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ChemicalBook > CAS DataBase List > 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)

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Product Name
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)
CAS No.
851477-20-8
Chemical Name
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)
Synonyms
1-[3,5-Bis(trifluoroMethyl)phenyl]-3-[(1S,2S) -2-(diMethylaMino)cyclohexyl]thiourea;Thiourea, N-[3,5-bis(trifluoroMethyl)phenyl]-N'-[(1S,2S)-2-(diMethylaMino)cyclohexyl]-;1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2- (dimethylamino)cyclohexyl]thiourea,99%e.e.;1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC);1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2-(dimethylamino)cyclohexyl]thiourea, 98%, (99% ee);1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]
thiourea (S,S-TUC)
CBNumber
CB61181012
Molecular Formula
C17H21F6N3S
Formula Weight
413.42
MOL File
851477-20-8.mol
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1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) Property

Melting point:
87-88°C
alpha 
+42° (c 1.16, CHCl3)
Boiling point:
380.8±52.0 °C(Predicted)
Density 
1.33±0.1 g/cm3(Predicted)
storage temp. 
2-8°C
form 
Powder
pka
11.76±0.70(Predicted)
color 
white
InChI
InChI=1S/C17H21F6N3S/c1-26(2)14-6-4-3-5-13(14)25-15(27)24-12-8-10(16(18,19)20)7-11(9-12)17(21,22)23/h7-9,13-14H,3-6H2,1-2H3,(H2,24,25,27)/t13-,14-/m0/s1
InChIKey
NQRCAVZHOLYEBJ-KBPBESRZSA-N
SMILES
N(C1=CC(C(F)(F)F)=CC(C(F)(F)F)=C1)C(N[C@H]1CCCC[C@@H]1N(C)C)=S
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
07-0284
Product name
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea (S,S-TUC)
Packaging
250mg
Price
$45
Updated
2024/03/01
Strem Chemicals
Product number
07-6332
Product name
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)
Packaging
1g
Price
$174
Updated
2024/03/01
Strem Chemicals
Product number
07-0284
Product name
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea (S,S-TUC)
Packaging
1g
Price
$134
Updated
2024/03/01
AK Scientific
Product number
5317AQ
Product name
1-[3,5-bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2-(dimethylamino)cyclohexyl]thiourea
Packaging
100mg
Price
$131.6
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0009905
Product name
1-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-3-[(1S,2S)-(+)-2-(DIMETHYLAMINO)CYCLOHEXYL]THIOUREA
Purity
95.00%
Packaging
5MG
Price
$500.78
Updated
2021/12/16
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1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) Chemical Properties,Usage,Production

Reaction

  1. Thiourea catalyst used in the enantio and diastereoselective Michael addition of malonates and ketoesters to nitroolefins.
  2. Catalyst used in the enantioselective hydrazination of 1,3-dicarbonyl compounds.
  3. Catalyst used for the dynamic resolution of azalactones.
  4. Catalyst used in Michael-Aldol reaction of 2-mercaptobenzaldehyde with α,β-unsaturated oxazolidinone.
  5. Catalyst for enantioselective synthesis of flavanones and chromanones.
  6. Catalyst for the asymmetric Neber Reaction.
  7. Catalyst for the three component synthesis of 2,6-diazabicyclo[2.2.2]octanones.

1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) Preparation Products And Raw materials

Raw materials

Preparation Products

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1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) Suppliers

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View Lastest Price from 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) manufacturers

Career Henan Chemical Co
Product
1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC) 851477-20-8
Price
US $0.01/KG
Min. Order
500g
Purity
98%; 99%
Supply Ability
500g;1kg; 10kg; 25kg
Release date
2020-01-08

851477-20-8, 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)Related Search:


  • 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]thiourea(S,S-TUC)
  • 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-(+)-2-(dimethylamino)cyclohexyl]<br />thiourea (S,S-TUC)
  • 1-[3,5-Bis(trifluoroMethyl)phenyl]-3-[(1S,2S) -2-(diMethylaMino)cyclohexyl]thiourea
  • Thiourea, N-[3,5-bis(trifluoroMethyl)phenyl]-N'-[(1S,2S)-2-(diMethylaMino)cyclohexyl]-
  • 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2- (dimethylamino)cyclohexyl]thiourea,99%e.e.
  • 1-[3,5-Bis(trifluoromethyl)phenyl]-3-[(1S,2S)-2-(dimethylamino)cyclohexyl]thiourea, 98%, (99% ee)
  • 851477-20-8
  • organic amine