3-ETHOXY-3-OXOPROPYLZINC BROMIDE

Product Name: 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
CAS No.: 193065-68-8
Chemical Name: 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
Synonyms: (3-ethoxy-3-oxopropyl)zinc(II) broMide;zinc bromide soL;3-Ethoxy-3-oxopropyL;3-ETHOXY-3-OXOPROPYLZINC BROMIDE;2-(Ethoxycarbonyl)ethylzinc bromide;3-ethoxy-3-oxopropylzinc bromide solution;2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF;3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF;3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF;3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN
CBNumber: CB5767797
Molecular Formula: C5H9BrO2Zn
Formula Weight: 246.41
MOL File: 193065-68-8.mol

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3-ETHOXY-3-OXOPROPYLZINC BROMIDE Property

Density: 0.972 g/mL at 25 °C
Flash point:: 1 °F
storage temp.: 2-8°C
Water Solubility: Reacts with water.
Exposure limits: ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)

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Safety

Hazard Codes: F,Xi,Xn
Risk Statements: 11-19-36/37-40
Safety Statements: 16-26-29-33-36/37
RIDADR: UN 3399 4.3/PG 2
WGK Germany: 1
HazardClass: 4.3
PackingGroup: II
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 498521
Product name: 3-Ethoxy-3-oxopropylzinc bromide solution
Purity: 0.5 M in THF
Packaging: 50ml
Price: $221.6
Updated: 2024/03/01

Alfa Aesar

Product number: H26739
Product name: 2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF
Packaging: 50ml
Price: $190
Updated: 2024/03/01

Rieke Metals

Product number: 2010
Product name: 3-Ethoxy-3-oxopropylzincbromide
Packaging: 100mL
Price: $460
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0005827
Product name: 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
Purity: 95.00%
Packaging: 100ML
Price: $2795.1
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0005827
Product name: 3-ETHOXY-3-OXOPROPYLZINC BROMIDE
Purity: 95.00%
Packaging: 500ML
Price: $5313
Updated: 2021/12/16

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3-ETHOXY-3-OXOPROPYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in:

Synthesis of γ-keto esters from aryl chlorides.
Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides.
Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.

3-ETHOXY-3-OXOPROPYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-ETHOXY-3-OXOPROPYLZINC BROMIDE Suppliers

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193065-68-8, 3-ETHOXY-3-OXOPROPYLZINC BROMIDERelated Search:

3-FLUOROPHENYLMAGNESIUM BROMIDE 2-FLUOROPHENYLZINC IODIDE 3-FLUOROPHENYLZINC IODIDE 2-ETHYLPHENYLZINC IODIDE 4-CHLOROPHENYLZINC IODIDE 4-(ETHOXYCARBONYL)PHENYLZINC BROMIDE 4-ETHYLPHENYLZINC IODIDE 4-N-PENTYLPHENYLZINC IODIDE 2-CHLOROPHENYLZINC IODIDE 2-METHYLPHENYLZINC IODIDE 1-NAPHTHYLZINC IODIDE 2-(ETHOXYCARBONYL)PHENYLZINC BROMIDE 4-METHYLPHENYLZINC IODIDE 6-CHLOROHEXYLZINC BROMIDE 3-BROMOPHENYLZINC IODIDE 3-ETHOXY-3-OXOPROPYLZINC BROMIDE 3-TERT-BUTOXY-3-OXOPROPYLZINC BROMIDE N-PROPYLZINC BROMIDE

3-ETHOXY-3-OXOPROPYLZINC BROMIDE

3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN

3-ethoxy-3-oxopropylzinc bromide solution

2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF

2-(Ethoxycarbonyl)ethylzinc bromide

3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF

(3-ethoxy-3-oxopropyl)zinc(II) broMide

3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF

3-Ethoxy-3-oxopropyL

zinc bromide soL

193065-68-8

BrZnCH2CH2COOCH2CH3

C5H9BrO2Zn

C2H5O2CCH2CH2ZnBr

Reike and Organozinc Reagents

Organometallic Reagents

Organozinc Halides

Alkyl

Organozinc Halides

Reike and Organozinc Reagents