ChemicalBook > CAS DataBase List > Lithium bis(oxalate)borate

Lithium bis(oxalate)borate

Product Name
Lithium bis(oxalate)borate
CAS No.
244761-29-3
Chemical Name
Lithium bis(oxalate)borate
Synonyms
LIBOB;LITHIUM BIS(OXALATO)BORATE;CHEMLYTE BO MX;CHEMLYTE BO M1;lithium bis(oxalate)borate;Lithium oxalate boronic acid;Lithium bis(ethanedioato)borate;Lithium diethyleneic acid borate;Lithium bis(oxalato)borate LIBOB;LITHIUM BIS (OXALATE) BORATE(LiBOB)
CBNumber
CB6159579
Molecular Formula
C4BLiO8
Formula Weight
193.79
MOL File
244761-29-3.mol
More
Less

Lithium bis(oxalate)borate Property

Melting point:
>300°C (lit.)
vapor pressure 
0.004Pa at 20℃
storage temp. 
Inert atmosphere,Room Temperature
form 
powder or crystals
Water Solubility 
1015g/L at 20℃
InChI
InChI=1S/C4BO8.Li/c6-1-2(7)11-5(10-1)12-3(8)4(9)13-5;/q-1;+1
InChIKey
NVQAYVUCVASGDK-UHFFFAOYSA-N
SMILES
O=C1C([O-][B+3]2([O-]C(=O)C(=O)[O-]2)[O-]1)=O.[Li+]
LogP
0 at 20℃
EPA Substance Registry System
Borate(1-), bis[ethanedioato(2-)-.kappa.O1,.kappa.O2]-, lithium, (T-4)- (244761-29-3)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26
WGK Germany 
3
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H317May cause an allergic skin reaction

H318Causes serious eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
757136
Product name
Lithium bis(oxalato)borate
Packaging
25g
Price
$215
Updated
2024/03/01
TRC
Product number
L469278
Product name
LithiumBis(oxalate)borate
Packaging
100mg
Price
$75
Updated
2021/12/16
Oakwood
Product number
095833
Product name
Lithium bis(oxalato)borate
Packaging
25g
Price
$85
Updated
2021/12/16
AK Scientific
Product number
J53685
Product name
Lithiumbis(oxalate)borate
Packaging
25g
Price
$85
Updated
2021/12/16
Oakwood
Product number
095833
Product name
Lithium bis(oxalato)borate
Packaging
5g
Price
$25
Updated
2021/12/16
More
Less

Lithium bis(oxalate)borate Chemical Properties,Usage,Production

Uses

LiBOB is a novel boron based Li salt electrolyte material for Li ion batteries. It is environmentally friendly with good film forming property and high thermal stability and is compatible with a variety of anodes and metal oxide cathode.

Uses

Lithium bis(oxalate)borate is a new and proprietary conductive salt for the use in high performance batteries like lithium batteries, lithium ion batteries and lithium polymer batteries. The new halide-free product may be used instead of traditional fluorinated compounds like LiPF6, LiBF4, Li-triflate, methanides, imides etc.

General Description

This product has been enhanced for energy efficiency.

Flammability and Explosibility

Non flammable

Synthesis

Yu et al. employed a solid-state reaction using oxalic acid, lithium hydroxide, and boric acid as starting materials for the first time. This was followed by a thermal treatment in the air and a recrystallization process to obtain LiBOB. In addition, LiBOB decomposes into Li2C2O3, B2O3, CO2, and CO at temperatures higher than 300 °C [1].

References

[1] Ceren Zor. “Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB).” The Journal of Physical Chemistry C 125 21 (2021): 11310–11317.

Lithium bis(oxalate)borate Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

Lithium bis(oxalate)borate Suppliers

Fine Corporation
Tel
--
Fax
--
Email
info@fine-c.jp
Country
Japan
ProdList
1427
Advantage
58
TCI Japan
Tel
--
Fax
--
Email
@TCIchemicals.com
Country
Japan
ProdList
2741
Advantage
58
More
Less

View Lastest Price from Lithium bis(oxalate)borate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-02-21
Hebei Weibang Biotechnology Co., Ltd
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-30
Hebei Yanxi Chemical Co., Ltd.
Product
Lithium bis(oxalate)borate 244761-29-3
Price
US $25.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-11

244761-29-3, Lithium bis(oxalate)borateRelated Search:


  • LIBOB
  • lithium bis(oxalate)borate
  • LITHIUM BIS(OXALATO)BORATE
  • CHEMLYTE BO M1
  • CHEMLYTE BO MX
  • LITHIUM BIS (OXALATE) BORATE(LiBOB)
  • Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium (1:1), (T-4)-
  • Borate(1-), bis(ethanedioato(2-)-kappao1,kappao2)-, lithium, (T-4)-
  • Lithium bis(oxalate)borate LiBOB Lithium bis(ethanedioato)borate
  • LithiuM 2,3,7,8-tetraoxo-1,4,6,9-tetraoxa-5-boraspiro[4.4]nonan-5-uide
  • Lithium bis(ethanedioato)borate
  • Lithium bis-(oxalato)borate - LiBOB (sbg), standard battery grade
  • lithium,1,4,6,9-tetraoxa-5-boranuidaspiro[4.4]nonane-2,3,7,8-tetrone
  • Lithium oxalate boronic acid
  • Lithium bis(oxalate)borate ISO 9001:2015 REACH
  • Lithium diethyleneic acid borate
  • Lithium bis(oxalato)borate LIBOB
  • 244761-29-3
  • LiBC4O8
  • C4BLiO8