Uses synthesis
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2-Adamantanone

Uses synthesis
Product Name
2-Adamantanone
CAS No.
700-58-3
Chemical Name
2-Adamantanone
Synonyms
Adamantanone;ADAMANTAN-2-ONE;AKOS BC-0654;2-ADAMANTONE;2- adaMantine;2-ADAMANTANONE;2-adamandanone;Adamantan-9-one;2-Oxoadamantane;ADAMANTANONE, 2-
CBNumber
CB6114022
Molecular Formula
C10H14O
Formula Weight
150.22
MOL File
700-58-3.mol
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2-Adamantanone Property

Melting point:
256-258 °C (subl.)(lit.)
Boiling point:
211.78°C (rough estimate)
Density 
0.8709 (rough estimate)
refractive index 
1.4993 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
methanol: 0.1 g/mL, clear
form 
Crystalline Powder
color 
White to off-white
BRN 
1210235
InChI
InChI=1S/C10H14O/c11-10-8-2-6-1-7(4-8)5-9(10)3-6/h6-9H,1-5H2
InChIKey
IYKFYARMMIESOX-UHFFFAOYSA-N
SMILES
C12CC3CC(CC(C3)C1=O)C2
CAS DataBase Reference
700-58-3(CAS DataBase Reference)
NIST Chemistry Reference
2-Adamantanone(700-58-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
52-36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
2
RTECS 
AU5018000
Hazard Note 
Irritant
HS Code 
29142900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H402Harmful to aquatic life

Precautionary statements

P273Avoid release to the environment.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
146048
Product name
2-Adamantanone
Purity
ReagentPlus , 99%
Packaging
5g
Price
$35.5
Updated
2024/03/01
Sigma-Aldrich
Product number
146048
Product name
2-Adamantanone
Purity
ReagentPlus , 99%
Packaging
25g
Price
$101
Updated
2024/03/01
TCI Chemical
Product number
A0719
Product name
2-Adamantanone
Purity
>98.0%(GC)
Packaging
5g
Price
$42
Updated
2024/03/01
TCI Chemical
Product number
A0719
Product name
2-Adamantanone
Purity
>98.0%(GC)
Packaging
25g
Price
$115
Updated
2024/03/01
Alfa Aesar
Product number
A14275
Product name
2-Adamantanone, 98%
Packaging
5g
Price
$42.65
Updated
2024/03/01
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2-Adamantanone Chemical Properties,Usage,Production

Uses

2-Adamantanone has been used as a probe for the dimensions and characteristics for the substrate binding pocket of alcohol dehydrogenases.

synthesis

Dissolve the alcohol (0.25 mmol) in acetonitrile (3 mL). Add oxidant 1,3-dichloro-5,5-dimethylhydantoin (DCH, 0.148 g, 0.75 mmol) to the reaction mixture. Add the pre-catalyst MWCNT-{(CH2)3-CO- NH-TEMPO}n (0.075 g) to the reaction mixture. Sonic the resulting suspension (1 min.) using an ultrasonic bath. Stir the reaction mixture. Heat the reaction mixture at 50 °C for 30 minutes. Filter the reaction mixture. Add CH2Cl2 (10 mL) to the reaction mixture. Wash the organic phase with aqueous Na2S2O3 (10 %, 10 mL) and H2O (10 mL x 2). Dry the residue with Na2SO4. Remove the solvent under reduced pressure using a rotary evaporator to obtain the product.

Chemical Properties

white to off-white crystalline powder with camphor smell, soluble in methanol, ethanol, DMSO and other organic solvents, from synthesis.

Uses

2-Adamantanone was used in the synthesis of dispiro N-Boc-protected 1,2,4-trioxane and (+/-)-1-(adamantan-2-yl)-2-propanamine.

Definition

ChEBI: Adamantanone is a member of adamantanones.

General Description

2-Adamantanone on deprotonation in the gas phase affords the corresponding β-enolate anion. It reacts with 1,1-dilithio-1-sila-2,3,4,5-tetraphenylsilole to yield 5-silafulvene.

Purification Methods

Purify 2-admantanone by repeated sublimation in vacuo. [Butler et al. J Chem Soc, Faraday Trans II 82 535 1986.]

2-Adamantanone Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2-Adamantanone manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
2-Adamantanone 700-58-3
Price
US $100.00-75.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-22
WUHAN FORTUNA CHEMICAL CO., LTD
Product
2-Adamantanone 700-58-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-16
Hebei Weibang Biotechnology Co., Ltd
Product
2-Adamantanone 700-58-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-25

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