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ChemicalBook > CAS DataBase List > (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT

(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT

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Product Name
(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
CAS No.
197389-47-2
Chemical Name
(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
Synonyms
oride acetonitriL;ane-4,5-dimethanoL;atotitanium(IV) dichL;-α,α,α',α'-tetra(1-naphthyL;((4R,5R)-2,2-dimethyloxazolidine-4,5-diyl)bis(di(naphthalen-1-yl)methanol);Dichloro[[(4R,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(di-1-naphthylmethanolato)]titanium;'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct;[(4R,5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol;(4R,5R)-(-)-2,2-DiMethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-diMethanolatotitaniuM(IV) dichloride acetonitrile adduct;(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
CBNumber
CB6124843
Molecular Formula
C49H40Cl2N2O3Ti
Formula Weight
823.63
MOL File
197389-47-2.mol
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Property

form 
Powder
color 
yellow
Sensitive 
air sensitive, moisture sensitive
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Safety

Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36/37/39
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
22-0761
Product name
(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
Packaging
250mg
Price
$157
Updated
2024/03/01
Strem Chemicals
Product number
22-0761
Product name
(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
Packaging
1g
Price
$470
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0000056
Product name
(4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM (IV) DICHLORIDE ACETONITRILE ADDUCT
Purity
95.00%
Packaging
1G
Price
$970.2
Updated
2021/12/16
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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Chemical Properties,Usage,Production

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  1. Catalyst used in the enantioselective fluorination of β-ketoesters.
  2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others. 

(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Preparation Products And Raw materials

Raw materials

Preparation Products

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(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT Suppliers

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197389-47-2, (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCTRelated Search:


  • (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
  • (4R,5R)-(-)-2,2-DIMETHYL-ALPHA,ALPHA,ALPHA',ALPHA'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM (IV) DICHLORIDE ACETONITRILE
  • (4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV)dichlorideacetonitrileadduct
  • (4R,5R)-(-)-2,2-DiMethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-diMethanolatotitaniuM(IV) dichloride acetonitrile adduct
  • Dichloro[[(4R,5S)-2,2-dimethyl-1,3-dioxolane-4,5-diyl]bis(di-1-naphthylmethanolato)]titanium
  • [(4R,5R)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-oxazolidin-4-yl]-dinaphthalen-1-ylmethanol
  • '-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
  • ane-4,5-dimethanoL
  • atotitanium(IV) dichL
  • oride acetonitriL
  • -α,α,α',α'-tetra(1-naphthyL
  • (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
  • ((4R,5R)-2,2-dimethyloxazolidine-4,5-diyl)bis(di(naphthalen-1-yl)methanol)
  • (4R,5R)-(-)-2,2-Dimethyl-α,α,α'',α''-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
  • (4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanolatotitanium(IV) dichloride acetonitrile adduct
  • 197389-47-2
  • C47H36Cl2O4Ti
  • Chiral Oxygen
  • TADDOL Series