Chromium(III) acetylacetonate

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Chromium(III) acetylacetonate

Uses

Product Name: Chromium(III) acetylacetonate
CAS No.: 21679-31-2
Chemical Name: Chromium(III) acetylacetonate
Synonyms: Cr(acac)3;CHROMIUM(III) AA;(CH3COCHCOCH3)3Cr;Chromium(III) acetyl;Acetylacetone calcium;Chromiumpentanedionate;CHROMIC ACETYLACETONATE;Acetyl acetone chromium;CHROMIUM ACETYLACETONATE;CHROMIUMACETONYLACETONATE
CBNumber: CB6162896
Molecular Formula: C15H21CrO6
Formula Weight: 349.32
MOL File: 21679-31-2.mol

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Chromium(III) acetylacetonate Property

Melting point:: 210 °C(lit.)
Boiling point:: 340 °C(lit.)
Density: 1,35 g/cm³
vapor pressure: 0Pa at 20℃
Flash point:: >200°C
storage temp.: Store below +30°C.
solubility: 11g/l
form: Crystalline Powder, Crystals, and/or Chunks
Specific Gravity: 1.35
color: Purple to maroon
PH: 6 (1g/l, H2O, 20℃)
Water Solubility: 11 g/L (20 ºC)
Hydrolytic Sensitivity: 1: no significant reaction with aqueous systems
BRN: 4148971
Exposure limits: NIOSH: IDLH 25 mg/m3; TWA 0.5 mg/m3
LogP: 0.4 at 20℃
NIST Chemistry Reference: Chromium, tris(2,4-pentanedionato-o,o')-(21679-31-2)
EPA Substance Registry System: Chromium(III) acetylacetonate (21679-31-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 22-26-36-37/39
WGK Germany: 2
RTECS: GB7575000
TSCA: Yes
HS Code: 29420000
Toxicity: LD50 orally in Rabbit: 3360 mg/kg LD50 dermal Rabbit 6350 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 202231
Product name: Chromium(III) acetylacetonate
Purity: 97%
Packaging: 5g
Price: $36.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 8.02485
Product name: Chromium(III) acetylacetonate
Purity: for synthesis
Packaging: 100g
Price: $70.4
Updated: 2024/03/01

Sigma-Aldrich

Product number: 202231
Product name: Chromium(III) acetylacetonate
Purity: 97%
Packaging: 100g
Price: $63.2
Updated: 2024/03/01

TCI Chemical

Product number: C0336
Product name: Tris(2,4-pentanedionato)chromium(III)
Purity: >98.0%(T)
Packaging: 25g
Price: $18
Updated: 2024/03/01

TCI Chemical

Product number: C0336
Product name: Tris(2,4-pentanedionato)chromium(III)
Purity: >98.0%(T)
Packaging: 100g
Price: $49
Updated: 2024/03/01

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Chromium(III) acetylacetonate Chemical Properties,Usage,Production

Uses

Chromium(III) acetylacetonate is a useful research chemical.

Chemical Properties

PURPLE CRYSTALLINE POWDER

Uses

Catalyst in the oxidation of methacrylic esters by hydrogen peroxide, MOCVDChromium(III) 2,4-pentanedionate is used in the reduction of detonation of nitromethane. It is also used in NMR spectroscopy as a relaxation agent due to its solubility in nonpolar organic solvents and its paramagnetism. Further, it is involved in the modification of the surface properties of solid polyurethanes.

Uses

Chromium(III) acetylacetonate may be used as an active site in the formation of redox systems for the fabrication of flow batteries. It may also be used as a precursor for chromium nitride based metallic coatings.

General Description

Chromium(III) acetylacetonate is an acidopentamminechromium (111) salt, which is a crystalline material that can be prepared by treatment of precipitated hydrous chromium(III) oxide with acetylacetone.

Flammability and Explosibility

Not classified

Safety Profile

Moderately toxic by ingestion. Mildly toxic by s h contact. When heated to decomposition it emits acrid smoke and irritating fumes. See also CHROMIUM COMPOUNDS.

Purification Methods

Purify it by dissolving 6g in hot *C6H6 (20mL) and adding 75mL of pet ether slowly. Cool to room temperature then chill on ice, filter off and dry in air to give 2.9g. It also crystallises from EtOH. It is soluble in heptane, *C6H6, toluene and pentane-2,4-dione at 20-40o. It forms a 1:2 complex with CHCl3. [Fernelius & Blanch Inorg Synth V 130 1957, Steinbach & Burns J Am Chem Soc 80 1839 1958, Beilstein 1 H 782, 1 II 836, 1 IV 3673.]

Chromium(III) acetylacetonate Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chromium(III) acetylacetonate manufacturers

hebei hongtan Biotechnology Co., Ltd

Product: Chromium(III) acetylacetonate 21679-31-2
Price: US $80.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 1000
Release date: 2024-03-27

Hebei Mojin Biotechnology Co., Ltd

Product: Chromium(III) acetylacetonate 21679-31-2
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2024-03-26

Shaanxi Dideu Medichem Co. Ltd

Product: Chromium(III) acetylacetonate 21679-31-2
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%
Supply Ability: 2000tons
Release date: 2020-01-16

21679-31-2, Chromium(III) acetylacetonateRelated Search:

1,1,1-Trifluoro-2,4-pentanedione Acetylacetone ZIRCONIUM(IV) ACETYLACETONATE Manganic acetylacetonate CERIUM (III) ACETYLACETONATE HYDRATE ZINC ACETYLACETONATE HYDRATE Vanadyl acetylacetonate Bis(acetylacetonato)cobalt Ferric acetylacetonate Chromium Aluminum acetylacetonate Potassium chromate VANADIUM(III) ACETYLACETONATE Ethyl levulinate Methyl levulinate Acetylcholine Levulinic acid Bis(2,4-pentanedionato-O,O')palladium(II)

ACETYLACETONE CHROMIUM(+3)

ACETYLACETONE, CHROMIUM(III) DERIVATIVE

ACETYLACETONE CHROMIUM(III) SALT

2,4-PENTANEDIONE CHROMIUM SALT

Chromium 2,4-pentanedionate, 97.5+%

CHROMIUM(III) AA

CHROMIUM(III) 2,4-PENTANEDIONATE

CHROMIUM(III) ACETYLACETONATE

CHROMIUM 2,4-PENTANEDIONATE

CHROMIUM(+3)ACETYLACETONATE

CHROMIUMACETONYLACETONATE

CHROMIUM ACETYLACETONATE

CHROMIC ACETYLACETONATE

TRIS(2,4-PENTANEDIONATO)CHROMIUM(3)

TRIS(ACETYLACETONATO)CHROMIUM(III)

(CH3COCHCOCH3)3Cr

(OC-6-11)-tris(2,4-pentanedionato-O,o’)-chromium

4-pentanedionato-o,o’)-tris((oc-6-11)-chromiu

Chromictri-acetylacetonate

Chromium triacetylacetonate

Chromium tris(2,4-pentanedionate)

Chromium tris(acetylacetonate)

Chromium(3+), tris(2,4-pentanedionato)-

Chromium, tris(2,4-pentanedionato)-

Chromium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-

Chromium, tris(acetylacetonato)-

chromium,tris(2,4-pentanedionato-O,o’)-,(OC-6-11)-

chromiumtriacetylacetonate

Chromium(III) 2,4-pentanedionate, Cr(acac)3

Chromium, tris(2,4-pentanedionato-kO,kO')-, (OC-6-11)-

Chromium(III) acetylacetonate,97%

Chromium(III) acetyl

Cr(acac)3

ChroMiuM(III) acetylacetonate, 97% 100GR

ChroMiuM(III) acetylacetonate, 97% 5GR

Acetylacetone Chromium(III) Salt Chromium(III) Acetylacetonate

CHROMIUM(III) ACETYLACETONATE FOR SYNTHE

Chromium(Ⅲ) acetylacetonate

ChroMiuM(III) acetylacetonate 97%

ChroMiuM(III) acetylacetonate 99.99% trace Metals basis

CHROMIUM ACETYLACETONATECHROMIUM ACETYLACETONATECHROMIUM ACETYLACETONATECHROMIUM ACETYLACETONATE

tris(2,4-pentanedionato-κ2O,O')chromium(III)

chromiumtris(2,4-pentanedionate)

chromiumtris(acetylacetonate)

tris(2,4-pentanedionato)-chromiu

Tris(2,4-pentanedionato)chromium

Tris(acetylacetonato)chromium

Chromium(III) 2,4-pentanedionate~Tris(acetylacetonato)chromium(III)~Tris(2,4-pentanedionato)chromium(III)

chromium(III) 4-oxopent-2-ene-2-olate

Chromiumpentanedionate

chromium acaetylacetonate

Chromium(Ⅲ) triacetylacetonate

Chromium(III)acetylacetonate,97.5%

Chromium, tris(2,4-pentanedionato-.kappa.O,.kappa.O)-, (OC-6-11)-

Acetylacetone calcium

Chromium(III) acetylacetonate, 99.99% metals basis

TRIS(2,4-PENTANEDIONATO)CHROMIUM(3) 98+%

Tris(2,4-pentanedionato)chromium(III) &gt