ChemicalBook > CAS DataBase List > DICHLOROTITANIUM DIISOPROPOXIDE
DICHLOROTITANIUM DIISOPROPOXIDE
- Product Name
- DICHLOROTITANIUM DIISOPROPOXIDE
- CAS No.
- 762-99-2
- Chemical Name
- DICHLOROTITANIUM DIISOPROPOXIDE
- Synonyms
- DICHLORO(DIISOPROPOXY)TITANIUM;DICHLOROTITANIUM DIISOPROPOXIDE;Diisopropoxytitanium(IV) Chloride;DichlorotitaniumDiisopropoxide>dichlorobis(propan-2-olato)titanium;Titanium,dichlorobis(2-propanolato)-, (T-4)-
- CBNumber
- CB4178327
- Molecular Formula
- C6H14Cl2O2Ti
- Formula Weight
- 236.95
- MOL File
- 762-99-2.mol
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DICHLOROTITANIUM DIISOPROPOXIDE Property
- Melting point:
- 42-43 °C
- storage temp.
- Freezer
- solubility
- sol CH2Cl2, toluene, and other solvents.
- form
- powder to crystal
- color
- White to Light yellow
- EPA Substance Registry System
- Titanium, dichlorobis(2-propanolato)-, (T-4)- (762-99-2)
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Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- HS Code
- 2931.90.9051
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
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N-Bromosuccinimide Price
TCI Chemical
- Product number
- D2257
- Product name
- Dichlorotitanium Diisopropoxide
- Purity
- >95.0%(T)
- Packaging
- 5g
- Price
- $112
- Updated
- 2025/07/31
TCI Chemical
- Product number
- D2257
- Product name
- Dichlorotitanium Diisopropoxide
- Purity
- >95.0%(T)
- Packaging
- 25g
- Price
- $341
- Updated
- 2025/07/31
Usbiological
- Product number
- 274625
- Product name
- Dichlorotitanium Diisopropoxide
- Packaging
- 5g
- Price
- $342
- Updated
- 2021/12/16
Chem-Impex
- Product number
- 41278
- Product name
- Dichlorotitaniumdiisopropoxide,95%(Assaybytitration)
- Purity
- 95%(Assaybytitration)
- Packaging
- 25G
- Price
- $377.44
- Updated
- 2021/12/16
Biosynth Carbosynth
- Product number
- FD60920
- Product name
- Dichlorotitanium Diisopropoxide
- Packaging
- 50g
- Price
- $391
- Updated
- 2021/12/16
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DICHLOROTITANIUM DIISOPROPOXIDE Chemical Properties,Usage,Production
Uses
Dichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes.
Preparation
Dichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane; dibromotitanium diisopropoxide is prepared similarly.
storage
Corrosive; moisture sensitive; use in a fume hood; can be stored under nitrogen in pure form or in solution.
DICHLOROTITANIUM DIISOPROPOXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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762-99-2, DICHLOROTITANIUM DIISOPROPOXIDERelated Search:
(ethyl acetoacetato-O1',O3)(pentane-2,4-dionato-O,O')[propane-1,3-diolato(2-)-O,O']titanium
[oxalato(2-)-O,O']bis(propan-2-olato)titanium
butoxytris(methylphenolato)titanium
dibutoxy[2-methylpentane-2,4-diolato(2-)-O,O']titanium
Chromic sulfate
Titanium carbide
(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT
TITANIUM DICHLORIDE DIETHOXIDE
TITANIUM(II) CHLORIDE
(4R,5R)-(-)-2,2-DIMETHYL-TETRAPHENYL-1,3-DIOXOLANE-4,5-DIMETHANOLATO[1,2-BIS(DIMETHOXY)ETHANE]TITANIUM(IV) DIC
DICHLOROTITANIUM DIISOPROPOXIDE