ChemicalBook > CAS DataBase List > 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE

4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE

Product Name
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
CAS No.
80058-84-0
Chemical Name
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
Synonyms
4-BroMo-2,6-diisopropylaniline;2,6-diisopropyl-4-bromoaniline;4-bromo-2,6-di(propan-2-yl)aniline;4-bromo-2,6-diisopropylbenzenamine;4-broMo-2,6-bis(propan-2-yl)aniline;4-Bromo-2,6-diisopropyl-phenylamine;4-bromo-2,6-bis(1-methylethyl)aniline;4-Bromo-2,6-diisopropylaniline 97%min;4-BROMO-2,6-BIS(1-METHYLETHYL)BENZEMINE;4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
CBNumber
CB61177253
Molecular Formula
C12H18BrN
Formula Weight
256.18
MOL File
80058-84-0.mol
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4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Property

Boiling point:
110 °C(Press: 0.14 Torr)
Density 
1.231±0.06 g/cm3(Predicted)
refractive index 
1.57
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Oil
pka
3.54±0.10(Predicted)
color 
Yellow to Brown
InChI
InChI=1S/C12H18BrN/c1-7(2)10-5-9(13)6-11(8(3)4)12(10)14/h5-8H,14H2,1-4H3
InChIKey
QAQRHTYPYQPBSX-UHFFFAOYSA-N
SMILES
C1(N)=C(C(C)C)C=C(Br)C=C1C(C)C
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Safety

HS Code 
2921.49.5000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4113
Product name
4-Bromo-2,6-diisopropylaniline
Purity
>98.0%(T)
Packaging
1g
Price
$39
Updated
2025/07/31
TCI Chemical
Product number
B4113
Product name
4-Bromo-2,6-diisopropylaniline
Purity
>98.0%(T)
Packaging
5g
Price
$129
Updated
2025/07/31
TRC
Product number
B683730
Product name
4-Bromo-2,6-diisopropylaniline
Packaging
2.5g
Price
$70
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0358745
Product name
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
Purity
95.00%
Packaging
5MG
Price
$498.65
Updated
2021/12/16
Alichem
Product number
80058840
Product name
4-Bromo-2,6-diisopropylaniline
Packaging
500mg
Price
$823.15
Updated
2021/12/16
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4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

4-Bromo-2,6-diisopropylaniline is used as a reactant in the preparation of hyperbranched ethylene oligomers.

Synthesis

24544-04-5

80058-84-0

To a stirred solution of 2,6-diisopropylaniline (14 g, 78.97 mmol, 1.00 eq.) in N,N-dimethylformamide (200 mL) was slowly added dropwise a solution of N-bromosuccinimide (NBS, 14 g, 78.65 mmol, 1.00 eq.) in N,N-dimethylformamide (100 mL) at 0 °C, the dropwise time was controlled to 60 min. The reaction mixture was continued to be stirred at 0 °C for 1 hour. Subsequently, water (900 mL) was added to the reaction system to quench the reaction. The reaction mixture was extracted with ethyl acetate (300 mL). The organic layers were combined and washed sequentially with saturated ammonium chloride solution (3 x 100 mL) and water (1 x 100 mL). The organic layer was dried over anhydrous sodium sulfate and concentrated under reduced pressure to afford 4-bromo-2,6-diisopropylaniline 20.05 g in 99% yield as a red oil.1H NMR (400 MHz, DMSO-d6): δ 6.95 (s, 2H), 4.77 (s, 2H), 5.47-5.39 (m, 1H), 3.04-2.98 (m, 1H) , 1.13 (d, J = 6.8 Hz, 12H) ppm.

References

[1] Patent: WO2012/116231, 2012, A2. Location in patent: Page/Page column 120
[2] Patent: US2014/323537, 2014, A1. Location in patent: Paragraph 0272
[3] Chemistry - A European Journal, 2015, vol. 21, # 44, p. 15676 - 15685
[4] Inorganic Chemistry, 2017, vol. 56, # 24, p. 14968 - 14978
[5] European Journal of Organic Chemistry, 2006, # 12, p. 2727 - 2738

4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Preparation Products And Raw materials

Raw materials

2,6-Diisopropylaniline

Preparation Products

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4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE Suppliers

Americas 1 China 95 Europe 1 India 4 Japan 1 United States 6 Global 108
TCI AMERICA
Tel
800-4238616
Fax
+1-888-520-1075 / +1-503-283-1987
Email
sales@tciamerica.com
Country
Americas
ProdList
23653
Advantage
75
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View Lastest Price from 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE manufacturers

RongNa Biotechnology Co.,Ltd
Product
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE 80058-84-0
Price
US $10.00/ASSAYS
Min. Order
1ASSAYS
Purity
99%
Supply Ability
1 ton
Release date
2025-08-28
ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE 80058-84-0
Price
US $1.60-6.60/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-19
Shanghai Rlavie Technology Co ltd
Product
4-Bromo-2,6-diisopropylaniline 80058-84-0
Price
US $0.00-0.00/KG
Min. Order
1g
Purity
98%min
Supply Ability
100kgs/month
Release date
2021-11-20

80058-84-0, 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINERelated Search:

Glyoxal 2,6-Diisopropylaniline 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE 4-BROMO-2,6-DIETHYLANILINE

  • 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINE
  • 4-broMo-2,6-bis(propan-2-yl)aniline
  • 4-BroMo-2,6-diisopropylaniline
  • Benzenamine,4-bromo-2,6-bis(1-methylethyl)-
  • 4-bromo-2,6-diisopropylbenzenamine
  • 4-Bromo-2,6-diisopropyl-phenylamine
  • 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZEMINE
  • 2,6-diisopropyl-4-bromoaniline
  • 4-bromo-2,6-di(propan-2-yl)aniline
  • 4-BROMO-2,6-BIS(1-METHYLETHYL)BENZENAMINEL
  • 4-bromo-2,6-bis(1-methylethyl)aniline
  • 4-Bromo-2,6-diisopropylaniline 97%min
  • 80058-84-0