1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),98%(S,S)-DACH-PhenylTrostLigand

(S,S)-DACH-phenyl ligand

(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N''-BIS(2''-DIPHENYLPHOSPHINOBENZOYL) TROST LIGAND

(S,S)-DACH-phenyl Trost ligand

(1S,2S)-(¨C)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphinobenzoyl)

"N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide] /(S,S)-DACH-Phenyl Trost Ligand"

(S,S)-DACH-phenyl Trost ligand 95%

BenzaMide,N,N'-(1S,2S)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-

N,N'-(1S,2S)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide]

(1S,2S)-DHAC-Phenyl Trost Ligand,99%e.e.

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl),(S,S)-DACH-Phenyl Trost Ligand

(1S,2S)-N,N'-1,2-Diaminocyclohexane-bis(2'-diphenylphosphinobenzoyl)

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosp...

N,N'-((1S,2S)-Cyclohexane-1,2-diyl)bis(2-(diphenylphosphino)benzamide)

169689-05-8

Chiral Nitrogen

DACH&Trost Series