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Lithium bis(oxalate)borate

Product Name
Lithium bis(oxalate)borate
CAS No.
244761-29-3
Chemical Name
Lithium bis(oxalate)borate
Synonyms
LIBOB;LITHIUM BIS(OXALATO)BORATE;CHEMLYTE BO MX;CHEMLYTE BO M1;lithium bis(oxalate)borate;Lithium oxalate boronic acid;Lithium bis(ethanedioato)borate;Lithium diethyleneic acid borate;Lithium bis(oxalato)borate LIBOB;LITHIUM BIS (OXALATE) BORATE(LiBOB)
CBNumber
CB6159579
Molecular Formula
C4BLiO8
Formula Weight
193.79
MOL File
244761-29-3.mol
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Lithium bis(oxalate)borate Property

Melting point:
>300°C (lit.)
vapor pressure 
0.004Pa at 20℃
storage temp. 
Inert atmosphere,Room Temperature
form 
powder or crystals
Water Solubility 
1015g/L at 20℃
InChI
InChI=1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1
InChIKey
NVQAYVUCVASGDK-UHFFFAOYSA-N
SMILES
O=C1C([O-][B+3]2([O-]C(=O)C(=O)[O-]2)[O-]1)=O.[Li+]
LogP
0 at 20℃
EPA Substance Registry System
Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
757136
Product name
Lithium bis(oxalato)borate
Packaging
25g
Price
$215
Updated
2024/03/01
TRC
Product number
L469278
Product name
LithiumBis(oxalate)borate
Packaging
100mg
Price
$75
Updated
2021/12/16
Oakwood
Product number
095833
Product name
Lithium bis(oxalato)borate
Packaging
25g
Price
$85
Updated
2021/12/16
AK Scientific
Product number
J53685
Product name
Lithiumbis(oxalate)borate
Packaging
25g
Price
$85
Updated
2021/12/16
Oakwood
Product number
095833
Product name
Lithium bis(oxalato)borate
Packaging
5g
Price
$25
Updated
2021/12/16
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Lithium bis(oxalate)borate Chemical Properties,Usage,Production

Uses

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.

Uses

Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc.

General Description

This product has been enhanced for energy efficiency.

Flammability and Explosibility

Non flammable

Synthesis

Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].

References

[1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.

Lithium bis(oxalate)borate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Lithium bis(oxalate)borate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $25.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-11
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-21
Hebei Mojin Biotechnology Co., Ltd
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-20

244761-29-3, Lithium bis(oxalate)borateRelated Search:


  • LIBOB
  • lithium bis(oxalate)borate
  • LITHIUM BIS(OXALATO)BORATE
  • CHEMLYTE BO M1
  • CHEMLYTE BO MX
  • LITHIUM BIS (OXALATE) BORATE(LiBOB)
  • Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium (1:1), (T-4)-
  • Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium, (T-4)-
  • Lithium bis(oxalate)borate LiBOB Lithium bis(ethanedioato)borate
  • LithiuM 2,3,7,8-tetraoxo-1,4,6,9-tetraoxa-5-boraspiro[4.4]nonan-5-uide
  • Lithium bis(ethanedioato)borate
  • Lithium bis-(oxalato)borate - LiBOB (sbg), standard battery grade
  • lithium,1,4,6,9-tetraoxa-5-boranuidaspiro[4.4]nonane-2,3,7,8-tetrone
  • Lithium oxalate boronic acid
  • Lithium bis(oxalate)borate ISO 9001:2015 REACH
  • Lithium diethyleneic acid borate
  • Lithium bis(oxalato)borate LIBOB
  • 244761-29-3
  • LiBC4O8
  • C4BLiO8