2-Adamantanone

ChemicalBook > CAS DataBase List > 2-Adamantanone

Uses synthesis

Product Name: 2-Adamantanone
CAS No.: 700-58-3
Chemical Name: 2-Adamantanone
Synonyms: Adamantanone;ADAMANTAN-2-ONE;AKOS BC-0654;2-ADAMANTONE;2- adaMantine;2-ADAMANTANONE;2-adamandanone;Adamantan-9-one;2-Oxoadamantane;ADAMANTANONE, 2-
CBNumber: CB6114022
Molecular Formula: C10H14O
Formula Weight: 150.22
MOL File: 700-58-3.mol

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2-Adamantanone Property

Melting point:: 256-258 °C (subl.)(lit.)
Boiling point:: 211.78°C (rough estimate)
Density: 0.8709 (rough estimate)
refractive index: 1.4993 (estimate)
storage temp.: Sealed in dry,Room Temperature
solubility: methanol: 0.1 g/mL, clear
form: Crystalline Powder
color: White to off-white
BRN: 1210235
InChI: InChI=1S/C10H14O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2
InChIKey: IYKFYARMMIESOX-UHFFFAOYSA-N
SMILES: C12CC3CC(CC(C3)C1=O)C2
CAS DataBase Reference: 700-58-3(CAS DataBase Reference)
NIST Chemistry Reference: 2-Adamantanone(700-58-3)

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Safety

Hazard Codes: Xi
Risk Statements: 52-36/37/38
Safety Statements: 22-24/25-36-26
WGK Germany: 2
RTECS: AU5018000
Hazard Note: Irritant
HS Code: 29142900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H402Harmful to aquatic life

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 146048
Product name: 2-Adamantanone
Purity: ReagentPlus , 99%
Packaging: 5g
Price: $35.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 146048
Product name: 2-Adamantanone
Purity: ReagentPlus , 99%
Packaging: 25g
Price: $101
Updated: 2024/03/01

TCI Chemical

Product number: A0719
Product name: 2-Adamantanone
Purity: >98.0%(GC)
Packaging: 5g
Price: $42
Updated: 2024/03/01

TCI Chemical

Product number: A0719
Product name: 2-Adamantanone
Purity: >98.0%(GC)
Packaging: 25g
Price: $115
Updated: 2024/03/01

Alfa Aesar

Product number: A14275
Product name: 2-Adamantanone, 98%
Packaging: 5g
Price: $42.65
Updated: 2024/03/01

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2-Adamantanone Chemical Properties,Usage,Production

Uses

2-Adamantanone has been used as a probe for the dimensions and characteristics for the substrate binding pocket of alcohol dehydrogenases.

synthesis

Dissolve the alcohol (0.25 mmol) in acetonitrile (3 mL). Add oxidant 1,3-dichloro-5,5-dimethylhydantoin (DCH, 0.148 g, 0.75 mmol) to the reaction mixture. Add the pre-catalyst MWCNT-{(CH2)3-CO- NH-TEMPO}n (0.075 g) to the reaction mixture. Sonic the resulting suspension (1 min.) using an ultrasonic bath. Stir the reaction mixture. Heat the reaction mixture at 50 °C for 30 minutes. Filter the reaction mixture. Add CH2Cl2 (10 mL) to the reaction mixture. Wash the organic phase with aqueous Na2S2O3 (10 %, 10 mL) and H2O (10 mL x 2). Dry the residue with Na2SO4. Remove the solvent under reduced pressure using a rotary evaporator to obtain the product.

Chemical Properties

white to off-white crystalline powder with camphor smell, soluble in methanol, ethanol, DMSO and other organic solvents, from synthesis.

Uses

2-Adamantanone was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane and (+/-)-1-(adamantan-2-yl)-2-propanamine.

Definition

ChEBI: Adamantanone is a member of adamantanones.

General Description

2-Adamantanone on deprotonation in the gas phase affords the corresponding β-enolate anion. It reacts with 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole to yield 5-silafulvene.

Purification Methods

Purify 2-admantanone by repeated sublimation in vacuo. [Butler et al. J Chem Soc, Faraday Trans II 82 535 1986.]

2-Adamantanone Preparation Products And Raw materials

Raw materials

Preparation Products

2-Ethyl-2-adamantanol 2-Methyl-2-adamantanol

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View Lastest Price from 2-Adamantanone manufacturers

airuikechemical co., ltd.

Product: 2-Adamantanone 700-58-3
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 99.9%
Supply Ability: 200tons
Release date: 2024-04-08

Wuhan Senwayer Century Chemical Co.,Ltd

Product: 2-Adamantanone 700-58-3
Price: US $0.00-0.00/g
Min. Order: 50g
Purity: 99%
Supply Ability: 300kg
Release date: 2023-02-10

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 2-Adamantanone 700-58-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-16

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LABOTEST-BB LT00239630

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2-AdaMantane Ketone

2-ADAMANTANONE FOR SYNTHESIS 5 G

2-ADAMANTANONE FOR SYNTHESIS 25 G

Tricyclo[3.3.1.1~3,7~]decan-2-one, 2-Oxotricyclo[3.3.1.1~3,7~]decane

2-Adamantanone Vetec(TM) reagent grade, 98%

2-AdaMantanone ReagentPlus(R), 99%

AdaMantane ketone

2- adaMantine

2-Oxoadamantane

2-Adamantanone(Tricyclo[3.3.1.1(3,7)]decane-2-one)

2-Adamantanone 700-58-3

Adamantanone 700-58-3

2-Adamantanone &gt

2-Adamantanone,99%

Factory Supply CAS 700-58-3 2-Adamantanone with Fast Delivery

700-58-3

C10H14O

Carbonyl Compounds

C10

Building Blocks

Ketones

Organic Building Blocks

Adamantanes

FINE Chemical & INTERMEDIATES

Adamantane Derivative

Ring Systems

C10

Adamantane derivatives

Adamantanes

Building Blocks

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Carbonyl Compounds

Ketones