1-BROMO-4-TRIMETHYLSILYLBENZENE

Product Name: 1-BROMO-4-TRIMETHYLSILYLBENZENE
CAS No.: 6999-03-7
Chemical Name: 1-BROMO-4-TRIMETHYLSILYLBENZENE
Synonyms: (4-Bromophenyl)trimethylsilane;1-BROMO-4-TRIMETHYLSILYLBENZENE;Silane, (4-bromophenyl)trimethyl-;Benzene, 1-bromo-4-(trimethylsilyl)-;1-Bromo-4-(trimethylsilyl)benzene,97%;1-Bromo-4-(trimethylsilyl)benzene 97%;1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%
CBNumber: CB6218009
Molecular Formula: C9H13BrSi
Formula Weight: 229.19
MOL File: 6999-03-7.mol

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1-BROMO-4-TRIMETHYLSILYLBENZENE Property

Melting point:: 95-96 °C
Boiling point:: 229.5 °C752 mm Hg(lit.)
Density: 1.173 g/mL at 25 °C(lit.)
refractive index: n20/D 1.529(lit.)
Flash point:: 205 °F
storage temp.: Sealed in dry,Room Temperature
form: clear liquid
color: Colorless to Almost colorless
InChIKey: UKTSSJJZFVGTCG-UHFFFAOYSA-N

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Safety

WGK Germany: 3
HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 455113
Product name: 1-Bromo-4-(trimethylsilyl)benzene
Purity: 97%
Packaging: 5g
Price: $168.9
Updated: 2025/07/31

TCI Chemical

Product number: B3357
Product name: 1-Bromo-4-(trimethylsilyl)benzene
Purity: >97.0%(GC)
Packaging: 5g
Price: $109
Updated: 2025/07/31

TCI Chemical

Product number: B3357
Product name: 1-Bromo-4-(trimethylsilyl)benzene
Purity: >97.0%(GC)
Packaging: 25g
Price: $389
Updated: 2025/07/31

GFS CHEMICALS

Product number: 10421
Product name: 1-BROMO-4-TMSBENZENE
Packaging: 1g
Price: $32.12
Updated: 2021/12/16

TRC

Product number: B700390
Product name: 1-Bromo-4-trimethylsilylbenzene
Packaging: 1g
Price: $75
Updated: 2021/12/16

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1-BROMO-4-TRIMETHYLSILYLBENZENE Chemical Properties,Usage,Production

Synthesis

75-77-4

106-37-6

6999-03-7

The general procedure for the synthesis of 1-bromo-4-trimethylsilylbenzene from trimethylchlorosilane and 1,4-dibromobenzene was as follows: the synthesis was carried out using the photoinitiator PI-1 as shown in Scheme 1. The specific operation was as follows: 1,4-dibromobenzene (23.6 g, 100 mmol) was dissolved in 200 mL of anhydrous ether in a 500 mL three-necked flask equipped with a thermometer, a condensing device and a dropping funnel. Slowly n-butyllithium (41.7 mL, 2.4 M in THF) was added dropwise at -78 °C. After completion of the reaction, the reaction was quenched by the addition of trimethylchlorosilane (5.2 mL, 40 mmol) at the same temperature to give the intermediate IM-1 (22 g, 96% yield) as an oil.

References

[1] Journal of the American Chemical Society, 2003, vol. 125, # 20, p. 6058 - 6059
[2] Bulletin of the Chemical Society of Japan, 2004, vol. 77, # 11, p. 2071 - 2080
[3] Angewandte Chemie - International Edition, 2018, vol. 57, # 36, p. 11688 - 11691
[4] Angew. Chem., 2018, vol. 130, # 36, p. 11862 - 11865,4
[5] European Journal of Organic Chemistry, 1999, # 9, p. 2079 - 2085

1-BROMO-4-TRIMETHYLSILYLBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-4-TRIMETHYLSILYLBENZENE Suppliers

Americas 1 China 120 Europe 1 Germany 1 India 2 Japan 1 Slovakia 1 Switzerland 1 United Kingdom 2 United States 12 Global 142

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View Lastest Price from 1-BROMO-4-TRIMETHYLSILYLBENZENE manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 1-Bromo-4-(trimethylsilyl)benzene 6999-03-7
Price: US $0.10/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000 tons
Release date: 2020-01-13

Career Henan Chemical Co

Product: 1-BROMO-4-TRIMETHYLSILYLBENZENE 6999-03-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1
Release date: 2018-08-06

6999-03-7, 1-BROMO-4-TRIMETHYLSILYLBENZENERelated Search:

2-(Trimethylsilyl)ethoxymethyl chloride TRIMETHYLSILANE 1-BROMO-3-TRIMETHYLSILYLBENZENE 4-Bromotetraphenylsilane 1-BROMO-4-TRIMETHYLSILYLBENZENE

1-Bromo-4-(trimethylsilyl)benzene 97%

1-Bromo-4-(trimethylsilyl)benzene,97%

1-BROMO-4-TRIMETHYLSILYLBENZENE

Silane, (4-bromophenyl)trimethyl-

(4-Bromophenyl)trimethylsilane

1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%1-BROMO-4-TRIMETHYLSILYLBENZENE, 97%

Benzene, 1-bromo-4-(trimethylsilyl)-

6999-03-7

BrC6H4SiCH33

C9H13BrSi

Halogenated Hydrocarbons

Organic Building Blocks

Aryl

C9 to C12

Building Blocks

Si (Classes of Silicon Compounds)

Si-(C)4 Compounds

Aryl

C9 to C12

Halogenated Hydrocarbons