DICHLOROTITANIUM DIISOPROPOXIDE

Product Name: DICHLOROTITANIUM DIISOPROPOXIDE
CAS No.: 762-99-2
Chemical Name: DICHLOROTITANIUM DIISOPROPOXIDE
Synonyms: DICHLORO(DIISOPROPOXY)TITANIUM;DICHLOROTITANIUM DIISOPROPOXIDE;Diisopropoxytitanium(IV) Chloride;DichlorotitaniumDiisopropoxide>dichlorobis(propan-2-olato)titanium;Titanium,dichlorobis(2-propanolato)-, (T-4)-
CBNumber: CB4178327
Molecular Formula: C6H14Cl2O2Ti
Formula Weight: 236.95
MOL File: 762-99-2.mol

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DICHLOROTITANIUM DIISOPROPOXIDE Property

Melting point:: 42-43 °C
storage temp.: Freezer
solubility: sol CH2Cl2, toluene, and other solvents.
form: powder to crystal
color: White to Light yellow
EPA Substance Registry System: Titanium, dichlorobis(2-propanolato)-, (T-4)- (762-99-2)

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HS Code: 2931.90.9051

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TCI Chemical

Product number: D2257
Product name: Dichlorotitanium Diisopropoxide
Purity: >95.0%(T)
Packaging: 5g
Price: $118
Updated: 2024/03/01

TCI Chemical

Product number: D2257
Product name: Dichlorotitanium Diisopropoxide
Purity: >95.0%(T)
Packaging: 25g
Price: $359
Updated: 2024/03/01

Usbiological

Product number: 274625
Product name: Dichlorotitanium Diisopropoxide
Packaging: 5g
Price: $342
Updated: 2021/12/16

Chem-Impex

Product number: 41278
Product name: Dichlorotitaniumdiisopropoxide,95%(Assaybytitration)
Purity: 95%(Assaybytitration)
Packaging: 25G
Price: $377.44
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD60920
Product name: Dichlorotitanium Diisopropoxide
Packaging: 50g
Price: $391
Updated: 2021/12/16

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DICHLOROTITANIUM DIISOPROPOXIDE Chemical Properties,Usage,Production

Uses

Dichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes.

Preparation

Dichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane; dibromotitanium diisopropoxide is prepared similarly.

storage

Corrosive; moisture sensitive; use in a fume hood; can be stored under nitrogen in pure form or in solution.

DICHLOROTITANIUM DIISOPROPOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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DICHLOROTITANIUM DIISOPROPOXIDE Suppliers

Americas 1 China 38 Europe 1 Germany 2 India 3 Japan 1 United Kingdom 2 United States 4 Global 52

J & K SCIENTIFIC LTD.

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TCI Europe

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762-99-2, DICHLOROTITANIUM DIISOPROPOXIDERelated Search:

(ethyl acetoacetato-O1',O3)(pentane-2,4-dionato-O,O')[propane-1,3-diolato(2-)-O,O']titanium [oxalato(2-)-O,O']bis(propan-2-olato)titanium butoxytris(methylphenolato)titanium dibutoxy[2-methylpentane-2,4-diolato(2-)-O,O']titanium Chromic sulfate Titanium carbide (4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT TITANIUM DICHLORIDE DIETHOXIDE TITANIUM(II) CHLORIDE (4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DIC DICHLOROTITANIUM DIISOPROPOXIDE

DICHLORO(DIISOPROPOXY)TITANIUM

DICHLOROTITANIUM DIISOPROPOXIDE

dichlorobis(propan-2-olato)titanium

DichlorotitaniumDiisopropoxide&gt

Titanium,dichlorobis(2-propanolato)-, (T-4)-

Diisopropoxytitanium(IV) Chloride

762-99-2

C6H14Cl2O2Ti

Transition Metal Compounds

Ti (Titanium) Compounds

Homogeneous Catalysts

Classes of Metal Compounds

Titanium Alkoxides, etc. (Homogeneous Catalysts)

Catalysts for Organic Synthesis

Classes of Metal Compounds

Homogeneous Catalysts

Synthetic Organic Chemistry

Ti (Titanium) Compounds

Titanium Alkoxides, etc. (Homogeneous Catalysts)

Transition Metal Compounds