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(-)-O-ACETYL-L-MALIC ANHYDRIDE

Product Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
CAS No.
59025-03-5
Chemical Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
Synonyms
(S)-Acetoxysuccinic Anhydride;L-O-Acetylmalic Anhydride;2-acetoxysuccinicanhydride;(S)-(-)-2-2-Acetoxysuccinic;(S)-2-O-Acetylmalic Anhydride;(-)-O-ACETYL-L-MALIC ANHYDRIDE;2-O-ACETYL-(S)-MALIC ANHYDRIDE;(-)-O-Acetyl-L-malic Anhydride;(S)-(-)-O-ACETYLMALIC ANHYDRIDE;(S)-2-ACETOXYSUCCINIC ANHYDRIDE
CBNumber
CB6114633
Molecular Formula
C6H6O5
Formula Weight
158.11
MOL File
59025-03-5.mol
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(-)-O-ACETYL-L-MALIC ANHYDRIDE Property

Melting point:
54-56 °C(lit.)
Boiling point:
296.6±33.0 °C(Predicted)
Density 
1.38±0.1 g/cm3(Predicted)
refractive index 
-25.5 ° (C=5, CHCl3)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Dichloromethane, DMF, Ethyl Acetate
form 
Powder
color 
White Crystalline
optical activity
[α]20/D 27°, c = 1 in chloroform
Water Solubility 
Reacts in water.
Sensitive 
Moisture Sensitive
BRN 
82504
Stability:
Stable. Incompatible with strong oxidizing agents. Sensitive to moisture.
CAS DataBase Reference
59025-03-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
F 
10-21
HS Code 
2917.19.7050
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
422800
Product name
(S)-(?)-2-Acetoxysuccinic anhydride
Purity
98%
Packaging
5g
Price
$60.2
Updated
2023/01/07
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
5g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
25g
Price
$228
Updated
2024/03/01
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
2g
Price
$20.1
Updated
2021/12/16
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
10g
Price
$74.6
Updated
2021/12/16
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(-)-O-ACETYL-L-MALIC ANHYDRIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystalline Solid

Uses

(S)-(-)-2-Acetoxysuccinic anhydride is used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles.

Uses

(-)-O-Acetyl-L-Malic Anhydride can be used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles

Purification Methods

Recrystallise it from Ac2O and dry it in a vacuum over KOH, or by washing it with dry Et2O due to its deliquescent nature. [Jones J Chem Soc 788 1933, Henrot et al. Synth Commun 16 183 1986, Shiuey et al. J Org Chem 52 1040 1988, RS: Cohen et al. J Am Chem Soc 88 5306 1966.]

(-)-O-ACETYL-L-MALIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-O-ACETYL-L-MALIC ANHYDRIDE Suppliers

Americas 1 Belgium 2 Canada 2 CHINA 60 Europe 1 France 1 Germany 4 India 5 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 7 United States 17 Global 103
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from (-)-O-ACETYL-L-MALIC ANHYDRIDE manufacturers

Career Henan Chemical Co
Product
(-)-O-ACETYL-L-MALIC ANHYDRIDE 59025-03-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-03

59025-03-5, (-)-O-ACETYL-L-MALIC ANHYDRIDERelated Search:

Succinic anhydride O-ACETYL D-MALIC ANHYDRIDE,(+)-O-ACETYL-D-MALIC ANHYDRIDE (-)-DIACETYL-D-TARTARIC ANHYDRIDE (-)-O-ACETYL-L-MALIC ANHYDRIDE D-PTAN (S)-2-TRIFLUOROACETOXYSUCCINIC ANHYDRIDE (+)-DIBENZOYL-L-TARTARIC ANHYDRIDE D-DAAN

  • 2-O-ACETYL-(S)-MALIC ANHYDRIDE
  • (-)-O-ACETYL-L-MALIC ANHYDRIDE
  • (S)-(-)-O-ACETYLMALIC ANHYDRIDE
  • (S)-(-)-2-ACETOXYSUCCINIC ANHYDRIDE
  • (S)-2-ACETOXYSUCCINIC ANHYDRIDE
  • L-O-Acetylmalic Anhydride
  • (S)-3-Acetoxy-dihydro-2,5-furandione, O-Acetyl-L-malic anhydride
  • (2S)-2-Acetoxysuccinic anhydride
  • (3S)-3-Acetoxyfuran-2,5(3H,4H)-dione
  • 2-acetoxysuccinicanhydride
  • (s)-3-acetoxy-dihydro-2,5-furandione
  • (3S)-3-(Acetyloxy)dihydro-2,5-furandione
  • (S)-2-O-Acetylmalic Anhydride
  • (S)-Acetoxysuccinic Anhydride
  • (S)-3β-Acetoxy-3,4-dihydro-2,5-furandione
  • [S,(-)]-2-(Acetyloxy)succinic anhydride
  • Acetic acid (S)-2,5-dioxotetrahydrofuran-3β-yl ester
  • (S)-(-)-2-2-Acetoxysuccinic
  • (-)-<i>O</i>-Acetyl-<small>L</small>-malic Anhydride
  • (-)-O-Acetyl-L-malic Anhydride &gt
  • 2,5-Furandione, 3-(acetyloxy)dihydro-, (3S)-
  • [(3S)-2,5-dioxooxolan-3-yl] acetate
  • (-)-O-Acetyl-L-malic Anhydride
  • (S)-2,5-dioxotetrahydrofuran-3-yl acetate
  • 59025-03-5
  • C6H6O5
  • Organic Building Blocks
  • Carboxylic Acid Anhydrides
  • Asymmetric Synthesis
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • ANHYDRIDE
  • Chiral Reagents
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Heterocycles
  • Miscellaneous Reagents