(-)-O-ACETYL-L-MALIC ANHYDRIDE

ChemicalBook > CAS DataBase List > (-)-O-ACETYL-L-MALIC ANHYDRIDE

(-)-O-ACETYL-L-MALIC ANHYDRIDE

Product Name: (-)-O-ACETYL-L-MALIC ANHYDRIDE
CAS No.: 59025-03-5
Chemical Name: (-)-O-ACETYL-L-MALIC ANHYDRIDE
Synonyms: (S)-Acetoxysuccinic Anhydride;L-O-Acetylmalic Anhydride;2-acetoxysuccinicanhydride;(S)-(-)-2-2-Acetoxysuccinic;(S)-2-O-Acetylmalic Anhydride;(-)-O-ACETYL-L-MALIC ANHYDRIDE;2-O-ACETYL-(S)-MALIC ANHYDRIDE;(-)-O-Acetyl-L-malic Anhydride;(S)-(-)-O-ACETYLMALIC ANHYDRIDE;(S)-2-ACETOXYSUCCINIC ANHYDRIDE
CBNumber: CB6114633
Molecular Formula: C6H6O5
Formula Weight: 158.11
MOL File: 59025-03-5.mol

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(-)-O-ACETYL-L-MALIC ANHYDRIDE Property

Melting point:: 54-56 °C(lit.)
Boiling point:: 296.6±33.0 °C(Predicted)
Density: 1.38±0.1 g/cm3(Predicted)
refractive index: -25.5 ° (C=5, CHCl3)
storage temp.: Inert atmosphere,Room Temperature
solubility: Dichloromethane, DMF, Ethyl Acetate
form: Powder
color: White Crystalline
optical activity: [α]20/D 27°, c = 1 in chloroform
Water Solubility: Reacts in water.
Sensitive: Moisture Sensitive
BRN: 82504
Stability:: Stable. Incompatible with strong oxidizing agents. Sensitive to moisture.
CAS DataBase Reference: 59025-03-5(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 10-21
HS Code: 2917.19.7050

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 422800
Product name: (S)-(?)-2-Acetoxysuccinic anhydride
Purity: 98%
Packaging: 5g
Price: $60.2
Updated: 2023/01/07

TCI Chemical

Product number: A1101
Product name: (-)-O-Acetyl-L-malic Anhydride
Purity: >97.0%(T)
Packaging: 5g
Price: $49
Updated: 2024/03/01

TCI Chemical

Product number: A1101
Product name: (-)-O-Acetyl-L-malic Anhydride
Purity: >97.0%(T)
Packaging: 25g
Price: $228
Updated: 2024/03/01

Alfa Aesar

Product number: 044366
Product name: (S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging: 2g
Price: $20.1
Updated: 2021/12/16

Alfa Aesar

Product number: 044366
Product name: (S)-(-)-2-Acetoxysuccinic anhydride, 98%
Packaging: 10g
Price: $74.6
Updated: 2021/12/16

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(-)-O-ACETYL-L-MALIC ANHYDRIDE Chemical Properties,Usage,Production

Chemical Properties

White Crystalline Solid

Uses

(S)-(-)-2-Acetoxysuccinic anhydride is used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles.

Uses

(-)-O-Acetyl-L-Malic Anhydride can be used as intermediates for detergents via O-acetylmalic acid amides. Regioselective ring opening of malic acid anhydrides by carbon nucleophiles

Purification Methods

Recrystallise it from Ac2O and dry it in a vacuum over KOH, or by washing it with dry Et2O due to its deliquescent nature. [Jones J Chem Soc 788 1933, Henrot et al. Synth Commun 16 183 1986, Shiuey et al. J Org Chem 52 1040 1988, RS: Cohen et al. J Am Chem Soc 88 5306 1966.]

(-)-O-ACETYL-L-MALIC ANHYDRIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-O-ACETYL-L-MALIC ANHYDRIDE Suppliers

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View Lastest Price from (-)-O-ACETYL-L-MALIC ANHYDRIDE manufacturers

Career Henan Chemical Co

Product: (-)-O-ACETYL-L-MALIC ANHYDRIDE 59025-03-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-03

59025-03-5, (-)-O-ACETYL-L-MALIC ANHYDRIDERelated Search:

Succinic anhydride O-ACETYL D-MALIC ANHYDRIDE,(+)-O-ACETYL-D-MALIC ANHYDRIDE (-)-DIACETYL-D-TARTARIC ANHYDRIDE (-)-O-ACETYL-L-MALIC ANHYDRIDE D-PTAN (S)-2-TRIFLUOROACETOXYSUCCINIC ANHYDRIDE (+)-DIBENZOYL-L-TARTARIC ANHYDRIDE D-DAAN

2-O-ACETYL-(S)-MALIC ANHYDRIDE

(-)-O-ACETYL-L-MALIC ANHYDRIDE

(S)-(-)-O-ACETYLMALIC ANHYDRIDE

(S)-(-)-2-ACETOXYSUCCINIC ANHYDRIDE

(S)-2-ACETOXYSUCCINIC ANHYDRIDE

L-O-Acetylmalic Anhydride

(S)-3-Acetoxy-dihydro-2,5-furandione, O-Acetyl-L-malic anhydride

(2S)-2-Acetoxysuccinic anhydride

(3S)-3-Acetoxyfuran-2,5(3H,4H)-dione

2-acetoxysuccinicanhydride

(s)-3-acetoxy-dihydro-2,5-furandione

(3S)-3-(Acetyloxy)dihydro-2,5-furandione

(S)-2-O-Acetylmalic Anhydride

(S)-Acetoxysuccinic Anhydride

(S)-3β-Acetoxy-3,4-dihydro-2,5-furandione

[S,(-)]-2-(Acetyloxy)succinic anhydride

Acetic acid (S)-2,5-dioxotetrahydrofuran-3β-yl ester

(S)-(-)-2-2-Acetoxysuccinic

(-)-<i>O</i>-Acetyl-<small>L</small>-malic Anhydride

(-)-O-Acetyl-L-malic Anhydride &gt

2,5-Furandione, 3-(acetyloxy)dihydro-, (3S)-

[(3S)-2,5-dioxooxolan-3-yl] acetate

(-)-O-Acetyl-L-malic Anhydride

(S)-2,5-dioxotetrahydrofuran-3-yl acetate

59025-03-5

C6H6O5

Organic Building Blocks

Carboxylic Acid Anhydrides

Asymmetric Synthesis

Carboxylic Acids (Chiral)

Chiral Building Blocks

ANHYDRIDE

Chiral Reagents

Carboxylic Acids (Chiral)

Chiral Building Blocks

Synthetic Organic Chemistry

Chiral Compound

Heterocycles

Miscellaneous Reagents