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(R)-C3-TUNEPHOS

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Product Name
(R)-C3-TUNEPHOS
CAS No.
486429-99-6
Chemical Name
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
CBNumber
CB6139371
Molecular Formula
C39H32O2P2
Formula Weight
594.62
MOL File
486429-99-6.mol
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(R)-C3-TUNEPHOS Property

Melting point:
153-161 °C(lit.)
Boiling point:
709.9±60.0 °C(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Powder
color 
white
Sensitive 
air sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Strem Chemicals
Product number
15-0176
Product name
(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS
Packaging
100mg
Price
$130
Updated
2024/03/01
Strem Chemicals
Product number
15-0176
Product name
(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS
Packaging
500mg
Price
$518
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0001361
Product name
(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
Purity
95.00%
Packaging
1G
Price
$630
Updated
2021/12/16
Crysdot
Product number
CD51000906
Product name
(S)-C3-TunePhos
Purity
95+%
Packaging
1g
Price
$1409
Updated
2021/12/16
Aaron Chemicals
Product number
AR003DCB
Product name
(S)-C3-TunePhos
Purity
98%
Packaging
250mg
Price
$233
Updated
2021/12/16
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(R)-C3-TUNEPHOS Chemical Properties,Usage,Production

Reaction

  1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
  2. Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
  3. Rh-catalyzed hydroformylation of cyclopropenes.

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Reactant for:

  • Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
  • Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates

Precatalyst for:
  • Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate

Catalyst for:
  • Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-C3-TUNEPHOS Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
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View Lastest Price from (R)-C3-TUNEPHOS manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
(S)-C3-TUNEPHOS 486429-99-6
Price
US $0.00-0.00/G
Min. Order
1G
Purity
98%
Supply Ability
500G
Release date
2024-06-19

486429-99-6, (R)-C3-TUNEPHOSRelated Search:


  • (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (S)-C3-TUNEPHOS
  • (R)-C3-TUNEPHOS
  • (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE
  • R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
  • (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN
  • (S)-C3-TUNEPHOS
  • (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,95%(S)-C3-TUNEPHOS
  • (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS
  • (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin
  • Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
  • 1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine
  • (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine
  • 1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine
  • 486429-99-6
  • C39H32O2P2
  • Privileged Ligands
  • ChiralQuest Ligands
  • Chiral Catalysts, Ligands, and Reagents
  • Asymmetric Synthesis
  • organophosphine ligand