ChemicalBook > CAS DataBase List > Thianthrene

Thianthrene

Product Name
Thianthrene
CAS No.
92-85-3
Chemical Name
Thianthrene
Synonyms
Thianthren;AKOS 90207;hianthrene;THIANTHRENE;Thiaanthrene;Thianthrene,97%;Thianthrene >Thianthrene ,98%;THIANTHRENE, 99+%;diphylene disulfide
CBNumber
CB2460275
Molecular Formula
C12H8S2
Formula Weight
216.32
MOL File
92-85-3.mol
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Thianthrene Property

Melting point:
151-155 °C (lit.)
Boiling point:
364-366 °C (lit.)
Density 
1.4420
refractive index 
1.6210 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMF: soluble
form 
powder to crystal
color 
White to Light yellow
BRN 
83046
CAS DataBase Reference
92-85-3(CAS DataBase Reference)
NIST Chemistry Reference
Thianthrene(92-85-3)
EPA Substance Registry System
Thianthrene (92-85-3)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
122440
Product name
Thianthrene
Purity
97%
Packaging
25g
Price
$87.1
Updated
2024/03/01
Sigma-Aldrich
Product number
NIST1656
Product name
Thianthrene
Purity
NIST SRM 1656, combustion calorimetric standard
Packaging
30g
Price
$566
Updated
2022/05/15
TCI Chemical
Product number
T0184
Product name
Thianthrene
Purity
>98.0%(GC)
Packaging
5g
Price
$35
Updated
2024/03/01
TCI Chemical
Product number
T0184
Product name
Thianthrene
Purity
>98.0%(GC)
Packaging
25g
Price
$77
Updated
2024/03/01
Frontier Specialty Chemicals
Product number
JK570323
Product name
Thianthrene
Purity
98%
Packaging
25g
Price
$79
Updated
2021/12/16
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Thianthrene Chemical Properties,Usage,Production

Chemical Properties

White to off-white solid

Uses

Thianthrene has been used to study aqueous solubilities of several solid nitrogen-, sulfur- and oxygen-containing heterocyclic derivatives of anthracene, phenanthrene and fluorene. It has been used in determination of partition coefficients of several sulfur-containing aromatics in 1-hexyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide and supercritical carbon dioxide.

Definition

ChEBI: The organosulfur heterocyclic compound that is the parent compound of the thianthrenes, a tricyclic structure comprising two benzene rings fused to the b and e sides of 1,4-dithin.

Synthesis Reference(s)

The Journal of Organic Chemistry, 31, p. 4071, 1966 DOI: 10.1021/jo01350a045

General Description

Thianthrene undergoes liquid phase tert-butylation in the presence of large pore zeolites and mesoporous aluminosilicates catalyst to yield tert-butyl derivatives. Thianthrene on oxidation in the presence of hydrogen peroxide and ligninase as catalyst from Phanerochaete chrysosporium yields thianthrene monosulfoxide.

Purification Methods

thianthrene from Me2CO (charcoal), AcOH or EtOH. It sublimes in a vacuum. [Beilstein 19 H 45, 19 I 619, 19 II 34, 19 III/IV 347, 19/2 V 49.]

Thianthrene Preparation Products And Raw materials

Raw materials

Preparation Products

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Thianthrene Suppliers

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View Lastest Price from Thianthrene manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Thianthrene 92-85-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-03-01
Career Henan Chemical Co
Product
Thianthrene 92-85-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-05-25

92-85-3, ThianthreneRelated Search:

5,7-Dihydro-2-methylthieno[3,4-d]pyrimidine Mesulfen 4,5-DIPHENYL-2-MERCAPTOOXAZOLE thianthrene 5-oxide,Thianthrene 10-oxide KU-55933 (ATM Kinase Inhibitor) Thianthrene THIANTHRENE-1-BORONIC ACID,Thianthrene-1-Boronic,THIANTHRENE-1-BORONIC ACID: TECH., 90% 5a,6a,12a,13a-Tetrahydro-dibenzo[b,i]thianthrene-5,7,12,14<br>-tetrone,5A,6A,12A,13A-TETRAHYDRO-DIBENZO[B,I]THIANTHRENE-5,7,12,14-TETRONE Dibenzo[b,i]thianthrene-5,7,12,14-tetrone Thianthrene, 5,10-dioxide thianthrene-1,9-dicarboxylic acid Thianthrene 5,5-dioxide Thianthrene-5-radical cation,Thianthrene 5-radical cation THIANTHRENE COMBUSTION CALORIMETR Dibenzo[a,h]thianthrene [1,4]Benzodithiino[2,3-b]thianthrene Dibenzo[b,i]thianthrene-5,7,12,14-tetrol 2,3,7,8-tetrabromo-5,10-dihydro-5lambda~6~,10lambda~6~-thianthrene-5,5,10,1 0-tetraone

  • THIANTHRENE
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  • dibenzo-1,4-dithiin
  • Thiaanthrene
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  • THIANTHRENE, 99+%
  • Dibenzodithiodioxane
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  • Thianthrene ,98%
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  • ethenyl dihydrogen phosphate
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  • 92-85-3
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