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ChemicalBook > CAS DataBase List > DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

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Product Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
CAS No.
134524-84-8
Chemical Name
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms
Dichloro [(S);RuCl2[S-BINAP];(S)-BINAP RUCL2;-binaphthyl]dichlororuthenium;-1,1'-binaphthyl]ruthenium(II);-binaphthyl]ruthenium(II),(S-BINAP)RuCl2;Dichlorobisdiphenylphosphinobinaphthylrutheniu;(S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II);Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...;dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium
CBNumber
CB6114507
Molecular Formula
C44H32Cl2P2Ru
Formula Weight
794.65
MOL File
134524-84-8.mol
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Property

Melting point:
>300 ºC
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
Benzene (Slightly, Heated), Dichloromethane (Slightly, Heated)
form 
Powder
color 
orange
Sensitive 
air sensitive
Stability:
Air Sensitive, Moisture Sensitive
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36/37/39-36/37
WGK Germany 
3
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3068
Product name
[(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
Packaging
250mg
Price
$318
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
100mg
Price
$73
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
500mg
Price
$163
Updated
2024/03/01
Strem Chemicals
Product number
44-0249
Product name
Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
Packaging
2g
Price
$486
Updated
2024/03/01
TRC
Product number
B430400
Product name
[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium
Packaging
250mg
Price
$80
Updated
2021/12/16
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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties,Usage,Production

Reaction

  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.

Chemical Properties

Solid

Uses

[(S)-2,2''-Bis(diphenylphosphino)-1,1''-binaphthyl]dichlororuthenium is used as a catalyst in the asymmetric synthesis of chiral δ-lactones and in the stereoselective synthesis of (hydroxy)amino acids via asymmetric hydrogenation of aminoketo esters.

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28387
Advantage
80
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View Lastest Price from DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) manufacturers

Shanghai UCHEM Inc.
Product
(S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 134524-84-8
Price
US $43.00-208.00/g
Min. Order
1g
Purity
0.98
Supply Ability
1kg
Release date
2024-04-12
Hangzhou ICH Biofarm Co., Ltd
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200kg
Release date
2023-06-28
Hangzhou ICH Biofarm Co., Ltd
Product
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) 134524-84-8
Price
US $0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
200kg
Release date
2023-06-28

134524-84-8, DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)Related Search:


  • (S)-(-)-2,2''-Bis-(diphenylphosphino)-1,1''-binaphthyl ruthenium dichloride
  • [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
  • Dichloro〔(S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl〕ruthenium(Ⅱ)
  • Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(S)-BINAP]RuCl2
  • (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium
  • -binaphthyl]dichlororuthenium
  • -binaphthyl]ruthenium(II),(S-BINAP)RuCl2
  • Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II), min. 95%
  • Dichloro[(S)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),(S-BINAP)RuCl2
  • [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium
  • (S)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium 95%
  • (S)-(-)2,2'bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • (S)-BINAP RUCL2
  • -1,1'-binaphthyl]ruthenium(II)
  • Dichloro [(S)
  • DICHLORO[(R)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
  • DICHLORO[(S)-2,2'-BIS-(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) HOMOPOLYMER
  • Dichlorobisdiphenylphosphinobinaphthylrutheniu
  • Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),min.95%
  • dichioro[(R)-(+)-2,2‘-bis(diphenylphosphino)-1,1‘-binaphthyl]ruthenium(II)
  • dichloro ((S)-(-)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(I)
  • dichloro-R-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ruthenium
  • RuCl2[S-BINAP]
  • Dichloro[(S)-(-)-,2,2'-bis(diphenylphosphino)-1,1'-binaphthy...
  • [(S)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Dichloride
  • Dichloro [(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • 134524-84-8
  • C44H32Cl2P2Ru
  • Catalysts for Organic Synthesis
  • Classes of Metal Compounds
  • Homogeneous Catalysts
  • Metal Complexes
  • Ru (Ruthenium) Compounds
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Ru