ChemicalBook > CAS DataBase List > trans-4-(Trifluoromethyl)cyclohexanol

trans-4-(Trifluoromethyl)cyclohexanol

Product Name: trans-4-(Trifluoromethyl)cyclohexanol
CAS No.: 75091-93-9
Chemical Name: trans-4-(Trifluoromethyl)cyclohexanol
Synonyms: trans-4-(Trifluoromethyl);Trans-4-(Trifluoromethyl)Cyclohexano;trans-4-(Trifluoromethyl)cyclohexanol;trans (e,e)-4-trifluoromethylcyclohexanol;Cyclohexanol, 4-(trifluoromethyl)-, trans-
CBNumber: CB5947269
Molecular Formula: C7H11F3O
Formula Weight: 168.16
MOL File: 75091-93-9.mol

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trans-4-(Trifluoromethyl)cyclohexanol Property

Boiling point:: 160.4±35.0 °C(Predicted)
Density: 1.231±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 14.88±0.40(Predicted)
Appearance: Colorless to light yellow Solid
InChI: InChI=1S/C7H11F3O/c8-7(9,10)5-1-3-6(11)4-2-5/h5-6,11H,1-4H2/t5-,6-
InChIKey: VJUJYNJEPPWWHS-IZLXSQMJSA-N
SMILES: [C@@H]1(O)CC[C@@H](C(F)(F)F)CC1

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Safety

HS Code: 2906190090

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Activate Scientific

Product number: AS46451
Product name: trans-4-(Trifluoromethyl)cyclohexanol
Purity: 97%
Packaging: 250mg
Price: $176
Updated: 2021/12/16

Activate Scientific

Product number: AS46451
Product name: trans-4-(Trifluoromethyl)cyclohexanol
Purity: 97%
Packaging: 1g
Price: $358
Updated: 2021/12/16

AK Scientific

Product number: 9829AL
Product name: trans-4-(Trifluoromethyl)cyclohexanol
Packaging: 5g
Price: $979
Updated: 2021/12/16

Activate Scientific

Product number: AS46451
Product name: trans-4-(Trifluoromethyl)cyclohexanol
Purity: 97%
Packaging: 5G
Price: $1127
Updated: 2021/12/16

Chemenu

Product number: CM129406
Product name: trans-4-(Trifluoromethyl)cyclohexanol
Purity: 98%
Packaging: 10g
Price: $1244
Updated: 2021/12/16

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trans-4-(Trifluoromethyl)cyclohexanol Chemical Properties,Usage,Production

Synthesis

402-45-9

75091-92-8

Step A: Synthesis of 4-trifluoromethylcyclohexanol; 4-hydroxytrifluorotoluene (5 g, 30.8 mmol) was placed in an autoclave reactor, dissolved in acetic acid (15 ml) and platinum oxide (PtO, 500 mg) was added as a catalyst. The reactor was pressurized using hydrogen (50 psi) and the reaction was carried out for 16 h at room temperature. Upon completion of the reaction, the reaction mixture was filtered through a bed of diatomaceous earth and the filtrate was neutralized with 1N sodium hydroxide solution and subsequently extracted with diethyl ether. The organic phase was dried over anhydrous magnesium sulfate (MgSO4) and concentrated in vacuum at room temperature to give trans-4-(trifluoromethyl)cyclohexanol (4.5 g, 87% yield). MS [M + H]+ = 169 (corresponding to M + 1).

References

[1] Patent: WO2008/7930, 2008, A1. Location in patent: Page/Page column 27
[2] Journal of Organic Chemistry USSR (English Translation), 1970, vol. 6, # 10, p. 2063 - 2067
[3] Zhurnal Organicheskoi Khimii, 1970, vol. 6, # 10, p. 2055 - 2060

trans-4-(Trifluoromethyl)cyclohexanol Preparation Products And Raw materials

Raw materials

Preparation Products

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75091-93-9, trans-4-(Trifluoromethyl)cyclohexanol Related Search:

4-(TRIFLUOROMETHYL)CYCLOHEXANOL

trans-4-(Trifluoromethyl)cyclohexanol

trans (e,e)-4-trifluoromethylcyclohexanol

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Trans-4-(Trifluoromethyl)Cyclohexano

75091-93-9