4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
- Product Name
- 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
- CAS No.
- 80058-84-0
- Chemical Name
- 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
- Synonyms
- 4-BroMo-2,6-diisopropylaniline;2,6-diisopropyl-4-bromoaniline;4-bromo-2,6-di(propan-2-yl)aniline;4-bromo-2,6-diisopropylbenzenamine;4-broMo-2,6-bis(propan-2-yl)aniline;4-Bromo-2,6-diisopropyl-phenylamine;4-bromo-2,6-bis(1-methylethyl)aniline;4-Bromo-2,6-diisopropylaniline 97%min;4-BROMO-2,6-BIS(1-METHYLETHYL)BENZEMINE;4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
- CBNumber
- CB61177253
- Molecular Formula
- C12H18BrN
- Formula Weight
- 256.18
- MOL File
- 80058-84-0.mol
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Property
- Boiling point:
- 110 °C(Press: 0.14 Torr)
- Density
- 1.231±0.06 g/cm3(Predicted)
- refractive index
- 1.57
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Chloroform (Slightly), Methanol (Slightly)
- form
- Oil
- pka
- 3.54±0.10(Predicted)
- color
- Yellow to Brown
- InChI
- InChI=1S/C12H18BrN/c1-7(2)10-5-9(13)6-11(8(3)4)12(10)14/h5-8H,14H2,1-4H3
- InChIKey
- QAQRHTYPYQPBSX-UHFFFAOYSA-N
- SMILES
- C1(N)=C(C(C)C)C=C(Br)C=C1C(C)C
Safety
- HS Code
- 2921.49.5000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- B4113
- Product name
- 4-Bromo-2,6-diisopropylaniline
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $39
- Updated
- 2025/07/31
- Product number
- B4113
- Product name
- 4-Bromo-2,6-diisopropylaniline
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $129
- Updated
- 2025/07/31
- Product number
- B683730
- Product name
- 4-Bromo-2,6-diisopropylaniline
- Packaging
- 2.5g
- Price
- $70
- Updated
- 2021/12/16
- Product number
- HCH0358745
- Product name
- 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $498.65
- Updated
- 2021/12/16
- Product number
- 80058840
- Product name
- 4-Bromo-2,6-diisopropylaniline
- Packaging
- 500mg
- Price
- $823.15
- Updated
- 2021/12/16
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Chemical Properties,Usage,Production
Chemical Properties
White solid
Uses
4-Bromo-2,6-diisopropylaniline is used as a reactant in the preparation of hyperbranched ethylene oligomers.
Synthesis
24544-04-5
80058-84-0
To a stirred solution of 2,6-diisopropylaniline (14 g, 78.97 mmol, 1.00 eq.) in N,N-dimethylformamide (200 mL) was slowly added dropwise a solution of N-bromosuccinimide (NBS, 14 g, 78.65 mmol, 1.00 eq.) in N,N-dimethylformamide (100 mL) at 0 °C, the dropwise time was controlled to 60 min. The reaction mixture was continued to be stirred at 0 °C for 1 hour. Subsequently, water (900 mL) was added to the reaction system to quench the reaction. The reaction mixture was extracted with ethyl acetate (300 mL). The organic layers were combined and washed sequentially with saturated ammonium chloride solution (3 x 100 mL) and water (1 x 100 mL). The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford 4-bromo-2,6-diisopropylaniline 20.05 g in 99% yield as a red oil.1H NMR (400 MHz, DMSO-d6): δ 6.95 (s, 2H), 4.77 (s, 2H), 5.47-5.39 (m, 1H), 3.04-2.98 (m, 1H) , 1.13 (d, J = 6.8 Hz, 12H) ppm.
References
[1] Patent: WO2012/116231, 2012, A2. Location in patent: Page/Page column 120
[2] Patent: US2014/323537, 2014, A1. Location in patent: Paragraph 0272
[3] Chemistry - A European Journal, 2015, vol. 21, # 44, p. 15676 - 15685
[4] Inorganic Chemistry, 2017, vol. 56, # 24, p. 14968 - 14978
[5] European Journal of Organic Chemistry, 2006, # 12, p. 2727 - 2738
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE manufacturers
- Product
- 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE 80058-84-0
- Price
- US $10.00/ASSAYS
- Min. Order
- 1ASSAYS
- Purity
- 99%
- Supply Ability
- 1 ton
- Release date
- 2025-08-28
- Product
- 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE 80058-84-0
- Price
- US $1.60-6.60/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-19
- Product
- 4-Bromo-2,6-diisopropylaniline 80058-84-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 100kgs/month
- Release date
- 2021-11-20