4-tert-Butoxystyrene
- Product Name
- 4-tert-Butoxystyrene
- CAS No.
- 95418-58-9
- Chemical Name
- 4-tert-Butoxystyrene
- Synonyms
- P-T-BUTOXYSTYRENE;4-T-BUTOXYSTYRENE;p-tert-butoxystyrene;1-ethenyl;butoxy styrene;4-tert-butoxystyene;4-TERT-BUTOXYSTYRENE;(1-Butoxyvinyl)benzene;4-tert-Butyloxystyrene;p-(tert-Butyloxy)styrene
- CBNumber
- CB6229094
- Molecular Formula
- C12H16O
- Formula Weight
- 176.25
- MOL File
- 95418-58-9.mol
4-tert-Butoxystyrene Property
- Melting point:
- −38 °C(lit.)
- Boiling point:
- 256.8±9.0 °C Press: 760 Torr
- Density
- 0.936 g/mL at 25 °C(lit.)
- vapor pressure
- 17.999Pa at 20℃
- refractive index
- n20/D 1.524(lit.)
- Flash point:
- 207 °F
- InChI
- InChI=1S/C12H16O/c1-5-10-6-8-11(9-7-10)13-12(2,3)4/h5-9H,1H2,2-4H3
- InChIKey
- GRFNSWBVXHLTCI-UHFFFAOYSA-N
- SMILES
- C1(OC(C)(C)C)=CC=C(C=C)C=C1
- LogP
- 3.83 at 22℃ and pH7
- CAS DataBase Reference
- 95418-58-9(CAS DataBase Reference)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 455644
- Product name
- 4-tert-Butoxystyrene
- Purity
- 99%, contains 200 ppm 4-tert-butylcatechol as inhibitor
- Packaging
- 50ml
- Price
- $69.7
- Updated
- 2024/03/01
- Product number
- 2907-1-04
- Product name
- 1-(tert-Butoxy)-4-ethenylbenzene
- Packaging
- 10g
- Price
- $30
- Updated
- 2021/12/16
- Product number
- 2907-1-04
- Product name
- 1-(tert-Butoxy)-4-ethenylbenzene
- Packaging
- 25g
- Price
- $59
- Updated
- 2021/12/16
4-tert-Butoxystyrene Chemical Properties,Usage,Production
Description
4-tert-butoxystyrene is a pendant functionalized styrene that structurally, It is similar to PMOS, both carrying an alkoxyl p-substituent, whose electron-donating and resonance effects allow them to be'polymerized by cationic, anionic, and radical mechanisms. It is used to treatment of its polymers with an acid leads to poly(4-vinylphenol), which finds a wide variety of applications to photoresists, epoxy-curing agents, adhesives, etc.).
Chemical Properties
Colorless to Almost colorless clear liquid.
Uses
4-tert-Butoxystyrene is used in organic synthesis. It is used to synthesize 4'-tert-butoxy-biphenyl-4-carboxylic acid methyl ester.
Application
4-tert-Butoxystyrene is an organic synthetic reagent used as a polymer monomer in the preparation of poly(4-tert-butoxystyrene) (PtBSt) and other living polymers. Poly(4-tert-Butoxystyrene) is a new hexane-soluble polymer surfactant that can be used to form micelles.
Synthesis
Preparation of 4-tert-Butoxystyrene (3-tert-Butoxystyrene). To a 2000-mL three-necked round-bottom flask equipped with a dropping funnel, thermometer, reflux condenser, paddle stirrer and nitrogen inlet were placed 19.4 g (0.80 mol) of magnesium turnings and enough freshly dried and distilled tetrahydrofuran (THF) to cover the turnings. There were then added dropwise with stirring a solution of 143.3g (0.78 mol) of freshly distilled 4-bromostyrene (bp 46-47°C (0.03 mm)) in 500mL of THF. After 20mL of the 4-bromostyrene had been added, an exothermic reaction set in and was maintained between 25 and 35°C by adjusting the rate of addition of the bromo compound and with the aid of an ice bath. After the addition had been completed, the reaction mixture was heated to 60°C for 0.5h. Using a NaC1-ice bath, the mixture was cooled to 0°C and a solution of 100.88g (0.52 mol) of tert-butyl peroxybenzoate in 200 mL of THF was added via the dropping funnel at such a rate that the reaction temperature was maintained between 0 and 5°C. After completion of the addition, the reaction mixture was stirred at 25°C for 2 h. The organic layer was separated from the solid magnesium benzoate by decantation and the volume of the solution reduced on a rotary evaporator. The yellow oil that remained was washed with 1000 mL of 3% aqueous HCl solution and the organic layer separated. The aqueous layer was washed with two 200-mL portions of ether, and the ether and organic layers were combined and together washed with two 75-mL portions of a 10% NaOH solution followed by washing with water until the aqueous washings were neutral. After the solution was dried over Na2S04 and the ether was removed via a rotary evaporator, the remaining pale yellow oil was purified by fractional distillation in the presence of a few milligrams of ionol (2,6-ditert-butyl-4-methylphenol) as an inhibitor. There were obtained 46 g (50% yield, bp 45°C (0.02 mm)) of 4-tert-Butoxystyrene having the following elemental analysis.
References
Living cationic sequential block copolymerization of isobutylene with 4-tert-butoxystyrene: synthesis and characterization of poly(p-hydroxystyrene-b-isobutylene-b-p-hydroxystyrene) triblock copolymers.
Bouchékif, H.; Som, A.; Sipos, L.; Faust, R.; Journal of Macromolecular Science, Part A: Pure and Applied Chemistry (2007), 44(4), 359-366.
4-tert-Butoxystyrene Preparation Products And Raw materials
Raw materials
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View Lastest Price from 4-tert-Butoxystyrene manufacturers
- Product
- 4-tert-Butoxystyrene 95418-58-9
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%+
- Supply Ability
- 10000kg per Month
- Release date
- 2023-04-05
- Product
- 4-tert-Butoxystyrene 95418-58-9
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99.5%
- Supply Ability
- 1000kg
- Release date
- 2024-06-04
- Product
- 4-tert-Butoxystyrene 95418-58-9
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99.5%GPC
- Supply Ability
- 2tons
- Release date
- 2023-11-24