ChemicalBook > CAS DataBase List > (-)-O-ACETYL-L-MALIC ANHYDRIDE

(-)-O-ACETYL-L-MALIC ANHYDRIDE

Product Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
CAS No.
59025-03-5
Chemical Name
(-)-O-ACETYL-L-MALIC ANHYDRIDE
Synonyms
(S)-Acetoxysuccinic Anhydride;L-O-Acetylmalic Anhydride;2-acetoxysuccinicanhydride;(S)-(-)-2-2-Acetoxysuccinic;(S)-2-O-Acetylmalic Anhydride;(-)-O-ACETYL-L-MALIC ANHYDRIDE;2-O-ACETYL-(S)-MALIC ANHYDRIDE;(-)-O-Acetyl-L-malic Anhydride;(S)-(-)-O-ACETYLMALIC ANHYDRIDE;(S)-2-ACETOXYSUCCINIC ANHYDRIDE
CBNumber
CB6114633
Molecular Formula
C6H6O5
Formula Weight
158.11
MOL File
59025-03-5.mol
More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Property

Melting point:
54-56 °C(lit.)
Boiling point:
296.6±33.0 °C(Predicted)
Density 
1.38±0.1 g/cm3(Predicted)
refractive index 
-25.5 ° (C=5, CHCl3)
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Dichloromethane, DMF, Ethyl Acetate
form 
Powder
color 
White Crystalline
optical activity
[α]20/D 27°, c = 1 in chloroform
Water Solubility 
Reacts in water.
Sensitive 
Moisture Sensitive
BRN 
82504
Stability:
Stable. Incompatible with strong oxidizing agents. Sensitive to moisture.
CAS DataBase Reference
59025-03-5(CAS DataBase Reference)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
10-21
HS Code 
2917.19.7050
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
422800
Product name
(S)-(?)-2-Acetoxysuccinic anhydride
Purity
98%
Packaging
5g
Price
$60.2
Updated
2023/01/07
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
5g
Price
$49
Updated
2024/03/01
TCI Chemical
Product number
A1101
Product name
(-)-O-Acetyl-L-malic Anhydride
Purity
>97.0%(T)
Packaging
25g
Price
$228
Updated
2024/03/01
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
2g
Price
$20.1
Updated
2021/12/16
Alfa Aesar
Product number
044366
Product name
(S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging
10g
Price
$74.6
Updated
2021/12/16
More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystalline Solid

Uses

(S)-(-)-2-Acetoxysuccinic anhydride is used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles.

Uses

(-)-O-Acetyl-L-Malic Anhydride can be used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles

Purification Methods

Recrystallise it from Ac2O and dry it in a vacuum over KOH, or by washing it with dry Et2O due to its deliquescent nature. [Jones J Chem Soc 788 1933, Henrot et al. Synth Commun 16 183 1986, Shiuey et al. J Org Chem 52 1040 1988, RS: Cohen et al. J Am Chem Soc 88 5306 1966.]

(-)-O-ACETYL-L-MALIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(-)-O-ACETYL-L-MALIC ANHYDRIDE Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
Adamas Reagent, Ltd.
Tel
400-6009262 16621234537
Fax
021-64823266
Email
chenyj@titansci.com
Country
China
ProdList
14103
Advantage
59
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Fax
021-50795055
Email
sales@accelachem.com
Country
China
ProdList
11655
Advantage
64
Shanghai Longsheng chemical Co.,Ltd.
Tel
021-58099652-8005 13585536065
Fax
021-58099609
Email
bin.wu@shlschem.com
Country
China
ProdList
9810
Advantage
59
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42958
Advantage
64
More
Less

View Lastest Price from (-)-O-ACETYL-L-MALIC ANHYDRIDE manufacturers

Career Henan Chemical Co
Product
(-)-O-ACETYL-L-MALIC ANHYDRIDE 59025-03-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-03

59025-03-5, (-)-O-ACETYL-L-MALIC ANHYDRIDERelated Search:


  • 2-O-ACETYL-(S)-MALIC ANHYDRIDE
  • (-)-O-ACETYL-L-MALIC ANHYDRIDE
  • (S)-(-)-O-ACETYLMALIC ANHYDRIDE
  • (S)-(-)-2-ACETOXYSUCCINIC ANHYDRIDE
  • (S)-2-ACETOXYSUCCINIC ANHYDRIDE
  • L-O-Acetylmalic Anhydride
  • (S)-3-Acetoxy-dihydro-2,5-furandione, O-Acetyl-L-malic anhydride
  • (2S)-2-Acetoxysuccinic anhydride
  • (3S)-3-Acetoxyfuran-2,5(3H,4H)-dione
  • 2-acetoxysuccinicanhydride
  • (s)-3-acetoxy-dihydro-2,5-furandione
  • (3S)-3-(Acetyloxy)dihydro-2,5-furandione
  • (S)-2-O-Acetylmalic Anhydride
  • (S)-Acetoxysuccinic Anhydride
  • (S)-3β-Acetoxy-3,4-dihydro-2,5-furandione
  • [S,(-)]-2-(Acetyloxy)succinic anhydride
  • Acetic acid (S)-2,5-dioxotetrahydrofuran-3β-yl ester
  • (S)-(-)-2-2-Acetoxysuccinic
  • (-)-<i>O</i>-Acetyl-<small>L</small>-malic Anhydride
  • (-)-O-Acetyl-L-malic Anhydride &gt
  • 2,5-Furandione, 3-(acetyloxy)dihydro-, (3S)-
  • [(3S)-2,5-dioxooxolan-3-yl] acetate
  • (-)-O-Acetyl-L-malic Anhydride
  • (S)-2,5-dioxotetrahydrofuran-3-yl acetate
  • 59025-03-5
  • C6H6O5
  • Organic Building Blocks
  • Carboxylic Acid Anhydrides
  • Asymmetric Synthesis
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • ANHYDRIDE
  • Chiral Reagents
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry
  • Chiral Compound
  • Heterocycles
  • Miscellaneous Reagents