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Calcium tungstate

Product Name
Calcium tungstate
CAS No.
7790-75-2
Chemical Name
Calcium tungstate
Synonyms
CALC;EFHA3;CBARA1;ara CALC;DKFZp564C246;Allergen=Hom s 4;CALCIUM TUNGSTATE;calcium wolframate;Calciumtungstenoxi;CALCIUM BIPHOSPHATE
CBNumber
CB6135863
Molecular Formula
CaO4W
Formula Weight
287.92
MOL File
7790-75-2.mol
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Calcium tungstate Property

Melting point:
1620°C
Density 
6.06 g/mL at 25 °C (lit.)
storage temp. 
-20°C
solubility 
Insoluble in H{2}O. Decomposes by hot HCl, HNO{3}
form 
Powder
Specific Gravity
6.062
color 
white
Water Solubility 
insoluble H2O; decomposed by hot HCl, HNO3 [MER06]
Merck 
14,1712
Solubility Product Constant (Ksp)
pKsp: 8.06
Exposure limits
ACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference
7790-75-2(CAS DataBase Reference)
EPA Substance Registry System
Calcium tungsten oxide (CaWO4) (7790-75-2)
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Safety

WGK Germany 
3
TSCA 
Yes
HS Code 
28418030
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
248665
Product name
Calcium tungstate
Purity
powder
Packaging
100g
Price
$200
Updated
2024/03/01
Sigma-Aldrich
Product number
SAB1304787
Product name
ANTI-CBAA1 (N-TERM) antibody produced in rabbit
Purity
IgG fraction of antiserum, buffered aqueous solution
Packaging
400μl
Price
$481
Updated
2024/03/01
Sigma-Aldrich
Product number
248665
Product name
Calcium tungstate
Purity
powder
Packaging
500g
Price
$702
Updated
2024/03/01
Alfa Aesar
Product number
013051
Product name
Calcium tungsten oxide, 98%
Packaging
100g
Price
$68.65
Updated
2024/03/01
Alfa Aesar
Product number
013051
Product name
Calcium tungsten oxide, 98%
Packaging
25g
Price
$37.5
Updated
2023/06/20
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Calcium tungstate Chemical Properties,Usage,Production

Chemical Properties

-325 mesh, 10μm or less 99.9% pure; occurs in nature as mineral scheelite; white tetr powder(s), a=0.524 nm, c=1.138 nm; can be prepared by heating tungstic acid and CaO or CaCO3; used in tumor treatment and in luminous paint [KIR83] [STR93] [MER06]

Uses

Calcium tungsten oxide is used as a luminophore.

Uses

Calcium tungstate can be ued for preparing screens for x-ray observations and photographs; in luminous paints; in scintillation counters.

Application

Calcium tungstate is well known as the phosphor that emits light in λ: 310–700 nm under the excitation light in λ: 220–300 nm. The peak wavelength is positioned at 440 nm, causing it to give off a blue color.

Production Methods

A single crystal is grown from melt by the Czochralski method. Rare earth ions are easy to incorporate into the crystal during growth. Fluorescent films are deposited on a glass substrate through vacuum evaporation using a W filament heated at 2000℃ for about 3 min, followed by thermal annealing in oxygen at 550℃ for 2 h. The film becomes crystalline through this thermal annealing.

General Description

Calcium tungstate (CaWO4) is an optical material, which can be used as a laser host material for a variety of electronic applications. It has a scheelite structure with luminescence, and thermo-luminescence properties.

Flammability and Explosibility

Not classified

Structure and conformation

The space lattice of CaWO4 belongs to the tetragonal system, and its Scheelite structure has lattice constants of a=0.524 nm and c=1.138 nm. The space group is I41/a, and there are four formula units per unit cell.

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View Lastest Price from Calcium tungstate manufacturers

Henan Fengda Chemical Co., Ltd
Product
Calcium tungstate 7790-75-2
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-22
Hebei Mojin Biotechnology Co., Ltd
Product
Calcium tungstate 7790-75-2
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-22
Hebei Guanlang Biotechnology Co., Ltd.
Product
Calcium tungstate 7790-75-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2022-10-11

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