2-chloro-3-isothiocyanato-prop-1-ene

ChemicalBook > CAS DataBase List > 2-chloro-3-isothiocyanato-prop-1-ene

2-chloro-3-isothiocyanato-prop-1-ene

Product Name: 2-chloro-3-isothiocyanato-prop-1-ene
CAS No.: 14214-31-4
Chemical Name: 2-chloro-3-isothiocyanato-prop-1-ene
Synonyms: 2-chloro allyl isothiocyanate;2-chloropropene isothiocyanate;2-Chloro-3-isothiocyanatopropene;2-Chloro-2-propenyl isothiocyanate;2-Chloro-3-isothiocyanato-1-propene;2-chloro-3-isothiocyanato-prop-1-ene;"1-PROPENE 2-CHLORO-3-ISOTHIOCYANATO-;2-Chloro-3-isothiocyanatopropene
CBNumber: CB61261116
Molecular Formula: C4H4ClNS
Formula Weight: 133.6
MOL File: 14214-31-4.mol

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2-chloro-3-isothiocyanato-prop-1-ene Property

Boiling point:: 182°C
Density: 1.2700
vapor pressure: 95-629Pa at 20-50℃
refractive index: 1.5560 (estimate)

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Safety

Hazard Codes: T
Risk Statements: 25
Safety Statements: 45
RIDADR: UN 2811 6.1 / PGIII
HS Code: 2930909899
Toxicity: mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#09496,

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Danger
Hazard statements: H301Toxic if swalloed
Precautionary statements: P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: SYX00300
Product name: 2-Chloro-3-isothiocyanatopropene
Packaging: 1g
Price: $104
Updated: 2024/03/01

TRC

Product number: C369063
Product name: 2-Chloro-3-isothiocyanatopropene
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: C369063
Product name: 2-Chloro-3-isothiocyanatopropene
Packaging: 500mg
Price: $110
Updated: 2021/12/16

Synthonix

Product number: C5098
Product name: 2-Chloro-3-isothiocyanatopropene
Purity: 95%
Packaging: 1g
Price: $45
Updated: 2021/12/16

Matrix Scientific

Product number: 070149
Product name: 2-Chloro-3-isothiocyanatopropene
Purity: 97%
Packaging: 1g
Price: $114
Updated: 2021/12/16

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2-chloro-3-isothiocyanato-prop-1-ene Chemical Properties,Usage,Production

Chemical Properties

colorless liquid, bp73～76℃/2.4kpa, insoluble in water, soluble in organic solvent.

Uses

2-chloro-3-isothiocyanato-prop-1-ene is an intermediate of insecticides thiamethoxam and clothianidin.

Synthesis

2-chloro-3-isothiocyanato-prop-1-ene was prepared by reacting 2,3-dichloropropene and sodium thiocyanate in acetonitrile, heating and refluxing for 3.5h in the presence of a catalyst. Reaction equation:
CH₂=CHClCH₂Cl+NaSCN→CH₂=CHClCH₂NCS

2-chloro-3-isothiocyanato-prop-1-ene Preparation Products And Raw materials

Raw materials

2,3-Dichloropropene Sodium thiocyanate Chloromethane

Preparation Products

2-Chloro-5-chloromethylthiazole

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14214-31-4, 2-chloro-3-isothiocyanato-prop-1-eneRelated Search:

Allyl isothiocyanate 2-chloro-3-isothiocyanato-prop-1-ene 2-CHLOROETHYL ISOTHIOCYANATE

2-chloro-3-isothiocyanato-prop-1-ene

2-chloro allyl isothiocyanate

2-Chloro-2-propenyl isothiocyanate

2-Chloro-3-isothiocyanatopropene

"1-PROPENE 2-CHLORO-3-ISOTHIOCYANATO-

2-chloropropene isothiocyanate

2-Chloro-3-isothiocyanato-1-propene

2-<WBR>Chloro-<WBR>3-<WBR>isothiocyanatopropene

14214-31-4

CH2CHClCH2NCS