thianthrene 5-oxide
- Product Name
- thianthrene 5-oxide
- CAS No.
- 2362-50-7
- Chemical Name
- thianthrene 5-oxide
- Synonyms
- thianthrene 5-oxide;Thianthrene 10-oxide;Benzothianthrene Oxide
- CBNumber
- CB61340273
- Molecular Formula
- C12H8OS2
- Formula Weight
- 232.32
- MOL File
- 2362-50-7.mol
thianthrene 5-oxide Property
- Melting point:
- 143-143.5 °C
- Boiling point:
- 423.2±15.0 °C(Predicted)
- Density
- 1.49±0.1 g/cm3(Predicted)
- storage temp.
- 2-8°C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 903973
- Product name
- Thianthrene S-oxide
- Purity
- ≥95%
- Packaging
- 1G
- Price
- $130
- Updated
- 2023/06/20
- Product number
- 903973
- Product name
- Thianthrene S-oxide
- Purity
- ≥95%
- Packaging
- 5G
- Price
- $570
- Updated
- 2023/06/20
- Product number
- CHM1040861
- Product name
- BENZOTHIANTHRENE OXIDE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $495.21
- Updated
- 2021/12/16
- Product number
- A1205571
- Product name
- Thianthrene5-oxide
- Purity
- 97%
- Packaging
- 100mg
- Price
- $63
- Updated
- 2021/12/16
- Product number
- A1205571
- Product name
- Thianthrene5-oxide
- Purity
- 97%
- Packaging
- 250mg
- Price
- $104
- Updated
- 2021/12/16
thianthrene 5-oxide Chemical Properties,Usage,Production
Uses
Thianthrene S-oxide is a sulfoxide-based thianthrene reagent for late-stage C-H functionalization. Developed by the Ritter Lab, C-H functionalization by thianthrenation proceeds with >99% selectivity and furnishes functionalized arenes serving as synthetic linchpins for further participation in diverse transformations. Nonfluorinated thianthrene S-oxide is best used for all arenes more electron-rich than anisole. For other arenes, the fluorinated TFT S-oxide (903981) was demonstrated as the thanthrenation reagent.
Synthesis Reference(s)
Journal of the American Chemical Society, 78, p. 2163, 1956 DOI: 10.1021/ja01591a037
Synthetic Communications, 22, p. 1799, 1992 DOI: 10.1080/00397919208020500
thianthrene 5-oxide Preparation Products And Raw materials
Raw materials
Preparation Products
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