ChemicalBook > CAS DataBase List > 2-chloro-3-isothiocyanato-prop-1-ene

2-chloro-3-isothiocyanato-prop-1-ene

Product Name
2-chloro-3-isothiocyanato-prop-1-ene
CAS No.
14214-31-4
Chemical Name
2-chloro-3-isothiocyanato-prop-1-ene
Synonyms
2-chloro allyl isothiocyanate;2-chloropropene isothiocyanate;2-Chloro-3-isothiocyanatopropene;2-Chloro-2-propenyl isothiocyanate;2-Chloro-3-isothiocyanato-1-propene;2-chloro-3-isothiocyanato-prop-1-ene;"1-PROPENE 2-CHLORO-3-ISOTHIOCYANATO-
CBNumber
CB61261116
Molecular Formula
C4H4ClNS
Formula Weight
133.6
MOL File
14214-31-4.mol
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2-chloro-3-isothiocyanato-prop-1-ene Property

Boiling point:
182°C
Density 
1.2700
vapor pressure 
95-629Pa at 20-50℃
refractive index 
1.5560 (estimate)
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Safety

Hazard Codes 
T
Risk Statements 
25
Safety Statements 
45
RIDADR 
UN 2811 6.1 / PGIII
HS Code 
2930909899
Toxicity
mouse,LD50,intravenous,56mg/kg (56mg/kg),U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#09496,
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

Precautionary statements

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SYX00300
Product name
2-Chloro-3-isothiocyanatopropene
Packaging
1g
Price
$104
Updated
2024/03/01
TRC
Product number
C369063
Product name
2-Chloro-3-isothiocyanatopropene
Packaging
500mg
Price
$110
Updated
2021/12/16
TRC
Product number
C369063
Product name
2-Chloro-3-isothiocyanatopropene
Packaging
100mg
Price
$60
Updated
2021/12/16
Synthonix
Product number
C5098
Product name
2-Chloro-3-isothiocyanatopropene
Purity
95%
Packaging
1g
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
070149
Product name
2-Chloro-3-isothiocyanatopropene
Purity
97%
Packaging
1g
Price
$114
Updated
2021/12/16
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2-chloro-3-isothiocyanato-prop-1-ene Chemical Properties,Usage,Production

Chemical Properties

colorless liquid, bp73～76℃/2.4kpa, insoluble in water, soluble in organic solvent.

Uses

2-chloro-3-isothiocyanato-prop-1-ene is an intermediate of insecticides thiamethoxam and clothianidin.

Synthesis

2-chloro-3-isothiocyanato-prop-1-ene was prepared by reacting 2,3-dichloropropene and sodium thiocyanate in acetonitrile, heating and refluxing for 3.5h in the presence of a catalyst. Reaction equation:
CH2=CHClCH2Cl+NaSCN→CH2=CHClCH2NCS

2-chloro-3-isothiocyanato-prop-1-ene Preparation Products And Raw materials

Raw materials

2,3-Dichloropropene Sodium thiocyanate Chloromethane

Preparation Products

2-Chloro-5-chloromethylthiazole
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14214-31-4, 2-chloro-3-isothiocyanato-prop-1-eneRelated Search:

Allyl isothiocyanate 2-chloro-3-isothiocyanato-prop-1-ene 2-CHLOROETHYL ISOTHIOCYANATE

  • 2-chloro-3-isothiocyanato-prop-1-ene
  • 2-chloro allyl isothiocyanate
  • 2-Chloro-2-propenyl isothiocyanate
  • 2-Chloro-3-isothiocyanatopropene
  • "1-PROPENE 2-CHLORO-3-ISOTHIOCYANATO-
  • 2-chloropropene isothiocyanate
  • 2-Chloro-3-isothiocyanato-1-propene
  • 14214-31-4
  • CH2CHClCH2NCS