ChemicalBook > CAS DataBase List > DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Reaction- Product Name
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- CAS No.
- 134524-84-8
- Chemical Name
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
- Synonyms
- Dichloro [(S);RuCl2[S-BINAP];(S)-BINAP RUCL2;-binaphthyl]dichlororuthenium;-1,1'-binaphthyl]ruthenium(II);-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichlorobisdiphenylphosphinobinaphthylrutheniu;(S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...;dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium
- CBNumber
- CB6114507
- Molecular Formula
- C44H32Cl2P2Ru
- Formula Weight
- 794.65
- MOL File
- 134524-84-8.mol
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Property
- Melting point:
- >300 ºC
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- solubility
- Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
- Stability:
- Air Sensitive, Moisture Sensitive
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39-36/37
- WGK Germany
- 3
- HS Code
- 28439000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- B3068
- Product name
- [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
- Packaging
- 250mg
- Price
- $318
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0249
- Product name
- Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
- Packaging
- 100mg
- Price
- $73
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0249
- Product name
- Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
- Packaging
- 500mg
- Price
- $163
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0249
- Product name
- Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
- Packaging
- 2g
- Price
- $486
- Updated
- 2024/03/01
TRC
- Product number
- B430400
- Product name
- [(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium
- Packaging
- 250mg
- Price
- $80
- Updated
- 2021/12/16
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Usage,Production
Reaction
- Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
- Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Chemical Properties
Solid
Uses
[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) manufacturers
Shanghai UCHEM Inc.
- Product
- (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 134524-84-8
- Price
- US $43.00-208.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 1kg
- Release date
- 2024-04-12
Hangzhou ICH Biofarm Co., Ltd
- Product
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2023-06-28
Hangzhou ICH Biofarm Co., Ltd
- Product
- DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 200kg
- Release date
- 2023-06-28
134524-84-8, DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)Related Search:
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(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl