Thianthrene
- Product Name
- Thianthrene
- CAS No.
- 92-85-3
- Chemical Name
- Thianthrene
- Synonyms
- Thianthren;AKOS 90207;hianthrene;THIANTHRENE;Thiaanthrene;Thianthrene,97%;Thianthrene >Thianthrene ,98%;THIANTHRENE, 99+%;diphylene disulfide
- CBNumber
- CB2460275
- Molecular Formula
- C12H8S2
- Formula Weight
- 216.32
- MOL File
- 92-85-3.mol
Thianthrene Property
- Melting point:
- 151-155 °C (lit.)
- Boiling point:
- 364-366 °C (lit.)
- Density
- 1.4420
- refractive index
- 1.6210 (estimate)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- DMF: soluble
- form
- powder to crystal
- color
- White to Light yellow
- BRN
- 83046
- CAS DataBase Reference
- 92-85-3(CAS DataBase Reference)
- NIST Chemistry Reference
- Thianthrene(92-85-3)
- EPA Substance Registry System
- Thianthrene (92-85-3)
Safety
- Safety Statements
- 24/25
- WGK Germany
- 3
- HS Code
- 29349990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 122440
- Product name
- Thianthrene
- Purity
- 97%
- Packaging
- 25g
- Price
- $87.1
- Updated
- 2024/03/01
- Product number
- NIST1656
- Product name
- Thianthrene
- Purity
- NIST SRM 1656, combustion calorimetric standard
- Packaging
- 30g
- Price
- $566
- Updated
- 2022/05/15
- Product number
- T0184
- Product name
- Thianthrene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $35
- Updated
- 2024/03/01
- Product number
- T0184
- Product name
- Thianthrene
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $77
- Updated
- 2024/03/01
- Product number
- JK570323
- Product name
- Thianthrene
- Purity
- 98%
- Packaging
- 5g
- Price
- $20
- Updated
- 2021/12/16
Thianthrene Chemical Properties,Usage,Production
Chemical Properties
White to off-white solid
Uses
Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.
Definition
ChEBI: The organosulfur heterocyclic compound that is the parent compound of the thianthrenes, a tricyclic structure comprising two benzene rings fused to the b and e sides of 1,4-dithin.
Synthesis Reference(s)
The Journal of Organic Chemistry, 31, p. 4071, 1966 DOI: 10.1021/jo01350a045
General Description
Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.
Purification Methods
thianthrene from Me2CO (charcoal), AcOH or EtOH. It sublimes in a vacuum. [Beilstein 19 H 45, 19 I 619, 19 II 34, 19 III/IV 347, 19/2 V 49.]
Thianthrene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Thianthrene manufacturers
- Product
- Thianthrene 92-85-3
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2023-03-01
- Product
- Thianthrene 92-85-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- Customized
- Release date
- 2019-05-25